James R. Heath (born 1962) is an American chemist and the president and professor of Institute of Systems Biology. [1] Previous to this, he was the Elizabeth W. Gilloon Professor of Chemistry at the California Institute of Technology, after having moved from University of California Los Angeles. [2]
Heath graduated with a degree in Chemistry in 1984 from Baylor University in Texas where he was an active member of the NoZe Brotherhood. He completed his Ph.D. in Physics and Chemistry from Rice University in 1988. [2]
From 1988 to 1991, he was a Miller Research Fellow at the Department of Chemistry, University of California, Berkeley. From 1991 to 1994, he was a Research Staff Member at IBM T.J. Watson Research Laboratory in Yorktown, New York. [3] He joined the faculty at UCLA in 1994 and became Professor of Chemistry in 1997. He founded the California NanoSystems Institute in 2000 and served as its Director until moving to become the Elizabeth W. Gilloon Professor of Chemistry at Caltech.
Heath's academic work has focused on quantum phase transitions and developed architectures, devices, and circuits for molecular electronics. More recently, his work has moved towards applying expertise in nanoscale and molecular systems to addressing problems in cancer and infectious diseases.
When Heath was a graduate student at Rice University, he ran the experimental apparatus that generated the first C60 molecules and, ultimately, won the Nobel Prize in Chemistry for the three senior members of the collaboration: Robert F. Curl and Richard E. Smalley of Rice University and Harold Kroto of the University of Sussex. This research is significant for the discovery of a new allotrope of carbon known as a fullerene. Other allotropes of carbon include graphite, diamond and graphene. James R. Heath's 1985 paper entitled "C60: Buckminsterfullerine", published with colleagues Harry Kroto, S. C. O’Brien, R. F. Curl, and R. E. Smalley, was honored by a Citation for Chemical Breakthrough Award from the Division of History of Chemistry of the American Chemical Society, presented to Rice University in 2015. [4] [5] [6] The discovery of fullerenes was recognized in 2010 by the designation of a National Historic Chemical Landmark by the American Chemical Society at the Richard E. Smalley Institute for Nanoscale Science and Technology at Rice University in Houston, Texas. [7]
Heath is known for publishing an architecture demonstration of molecular computers, or moletronics. In moletronics, single molecules serve as switches, "quantum wires" a few atoms thick serve as wiring, and the hardware is synthesized chemically from the bottom up. It was published in the summer of 1999 by Heath, J. Fraser Stoddart (at the time at UCLA) and their collaborators in the journal Science . [8]
As of 2011, Heath's research has split into one area devoted to solid-state quantum physics, materials science, and surface science, with a slight focus on energy conversion and another working on applying synthetic chemistry and a systems perspective to fundamental biology and translational medicine - with a clear focus on oncology.
Heath has received several awards and honours for his research. [9] He was awarded the 2000 Feynman Prize in Nanotechnology. He became a fellow of American Physical Society in 1999. [10] In 2009, Heath was named one of the seven most powerful innovators of the world by Forbes magazine. [11]
A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to seven atoms. The molecules may have hollow sphere- and ellipsoid-like forms, tubes, or other shapes.
Sir Harold Walter Kroto was an English chemist. He shared the 1996 Nobel Prize in Chemistry with Robert Curl and Richard Smalley for their discovery of fullerenes. He was the recipient of many other honors and awards.
Nanotechnology was defined by the National Nanotechnology Initiative as the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). At this scale, commonly known as the nanoscale, surface area and quantum mechanical effects become important in describing properties of matter. The definition of nanotechnology is inclusive of all types of research and technologies that deal with these special properties. It is therefore common to see the plural form "nanotechnologies" as well as "nanoscale technologies" to refer to the broad range of research and applications whose common trait is size. An earlier description of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabrication of macroscale products, also now referred to as molecular nanotechnology.
Richard Errett Smalley was an American chemist who was the Gene and Norman Hackerman Professor of Chemistry, Physics, and Astronomy at Rice University. In 1996, along with Robert Curl, also a professor of chemistry at Rice, and Harold Kroto, a professor at the University of Sussex, he was awarded the Nobel Prize in Chemistry for the discovery of a new form of carbon, buckminsterfullerene, also known as buckyballs. He was an advocate of nanotechnology and its applications.
Robert Floyd Curl Jr. was an American chemist who was Pitzer–Schlumberger Professor of Natural Sciences and professor of chemistry at Rice University. He was awarded the Nobel Prize in Chemistry in 1996 for the discovery of the nanomaterial buckminsterfullerene, and hence the fullerene class of materials, along with Richard Smalley and Harold Kroto of the University of Sussex.
Buckminsterfullerene is a type of fullerene with the formula C60. It has a cage-like fused-ring structure (truncated icosahedron) made of twenty hexagons and twelve pentagons, and resembles a football. Each of its 60 carbon atoms is bonded to its three neighbors.
The year 1985 in science and technology involved many significant events, listed below.
