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| Names | |
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Other names
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| Identifiers | |
3D model (JSmol) | |
PubChem CID | |
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| Properties | |
| C2H7N7O5 | |
| Molar mass | 209.122 g·mol−1 |
| Appearance | White crystalline powder |
| Density | 1.760 g cm−3 |
| Explosive data | |
| Detonation velocity | 8235 m/s |
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
Main hazards | Explosive |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Guanylurea dinitramide (FOX-12 or GUDN) is a novel insensitive high explosive.
GUDN was discovered by Abraham Langlet, a chemist at the Swedish Defence Research Agency, and patented in 1997. [1] The moniker FOX-12 stems from the Swedish-language acronym for the Agency, FOI, plus x for "explosive." [2]
GUDN is particularly valued for its extreme stability and insensitivity.
GUDN found its first major application when mixed with oxidizers such as potassium nitrate or copper nitrate in automotive airbag inflators. [3]
GUDN is also used in a 60/40 mix with RDX as a propellant in the UNIFLEX 2 IM modular artillery charge system fielded in the BAE 155mm/L52 Archer howitzer. [4]
Blended in equal parts with TNT, GUDN forms the a melt-castable explosive known as GUNTOL. A variation adding 15% Aluminum is known as GUNTONAL. [5]
Upon detonation, GUDN undergoes a thermal decomposition which is not entirely understood as of 2021. [6] The calculated detonation velocity is 8235 m/s, with a detonation pressure of 25.89 GPa, and a detonation temperature of 2887 K. [7]
GUDN is synthesized by a reaction of Ammonium dinitramide and the sulfate salt of guanylurea. [2]
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
Nitroglycerin (NG), also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Invented in 1847 by Ascanio Sobrero, nitroglycerin has been used ever since as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. Since the 1880s, it has been used by militaries as an active ingredient and gelatinizer for nitrocellulose in some solid propellants such as cordite and ballistite. It is a major component in double-based smokeless propellants used by reloaders. Combined with nitrocellulose, hundreds of powder combinations are used by rifle, pistol, and shotgun reloaders.
Trinitrotoluene, more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts.
Ammonium nitrate is a chemical compound with the chemical formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer. Global production was estimated at 21.6 million tonnes in 2017.
Polymer-bonded explosives, also called PBX or plastic-bonded explosives, are explosive materials in which explosive powder is bound together in a matrix using small quantities of a synthetic polymer. PBXs are normally used for explosive materials that are not easily melted into a casting, or are otherwise difficult to form.
Amatol is a highly explosive material made from a mixture of TNT and ammonium nitrate. The British name originates from the words ammonium and toluene. Similar mixtures were known as Schneiderite in France. Amatol was used extensively during World War I and World War II, typically as an explosive in military weapons such as aircraft bombs, shells, depth charges, and naval mines. It was eventually replaced with alternative explosives such as Composition B, Torpex, and Tritonal.
A triggering sequence, also called an explosive train or a firing train, is a sequence of events that culminates in the detonation of explosives. For safety reasons, most widely used high explosives are difficult to detonate. A primary explosive of higher sensitivity is used to trigger a uniform and predictable detonation of the main body of the explosive. Although the primary explosive itself is generally a more sensitive and expensive compound, it is only used in small quantities and in relatively safely packaged forms. By design there are low explosives and high explosives made such that the low explosives are highly sensitive and high explosives are comparatively insensitive. This not only affords inherent safety to the usage of explosives during handling and transport, but also necessitates an explosive triggering sequence or explosive train. The explosive triggering sequence or the explosive train essentially consists of an 'initiator', an 'intermediary' and the 'high explosive'.
Octanitrocubane (molecular formula: C8(NO2)8) is a high explosive that, like TNT, is shock-insensitive (not readily detonated by shock). The octanitrocubane molecule has the same chemical structure as cubane (C8H8) except that each of the eight hydrogen atoms is replaced by a nitro group (NO2).
