Isinuka Mud Caves and Sulphur Pools

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Isinuka Mud Caves and Sulphur Pools
Map of the Eastern Cape with Port St Johns highlighted (2016).svg
Map of the Eastern Cape with Port St Johns highlighted
LocationIsinuka village in Port St. Johns OR Tambo District Municipality
Region Eastern Cape, South Africa
Coordinates 31°36′29.38″S29°28′53.87″E / 31.6081611°S 29.4816306°E / -31.6081611; 29.4816306 Coordinates: 31°36′29.38″S29°28′53.87″E / 31.6081611°S 29.4816306°E / -31.6081611; 29.4816306
History
Materialmud, clay
Cultures Pondo people, Xhosa people
Forest of Port St John's where the Isinuka caves and Springs are situated Typical Port St. Johns flora.JPG
Forest of Port St John's where the Isinuka caves and Springs are situated

The Isinuka Mud Caves and Sulphur Pools are located next to the Isinuka village which is located in OR Tambo District Municipality, Eastern Cape, South Africa. The name "Isinuka", means "place of smell", which refers to the odour of the sulfur which diffuses from the springs. This name was given by the Mpondo people of the Eastern Cape who regard this site as a sacred area. The springs are also visited by thousands of tourists who seek relief from various ailments yearly. [1]

Contents

Uses

The white soil clay from the springs is used for cosmetic and dermatological applications by the people of Isinuka, Port St Johns and the surrounding towns in Pondoland of the Eastern Cape province. The presence of sulfur, copper and zinc may play a significant role in their antibacterial and antifungal properties. The clays are particularly used by local women to protect their skin from the ultra violet rays. The presence of zinc oxide and TiO2 are likely responsible for protection against the sun. The minor presence of arsenic also aids in healing properties however, arsenic is a human carcinogen and may be extremely toxic at high concentrations.

Description

The springs are located in a densely forested region a few kilometers from Port St John's. In order to reach the pure spring water, the people need to climb large rocks and use a strong fig tree as an improvised staircase. [2] The Isinuka cave is below a rock outcrop and water drips from the roof of the cave onto a slippery white clayey sedimentary material which is the material used for the treatment of skin diseases such as acne. The most popular pond like spring (which is about 3 square meters) is located above the rock outcrop. The spring emits a foul smelling hydrogen sulfide odor. The water is turbid and dark grey in colour. [1]

Mineralogical and biochemical properties

Analytical sample studies have been done using X-ray diffraction techniques.

The pH range of samples range between 7.94 and 10.05 which indicates alkaline clay. The pH of normal human skin ranges between 5.4 and 5.9, this variability brings into the question the viability of using these clays to treat acne as highly alkaline substances often have an adverse effect on the skin when applied without premedication or neutralization. Additionally, Cutibacterium acnes , bacteria which play a role in the development of acne, thrives on skin with high alkalinity.[ citation needed ] Therefore, the continuous application of alkaline clay on skin will increase the skin pH resulting in the development of acne. The local people often mix these clay materials with other plant and animal extracts in order to make the clay suitable for application to the skin.

The particle sizes vary between silt, loam and silt loam. Large particle sizes when used cosmetically, may cause abrasion and damage to the skin. The smaller particles have a large potential to be used as a cleanser. The clays and soils particle size influences the refractive index (light) which allows for them to be used a s skin protectors.

There are 17 minerals identified in Isinuku clay namely quartz (SiO2), mica, calcite (CaCO3), interstratified illite (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], aragonite (CaCO3), gypsum CaSO4.2(H2O), rozenite Fe2+SO4.4(H2O), K-feldspar (KAlSi3O8), plagioclase (Na,Ca)(Si,Al)4O8), kaolinite (Al2SiO5(OH)4), chlorite, halite (NaCl), pyrite (FeS2), pyrophyllite (Al2Ai4O10(OH)2), spinel (MgAl2O4) and smectite (NaO3(Al,Mg)2SiO10(OH)2·H2O). The three dominant mineral phases are quartz, mica and calcite followed by interstratified illite and smectite. The alkaline nature of the clay can be attributed to calcite. Quartz, mica and illite are very stable substances however, due to their particle size, can cause abrasions when applied topically. Illite is applied topically and orally.

