Harpur Hill Quarry Lagoon | |
---|---|
Location | Harpur Hill |
Coordinates | 53°14′01″N1°54′15″W / 53.2336°N 1.9043°W |
Lake type | artificial |
Primary inflows | groundwater |
Primary outflows | evaporation, seepage |
Basin countries | England |
First flooded | c. 2005 |
Max. length | 308 ft (94 m) |
Average depth | 2 m (6 ft 7 in) |
Max. depth | 3 m (9.8 ft) |
Settlements | King Sterndale, Buxton |
Harpur Hill Quarry is a disused limestone quarry on Harpur Hill, Derbyshire, England. Limestone was extracted there from 1835 to 1952 for lime burning at lime kilns to produce quicklime. The quarry was used by the Royal Air Force as a chemical weapons storage depot during the Second World War, the largest such depot in the United Kingdom. Afterwards a number of captured German chemical munitions were disposed of at the site by burning, which was only partially successful. The RAF depot closed in 1960 and the site is now vacant.
A small part of the abandoned quarry has flooded to become a quarry lake. Its water has a very high pH, that is, it is very alkaline, owing to the presence of caustic chemicals that are leaching from the waste left from the lime burning. The lake water has a vivid blue colour due to the scattering of light by finely dispersed particles of calcium carbonate. Despite signs warning of the health risks the lake became a popular tourist destination and swimming spot. The local High Peak Borough Council dyed the water black in 2013, 2016 and 2020 in an attempt to deter swimmers.
The site near Harpur Hill, south of Buxton, was worked as a limestone quarry. [1] Small-scale lime burning had taken place near Harpur Hill since at least the 1600s, initially around Grin Low near Poole's Cavern to the north, using lime kilns to produce quicklime by calcinating the limestone (mainly Bee Low Limestones) quarried nearby (that is, heating calcium carbonate to produce calcium oxide). A site beside the quarry was used for large-scale lime production from around 1835 to around 1952, using larger shaft kilns and then a multi-chambered Hoffmann kiln, operated by Buxton Lime Firms Ltd (later Brunner Mond from 1918, and then ICI from 1926). The Hoffmann lime kiln was demolished in 1980 to create space for an industrial estate. Large volumes of solid waste from the lime burning were dumped in tips nearby, creating spoil heaps contaminated with traces of quicklime and with ash from the coal used in the process. Water percolating through the waste leaches calcium hydroxide and becomes alkaline. [2]
The site was taken over by the Royal Air Force (RAF) in 1938 for use as a depot for the storage of chemical weapons. Poor weather delayed construction and the depot did not become operational until 1940. [3]
During the Second World War it was the largest chemical weapons storage depot in the country, covering some 500 acres (2.0 km2). [1] [4] [3]
After the war the site was occupied by an RAF unexploded ordnance disposal unit, known as an X station, and used for storage and disarmament of captured German chemical weapons and V-rocket warheads. The RAF disposed of chemical weapons, including mustard gas and phosgene, by burning the substances with bleach on the surrounding hills. This proved unsustainable, as large quantities of smoke were produced and the destruction was incomplete. Some mustard gas escaped as a vapour and much of the nearby vegetation was killed. The site also housed an RAF Mountain Rescue team who attended air crashes across Derbyshire. The RAF depot closed down in 1960. [3]
A quarry lake, officially known as Hoffman Quarry but also known as the Blue Lagoon, at the site became a tourist attraction owing to its vivid turquoise-blue coloration. [5] It has attracted visitors from across the country. [5] [6] [7] The colour derives from the scattering of light by small particles of calcium carbonate that are precipitating within the water. [2] The caustic quicklime dissolved in the water gives it a pH level of 11.3 (by comparison bleach has a pH of 12.3). [6]
Signs at the site state the water can cause "skin and eye irritations, stomach problems and fungal infections such as thrush" and that the quarry is known to contain car wrecks, dead animals, excrement and rubbish. [6] [5] The water is also extremely cold. [5] Despite this the lake continued to be a popular destination visited by hundreds of people. [8]
Around 750 local people, concerned about the health risks, signed a petition to have the quarry drained and closed off. However the water was deemed too toxic to drain, as it would risk contaminating local water supplies. [5]
