Jillian Lee Dempsey

Last updated
Jillian Lee Dempsey
Jillian Dempsey.jpg
Alma mater MIT (S.B.) (2005) [1]
Caltech (Ph.D.) (2010) [1]
SpouseAlex J. M. Miller
Scientific career
Fields Inorganic Chemistry, Photochemistry, Electrochemistry
Institutions University of North Carolina at Chapel Hill
Thesis Hydrogen evolution catalyzed by cobaloximes  (2010)
Doctoral advisor Harry B. Gray
Other academic advisors Daniel G. Nocera, Daniel R. Gamelin
Website chem.unc.edu/faculty/dempsey-jillian/

Jillian Lee Dempsey is an American inorganic chemist and the Bowman and Gordon Gray Distinguished Term Professor at the University of North Carolina at Chapel Hill. Currently, her work focuses on proton-coupled electron transfer, charge transfer events, and quantum dots. [2] She is the recipient of numerous awards for rising stars of chemistry, including most recently a 2016 Alfred P. Sloan Research Fellowship [3] and a 2016 Air Force's Young Investigator Research Program (YIP). [4]

Contents

Education and training

Dempsey attended the Massachusetts Institute of Technology for her undergraduate, earning her S.B. in Chemistry in 2005. She worked with Prof. Daniel G. Nocera on the development of molecular water splitting catalysts. [5] [6] While at MIT, she also worked at Merck Research Laboratories' Department of Analytical Research, on the development of HPLC columns for pharmaceutical process development. [7] Dempsey then travelled to the California Institute of Technology for graduate studies, where she worked in the laboratory of Prof. Harry B. Gray and Jay R. Winkler. [8] [9] Dempsey's research at Caltech focused on elucidating the mechanism of hydrogen evolution for cobaloxime catalysts, [10] [11] as well as the reactivity of photogenerated osmium(II) complexes. [12] She graduated with her Ph.D. in 2011.

From 2011 to 2012, Dempsey then conducted postdoctoral research as an NSF American Competitiveness in Chemistry Fellow in the laboratory of Daniel R. Gamelin at the University of Washington. [13] There, she worked on photoconductive quantum dot thin films, [14] as well as magnetic coupling in illuminated quantum dots. [15]

Independent career

Dempsey began her independent career at the University of North Carolina at Chapel Hill in 2012 as an assistant professor. She was granted tenure in 2018 and promoted to the rank of associate professor. Since 2020, she has served as the Bowman and Gordon Gray Distinguished Term Professor.

Awards

Related Research Articles

<span class="mw-page-title-main">Covalent bond</span> Chemical bond by sharing of electron pairs

A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding. For many molecules, the sharing of electrons allows each atom to attain the equivalent of a full valence shell, corresponding to a stable electronic configuration. In organic chemistry, covalent bonding is much more common than ionic bonding.

In chemistry, a superatom is any cluster of atoms that seem to exhibit some of the properties of elemental atoms.

<span class="mw-page-title-main">Cadmium selenide</span> Chemical compound

Cadmium selenide is an inorganic compound with the formula CdSe. It is a black to red-black solid that is classified as a II-VI semiconductor of the n-type. It is a pigment but applications are declining because of environmental concerns

Car–Parrinello molecular dynamics or CPMD refers to either a method used in molecular dynamics or the computational chemistry software package used to implement this method.

<span class="mw-page-title-main">Molecular sensor</span>

A molecular sensor or chemosensor is a molecular structure that is used for sensing of an analyte to produce a detectable change or a signal. The action of a chemosensor, relies on an interaction occurring at the molecular level, usually involves the continuous monitoring of the activity of a chemical species in a given matrix such as solution, air, blood, tissue, waste effluents, drinking water, etc. The application of chemosensors is referred to as chemosensing, which is a form of molecular recognition. All chemosensors are designed to contain a signalling moiety and a recognition moiety, that is connected either directly to each other or through a some kind of connector or a spacer. The signalling is often optically based electromagnetic radiation, giving rise to changes in either the ultraviolet and visible absorption or the emission properties of the sensors. Chemosensors may also be electrochemically based. Small molecule sensors are related to chemosensors. These are traditionally, however, considered as being structurally simple molecules and reflect the need to form chelating molecules for complexing ions in analytical chemistry. Chemosensors are synthetic analogues of biosensors, the difference being that biosensors incorporate biological receptors such as antibodies, aptamers or large biopolymers.

<span class="mw-page-title-main">Harry B. Gray</span> American inorganic chemist

Harry Barkus Gray is the Arnold O. Beckman Professor of Chemistry at California Institute of Technology.

Quantum biology is the study of applications of quantum mechanics and theoretical chemistry to aspects of biology that cannot be accurately described by the classical laws of physics. An understanding of fundamental quantum interactions is important because they determine the properties of the next level of organization in biological systems.

<span class="mw-page-title-main">Louis E. Brus</span> American chemist

Louis Edward Brus is an American chemist, and currently the Samuel Latham Mitchell Professor of Chemistry at Columbia University. He is the co-discoverer of the colloidal semi-conductor nanocrystals known as quantum dots. In 2023, he was awarded the Nobel Prize in Chemistry.

<span class="mw-page-title-main">Daniel G. Nocera</span> American chemist

Daniel George Nocera is an American chemist, currently the Patterson Rockwood Professor of Energy in the Department of Chemistry and Chemical Biology at Harvard University. He is a member of the National Academy of Sciences and the American Academy of Arts and Sciences. In 2006 he was described as a "major force in the field of inorganic photochemistry and photophysics". Time magazine included him in its 2009 list of the 100 most influential people.