The use of sulfur in various skin preparations in the field of dermatology due to sulfur's antifungal, antibacterial and keratolytic properties. The sulfur content in the springs ranges from 0.8% to 1.3%. Furthermore the continued saturation of the sulfur containing clay with the saline water which drips from the roof of the cave results in an improvement medicinal properties of the clay. The clay also has components which include bromide and arsenic, the latter was used to treat syphilis, yaws and other bacterial infections before the development of penicillin. Other trace elements found include cobalt, chromium, copper, zinc, uranium and radioactive strontium. [1]

Although the clay may be useful for therapeutic and cosmetic purposes, the clay may also constitute a health risk resulting from repeated and unsupervised exposure. There are however, no toxicological studies yet done to identify appropriate beneficial methods to make the clay safer to use. [3]

Traditional beliefs

The sulfur is used to cure stomach and skin ailments. The thick mud and bubbling water is believed to contain chemicals which are capable of curing all ailments. The people of Isinuka and surrounding villages believe that the clay is a gift which has been passed down from their ancestors therefore the cessation of the use of the water and clay from the springs is unlikely. [4]

See also

Related Research Articles

Mineral Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

Silicon dioxide Oxide of silicon

Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO2, most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics, and as components in the food and pharmaceutical industries.

Shale Fine-grained, clastic sedimentary rock

Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals and tiny fragments of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.

Bentonite Smectite clay consisting mostly of montmorillonite

Bentonite is an absorbent swelling clay consisting mostly of montmorillonite which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite.

The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al2O3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. The aluminium oxide must be purified before it can be refined to aluminium metal.

Garnierite Nickel layer silicate

Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the world. It is an important nickel ore, having a large weight percent NiO. As garnierite is not a valid mineral name according to the Commission on New Minerals, Nomenclature and Classification (CNMNC), no definite composition or formula has been universally adopted. Some of the proposed compositions are all hydrous Ni-Mg silicates, a general name for the Ni-Mg hydrosilicates which usually occur as an intimate mixture and commonly includes two or more of the following minerals: serpentine, talc, sepiolite, smectite, or chlorite, and Ni-Mg silicates, with or without alumina, that have x-ray diffraction patterns typical of serpentine, talc, sepiolite, chlorite, vermiculite or some mixture of them all.

Clay mineral Fine-grained aluminium phyllosilicates

Clay minerals are hydrous aluminium phyllosilicates, sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces.

Silicate mineral Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

Chlorite group Type of mineral

The chlorites are a group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

Montmorillonite Member of the smectite group of swelling 2:1 clay mineral

Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm; magnification of about 25,000 times, using an electron microscope, is required to "see" individual clay particles. Members of this group include, amongst others, saponite, nontronite, beidellite, and hectorite.

Illite Group of related non-expanding clay minerals

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Smectite Swelling 2:1 (TOT) phyllosilicates

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Fault gouge Small grain size infilling material in fault mainly consisting of clay minerals

Fault gouge is a tectonite with a very small grain size. Fault gouge has no cohesion and it is normally an unconsolidated rock type, unless cementation took place at a later stage. A fault gouge forms in the same way as fault breccia, the latter also having larger clasts. In comparison to fault breccia, which is another incohesive fault rock, fault gouge has a lower volume-fraction of visible fragments. Fault gouge is also classified as have particles that are smaller than 1mm in diameter. Therefore, fault gouge is commonly composed of clay minerals which commonly consist of illite, smectite, kaolinite, chlorite, sometimes vermiculite, along with unaltered detritic minerals produced by granite and gneiss erosion .. Here, TOT and TO respectively refer to the two more common layered crystal structures of clay minerals, where T represents the tetrahedral silica sheets and O the octahedral gibbsite sheets.

Iberulite

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Illite crystallinity

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References

  1. 1 2 3 Jumbam, Ndze Denis (June 2012). "Demographic characteristics associated with Isinuka Traditional Spa near Port St Johns in the Eastern Cape Province of South Africa". Indilinga African Journal of Indigenous Knowledge Systems. 11 (1): 20–31.
  2. "Isinuka Springs Information | WhereToStay.co.za". www.wheretostay.co.za. Retrieved 24 September 2018.
  3. Jumbam, Ndze Denis (January 15, 2013). "Mineralogical and geochemical analyses of the healing elements in clayey soils from Isinuka traditional spa in Port St Johns, South Africa". Transactions of the Royal Society of South Africa. 68 (1): 25–31. doi:10.1080/0035919X.2012.756075. S2CID   129076346.
  4. Piliso, Simpiwe (November 13, 1999). "Kei's miracle health spa is a mud bath" . Retrieved December 24, 2020.