Hypogene

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In ore deposit geology, hypogene processes occur deep below the Earth's surface, and tend to form deposits of primary minerals, as opposed to supergene processes that occur at or near the surface, and tend to form secondary minerals. [1]

Contents

At great depth the pressure is high, and water can remain liquid at temperatures well above 100 °C. Hot aqueous solutions originating from magmas, deep sedimentary basins, or areas of elevated geothermal gradients can contain metals and other ions derived from the magma itself or from leaching of sedimentary, igneous, or metamorphic rocks. Hypogene deposition processes include crystallization from the hot aqueous solutions flowing through the Earth's crust, driven by temperature and pressure gradients, as well as topographic, orogenic, and structural changes and/or controls. [2]

Major dissolved components are chlorine, sodium, calcium, magnesium and potassium, and other important components include iron, manganese, copper, zinc, lead, sulfur (as SO2−
4
or S2− or both) carbon (as HCO
3
and CO2) and nitrogen (as NH+
4
). Most ore fluids contain chloride as the dominant anion. [3]

As the solutions rise the temperature and pressure fall. Eventually a point is reached where the minerals start to crystallise out. [2] Minerals formed in this way are called primary, or hypogene, minerals. Sulfur is a common component of the fluids, and most of the common ore metals, lead, zinc, copper, silver, molybdenum and mercury, occur chiefly as sulfide and sulfosalt minerals. [3] Examples of primary minerals formed in this way include the sulfide minerals pyrite (FeS2), galena (PbS), sphalerite (ZnS), and chalcopyrite (CuFeS2).

Etymology

The word hypogene is derived from the Greek roots hypo- ( ὑπο- ) meaning 'under' and -gene ( -γενής ) meaning 'born' or 'produced'. The terms hypogene and supergene refer to the depth at which they occur.

See also

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<span class="mw-page-title-main">Chalcopyrite</span> Copper iron sulfide mineral

Chalcopyrite ( KAL-kə-PY-ryte, -⁠koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.

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<span class="mw-page-title-main">Bornite</span> Sulfide mineral

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<span class="mw-page-title-main">Skarn</span> Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, bimetasomatic reaction of different lithologies, and infiltration metasomatism by magmatic-hydrothermal fluids. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.

<span class="mw-page-title-main">Copper extraction</span> Process of extracting copper from the ground

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<span class="mw-page-title-main">Volcanogenic massive sulfide ore deposit</span> Metal sulfide ore deposit

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<span class="mw-page-title-main">Porphyry copper deposit</span> Type of copper ore body

Porphyry copper deposits are copper ore bodies that are formed from hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those fluids are vertical dikes of porphyritic intrusive rocks from which this deposit type derives its name. In later stages, circulating meteoric fluids may interact with the magmatic fluids. Successive envelopes of hydrothermal alteration typically enclose a core of disseminated ore minerals in often stockwork-forming hairline fractures and veins. Because of their large volume, porphyry orebodies can be economic from copper concentrations as low as 0.15% copper and can have economic amounts of by-products such as molybdenum, silver, and gold. In some mines, those metals are the main product.

<span class="mw-page-title-main">Ore genesis</span> How the various types of mineral deposits form within the Earths crust

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<span class="mw-page-title-main">Sedimentary exhalative deposits</span> Zinc-lead deposits

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In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary (hypogene) sulfide ore minerals and redistribute the metallic ore elements. Supergene enrichment occurs at the base of the oxidized portion of an ore deposit. Metals that have been leached from the oxidized ore are carried downward by percolating groundwater, and react with hypogene sulfides at the supergene-hypogene boundary. The reaction produces secondary sulfides with metal contents higher than those of the primary ore. This is particularly noted in copper ore deposits where the copper sulfide minerals chalcocite (Cu2S), covellite (CuS), digenite (Cu18S10), and djurleite (Cu31S16) are deposited by the descending surface waters.

Violarite (Fe2+Ni23+S4) is a supergene sulfide mineral associated with the weathering and oxidation of primary pentlandite nickel sulfide ore minerals.

<span class="mw-page-title-main">Mineral redox buffer</span> Geochemical assemblage

In geology, a redox buffer is an assemblage of minerals or compounds that constrains oxygen fugacity as a function of temperature. Knowledge of the redox conditions (or equivalently, oxygen fugacities) at which a rock forms and evolves can be important for interpreting the rock history. Iron, sulfur, and manganese are three of the relatively abundant elements in the Earth's crust that occur in more than one oxidation state. For instance, iron, the fourth most abundant element in the crust, exists as native iron, ferrous iron (Fe2+), and ferric iron (Fe3+). The redox state of a rock affects the relative proportions of the oxidation states of these elements and hence may determine both the minerals present and their compositions. If a rock contains pure minerals that constitute a redox buffer, then the oxygen fugacity of equilibration is defined by one of the curves in the accompanying fugacity-temperature diagram.

<span class="mw-page-title-main">Polymetallic replacement deposit</span>

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<span class="mw-page-title-main">Carbonate-hosted lead-zinc ore deposits</span>

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<span class="mw-page-title-main">Cobalt extraction</span>

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<span class="mw-page-title-main">Primary mineral</span>

A primary mineral is any mineral formed during the original crystallization of the host igneous primary rock and includes the essential mineral(s) used to classify the rock along with any accessory minerals. In ore deposit geology, hypogene processes occur deep below the Earth's surface, and tend to form deposits of primary minerals, as opposed to supergene processes that occur at or near the surface, and tend to form secondary minerals.

Hydrothermal mineral deposits are accumulations of valuable minerals which formed from hot waters circulating in Earth's crust through fractures. They eventually produce metallic-rich fluids concentrated in a selected volume of rock, which become supersaturated and then precipitate ore minerals. In some occurrences, minerals can be extracted for a profit by mining. Discovery of mineral deposits consumes considerable time and resources and only about one in every one thousand prospects explored by companies are eventually developed into a mine. A mineral deposit is any geologically significant concentration of an economically useful rock or mineral present in a specified area. The presence of a known but unexploited mineral deposit implies a lack of evidence for profitable extraction.

References

  1. Rakovan, John (November–December 2003). "A Word to the Wise: Hypogene & Supergene" (PDF). Rocks & Minerals. 78 (6). Taylor & Francis: 419. Bibcode:2003RoMin..78..419R. doi:10.1080/00357529.2003.9926759. S2CID   128609800 . Retrieved August 18, 2012.
  2. 1 2 The Encyclopedia of Gemstones and Minerals (1991). Martin Holden. Publisher: Facts on File
  3. 1 2 Understanding Mineral Deposits (2000). Kula C Misra. Kluwer Academic Publishers