Endohedral fullerenes, also called endofullerenes, are fullerenes that have additional atoms, ions, or clusters enclosed within their inner spheres. The first lanthanum C60 complex called La@C60 was synthesized in 1985. The @ (at sign) in the name reflects the notion of a small molecule trapped inside a shell. Two types of endohedral complexes exist: endohedral metallofullerenes and non-metal doped fullerenes.
Fullerene chemistry is a field of organic chemistry devoted to the chemical properties of fullerenes. Research in this field is driven by the need to functionalize fullerenes and tune their properties. For example, fullerene is notoriously insoluble and adding a suitable group can enhance solubility. By adding a polymerizable group, a fullerene polymer can be obtained. Functionalized fullerenes are divided into two classes: exohedral fullerenes with substituents outside the cage and endohedral fullerenes with trapped molecules inside the cage.
The history of nanotechnology traces the development of the concepts and experimental work falling under the broad category of nanotechnology. Although nanotechnology is a relatively recent development in scientific research, the development of its central concepts happened over a longer period of time. The emergence of nanotechnology in the 1980s was caused by the convergence of experimental advances such as the invention of the scanning tunneling microscope in 1981 and the discovery of fullerenes in 1985, with the elucidation and popularization of a conceptual framework for the goals of nanotechnology beginning with the 1986 publication of the book Engines of Creation. The field was subject to growing public awareness and controversy in the early 2000s, with prominent debates about both its potential implications as well as the feasibility of the applications envisioned by advocates of molecular nanotechnology, and with governments moving to promote and fund research into nanotechnology. The early 2000s also saw the beginnings of commercial applications of nanotechnology, although these were limited to bulk applications of nanomaterials rather than the transformative applications envisioned by the field.
The following outline is provided as an overview of and topical guide to nanotechnology:
Molecular scale electronics, also called single-molecule electronics, is a branch of nanotechnology that uses single molecules, or nanoscale collections of single molecules, as electronic components. Because single molecules constitute the smallest stable structures imaginable, this miniaturization is the ultimate goal for shrinking electrical circuits.
Eiji Osawa (Japanese: 大澤 映二, Hepburn: Ōsawa Eiji, born June 9, 1935 in Toyama, Japan) is a former professor of computational chemistry, noted for his prediction of the C60 molecule in 1970.
Carbocatalysis is a form of catalysis that uses heterogeneous carbon materials for the transformation or synthesis of organic or inorganic substrates. The catalysts are characterized by their high surface areas, surface functionality, and large, aromatic basal planes. Carbocatalysis can be distinguishable from supported catalysis in that no metal is present, or if metals are present they are not the active species.
The Drexler–Smalley debate on molecular nanotechnology was a public dispute between K. Eric Drexler, the originator of the conceptual basis of molecular nanotechnology, and Richard Smalley, a recipient of the 1996 Nobel prize in Chemistry for the discovery of the nanomaterial buckminsterfullerene. The dispute was about the feasibility of constructing molecular assemblers, which are molecular machines which could robotically assemble molecular materials and devices by manipulating individual atoms or molecules. The concept of molecular assemblers was central to Drexler's conception of molecular nanotechnology, but Smalley argued that fundamental physical principles would prevent them from ever being possible. The two also traded accusations that the other's conception of nanotechnology was harmful to public perception of the field and threatened continued public support for nanotechnology research.
C70 fullerene is the fullerene molecule consisting of 70 carbon atoms. It is a cage-like fused-ring structure which resembles a rugby ball, made of 25 hexagons and 12 pentagons, with a carbon atom at the vertices of each polygon and a bond along each polygon edge. A related fullerene molecule, named buckminsterfullerene (or C60 fullerene) consists of 60 carbon atoms.
Azafullerenes are a class of heterofullerenes in which the element substituting for carbon is nitrogen. They can be in the form of a hollow sphere, ellipsoid, tube, and many other shapes. Spherical azafullerenes resemble the balls used in football (soccer). They are also a member of the carbon nitride class of materials that include beta carbon nitride (β-C3N4), predicted to be harder than diamond. Besides the pioneering work of a couple of academic groups, this class of compounds has so far garnered little attention from the broader fullerene research community. Many properties and structures are yet to be discovered for the highly-nitrogen substituted subset of molecules.
Konstantinos Fostiropoulos is a Greek physicist who has been working in Germany in the areas nano-materials, solid-state physics, molecular physics, astrophysics, and thermodynamics. From 2003 to 2016 he has been founder and head of the Organic Solar Cells Group at the Institute Heterogeneous Materials Systems within the Helmholtz-Zentrum Berlin. His scientific works include novel energy materials and photovoltaic device concepts, carbon clusters in the Interstellar Medium, and intermolecular forces of real gases.
The Carbon Medal is a medal of achievement in carbon science and technology given by the American Carbon Society for the "... outstanding contributions to the discovery of novel carbon products or processes."
Dirk M. Guldi is a German chemist, academic, and author. He is an adjunct professor at Xi'an University of Science and Technology and Huazhong University of Science and Technology, a partner investigator at the Intelligent Polymer Research Institute at the University of Wollongong, as well as a full professor at Friedrich-Alexander-University Erlangen-Nürnberg.
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