FOX-7 or 1,1-diamino-2,2-dinitroethylene(DADNE) is an insensitive high explosive compound. It was first synthesized in 1998 by the Swedish National Defence Research Institute (FOS). The name FOX-7 is derived from the acronym of the Swedish Defence Research Agency (FOI), with the I replaced by an X to indicate an explosive, as in RDX and HMX.
Nitroguanidine - sometimes abbreviated NGu - is a colorless, crystalline solid that melts at 257 °C and decomposes at 254 °C. Nitroguanidine is an extremely insensitive but powerful high explosive. Wetting it with > 20 wt.-% water effects desensitization from HD 1.1 down to HD 4.1 . Nitroguanidine is used as an energetic material, i.e., propellant or high explosive, precursor for insecticides, and for other purposes.
TATB, triaminotrinitrobenzene or 2,4,6-triamino-1,3,5-trinitrobenzene is an aromatic explosive, based on the basic six-carbon benzene ring structure with three nitro functional groups (NO2) and three amine (NH2) groups attached, alternating around the ring.
Erythritol tetranitrate (ETN) is an explosive compound chemically similar to PETN, though it is thought to be slightly more sensitive to friction and impact.
Urea nitrate is a fertilizer-based high explosive that has been used in improvised explosive devices in Afghanistan, Pakistan, Iraq, and various terrorist acts elsewhere in the world such as in the 1993 World Trade Center bombings. It has a destructive power similar to better-known ammonium nitrate explosives, with a velocity of detonation between 3,400 m/s (11,155 ft/s) and 4,700 m/s (15,420 ft/s). It's chemical formula is CH5N3O4 or (NH2)2COHNO3.
High Energy Materials Research Laboratory (HEMRL) is a laboratory of the Defence Research and Development Organisation (DRDO). Located in Pune, its main function is the research and development of technologies and products in the area of High Energy Materials and Explosive materials. HEMRL is organised under the Armaments Directorate of DRDO. The Ex. director of HEMRL was Late Bikash Bhattacharya.
Xylitol pentanitrate (XPN) is a nitrated ester primary explosive first synthesized in 1891 by Gabriel Bertrand. Law enforcement has taken an interest in XPN along with erythritol tetranitrate (ETN) and pentaerythritol tetranitrate (PETN) due to their ease of synthesis, which makes them accessible to amateur chemists and terrorists.
Ammonium dinitramide (ADN) is the ammonium salt of dinitraminic acid. ADN decomposes under heat to leave only nitrogen, oxygen, and water. The ions are the ammonium ion NH4+ and the dinitramide N(NO2)2−.
IMX-101 is a high-performance insensitive high explosive composite mixture developed by BAE Systems and the United States Army to replace TNT in artillery shells, starting as soon as 2011. IMX stands for "Insensitive Munitions eXplosives", which refers to the purpose of IMX-101: to provide explosive force equivalent to TNT without its sensitivity to shocks such as gunfire, explosions from improvised explosive devices, fire, and shrapnel. For example, it is believed that a training incident in Nevada which killed seven Marines would not have occurred with the new explosive. On March 23, 2013, the United States Army ordered $780 million worth of the explosive, with a production of millions of pounds annually, to be produced by BAE at Holston Army Ammunition Plant in Tennessee. The new explosive will cost $8 per pound, compared to $6 per pound for TNT.
Staged detonation is an overall principle used for many explosive devices. A general description of the principle is that one explosive compound with one set of properties is detonated, and the detonation wave from this is transfers into another explosive compound with different set of properties.
Nickel hydrazine nitrate (NHN), (chemical formula: [Ni(N2H4)3](NO3)2 is an energetic material having explosive properties in between that of primary explosive and a secondary explosive. It is a salt of a coordination compound of nickel with a reaction equation of 3N2H4·H2O + Ni(NO3)2 →〔Ni(N2H4)3〕(NO3)2 ＋ 3H2O
Bis-oxadiazole, or more formally known as bis(1,2,4-oxadiazole)bis(methylene) dinitrate, is a nitrated heterocyclic compound of the oxadiazole family.
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