In order to deter swimmers the water was dyed black in 2013 by High Peak Borough Council, who acted after being unable to get in touch with the site's owner. [6] [5] The dye wore off by 2015 and the water returned to a blue coloration. The council redyed the lake in 2016 with a stronger mixture, but by October 2019 it showed signs of returning to a blue colour. [5] In March 2020 the lake was dyed again following reports of people gathering there despite social distancing instructions issued by the British government to combat the COVID-19 pandemic. [9] It was redyed by High Peak Borough Council and Derbyshire Fire and Rescue on 29 May after people flocked to the site for the bank holiday weekend (25 May). The police also coned off potential parking spaces in Harpur Hill. [10] With people continuing to visit the site local farmers attempted to deter them by spreading pig and cow slurry across the surrounding land on 19 June 2020. [11]
Derbyshire Police found the body of a 44-year-old man at the quarry on 18 February 2019. The death was found not to be suspicious. [12]
On 29 September 2019 two firefighters from Staffordshire Fire and Rescue Service were injured whilst carrying out rope rescue training at the quarry. One of them was hospitalised with life-changing injuries. [13]
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource.
Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.
Buxton is a spa town in the Borough of High Peak, Derbyshire, in the East Midlands region of England. It is England's highest market town, sited at some 1,000 feet (300 m) above sea level. It lies close to Cheshire to the west and Staffordshire to the south, on the edge of the Peak District National Park. In 1974, the municipal borough merged with other nearby boroughs, including Glossop, to form the local government district and borough of High Peak.
Calcium oxide, commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.
A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is
Agricultural lime, also called aglime, agricultural limestone, garden lime or liming, is a soil additive made from pulverized limestone or chalk. The primary active component is calcium carbonate. Additional chemicals vary depending on the mineral source and may include calcium oxide. Unlike the types of lime called quicklime and slaked lime, powdered limestone does not require lime burning in a lime kiln; it only requires milling. All of these types of lime are sometimes used as soil conditioners, with a common theme of providing a base to correct acidity, but lime for farm fields today is often crushed limestone. Historically, liming of farm fields in centuries past was often done with burnt lime; the difference is at least partially explained by the fact that affordable mass-production-scale fine milling of stone and ore relies on technologies developed since the mid-19th century.
Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition.
Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.
Dove Holes is a village in the High Peak district of Derbyshire, England. It has a population of about 1,200 (2001), shown in the 2011 Census as being included in the population of Chapel-en-le-Frith. It straddles the A6 road, approximately three miles north of Buxton and three miles south of Chapel-en-le-Frith.
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The Milwaukee Falls Lime Company is the former owner of a limestone quarry and lime kilns located in Grafton, Wisconsin. It was added to the National Register of Historic Places in 2012. The quarry and kilns are now Lime Kiln Park, which also features a pavilion, playground, walking paths, sledding hill, horseshoe pits, and disc golf course.
RAF Harpur Hill is a former Royal Air Force station, situated at Harpur Hill near Buxton, Derbyshire in England. The site was operational from 1938 to 1960 and was mainly used as an underground munitions storage facility. It became the largest ammunitions dump in the country across the 500 acres (200 ha) site.
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A limepit is either a place where limestone is quarried, or a man-made pit used to burn lime stones in the same way that modern-day kilns and furnaces constructed of brick are now used above ground for the calcination of limestone (calcium carbonate, CaCO3) and by which quicklime (calcium oxide, CaO) is produced, an essential component in waterproofing and in wall plastering (plaster skim).
The Buxton lime industry has been important for the development of the town of Buxton in Derbyshire, England, and it has shaped the landscape around the town.
The Derbyshire Dome is a geological formation across mid-Derbyshire in England.
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Grin Low is a hill overlooking Buxton in Derbyshire, in the Peak District. The summit is 434 metres (1,424 ft) above sea level.
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