Michelle C. Y. Chang is a Professor of Chemistry and Chemical and Biomolecular Engineering at the University of California, Berkeley, and is a recipient of several young scientist awards for her research in biosynthesis of biofuels and pharmaceuticals.

Christopher J. Chang is a professor of chemistry and of molecular and cell biology at the University of California, Berkeley, where he holds the Class of 1942 Chair. Chang is also a member of the Helen Wills Neuroscience Institute, a Howard Hughes Medical Institute investigator, adjunct professor of pharmaceutical chemistry at the University of California, San Francisco, and faculty scientist at the chemical sciences division of Lawrence Berkeley Lab. He is the recipient of several awards for his research in bioinorganic chemistry, molecular and chemical biology.

Sharon Hammes-Schiffer is a physical chemist who has contributed to theoretical and computational chemistry. She is currently a Sterling Professor of Chemistry at Yale University. She has served as senior editor and deputy editor of the Journal of Physical Chemistry and advisory editor for Theoretical Chemistry Accounts. As of 1 January 2015 she is editor-in-chief of Chemical Reviews.

<span class="mw-page-title-main">Water oxidation catalysis</span>

Water oxidation catalysis (WOC) is the acceleration (catalysis) of the conversion of water into oxygen and protons:

Jenny Yue-fon Yang is an American chemist. She is a Professor of chemistry at the University of California, Irvine where she leads a research group focused on inorganic chemistry, catalysis, and solar fuels.

<span class="mw-page-title-main">Brandi Cossairt</span> American chemist (b. 1984)

Brandi Michelle Cossairt is an American chemist specializing in synthetic inorganic and materials chemistry. She is the Lloyd E. and Florence M. West Endowed Professor of Chemistry at University of Washington.

Sandra J. Rosenthal is the Jack and Pamela Egan Professor of Chemistry, professor of physics and astronomy, pharmacology, chemical and biomolecular engineering, and materials science at Vanderbilt University. She is a joint faculty member at Oak Ridge National Laboratory in the Materials Science and Technology Division and the director of the Vanderbilt Institute of Nanoscale Science and Engineering.

David Nathan Beratan is an American chemist and physicist, the R.J. Reynolds Professor of Chemistry at Duke University. He has secondary appointments in the departments of Physics and Biochemistry. He is the director of the Center for Synthesizing Quantum Coherence, a NSF Phase I Center for Chemical Innovation.

Daniel Kwabena Dakwa Bediako is a Ghanaian-British chemist. He is currently assistant professor at the University of California, Berkeley, and is the Cupola Era Professor in the college of chemistry. His research considers charge transport and interfacial charge transfer in two-dimensional materials and heterostructures. He is also a member of the Editorial Advisory Board of the Journal of the American Chemical Society (JACS).

R. David Britt is the Winston Ko Chair and Distinguished Professor of Chemistry at the University of California, Davis. Britt uses electron paramagnetic resonance (EPR) spectroscopy to study metalloenzymes and enzymes containing organic radicals in their active sites. Britt is the recipient of multiple awards for his research, including the Bioinorganic Chemistry Award in 2019 and the Bruker Prize in 2015 from the Royal Society of Chemistry. He has received a Gold Medal from the International EPR Society (2014), and the Zavoisky Award from the Kazan Scientific Center of the Russian Academy of Sciences (2018). He is a Fellow of the American Association for the Advancement of Science and of the Royal Society of Chemistry.

Silicon quantum dots are metal-free biologically compatible quantum dots with photoluminescence emission maxima that are tunable through the visible to near-infrared spectral regions. These quantum dots have unique properties arising from their indirect band gap, including long-lived luminescent excited-states and large Stokes shifts. A variety of disproportionation, pyrolysis, and solution protocols have been used to prepare silicon quantum dots, however it is important to note that some solution-based protocols for preparing luminescent silicon quantum dots actually yield carbon quantum dots instead of the reported silicon. The unique properties of silicon quantum dots lend themselves to an array of potential applications: biological imaging, luminescent solar concentrators, light emitting diodes, sensors, and lithium-ion battery anodes.

References

  1. 1 2 Dempsey, Jillian L.; Winkler, Jay R.; Gray, Harry B. (November 17, 2010). "Proton-Coupled Electron Flow in Protein Redox Machines". Chem. Rev. 110 (12): 7024–7039. doi:10.1021/cr100182b. PMC   3005815 . PMID   21082865.
  2. "Research – Dempsey Group". University of North Carolina. Retrieved 2018-04-26.
  3. 1 2 "Past Fellows". sloan.org. Archived from the original on 2018-03-14. Retrieved 2018-04-26.
  4. 1 2 "Air Force Office of Scientific Research Awards Grants to 56 Scientists and Engineers through Young Investigator Research Program". Defense Acquisition University. 2016-01-14. Archived from the original on 2018-04-27. Retrieved 2018-04-26.
  5. Dempsey, Jillian L.; Esswein, Arthur J.; Manke, David R.; Rosenthal, Joel; Soper, Jake D.; Nocera, Daniel G. (2005-10-01). "Molecular Chemistry of Consequence to Renewable Energy". Inorganic Chemistry. 44 (20): 6879–6892. doi:10.1021/ic0509276. ISSN   0020-1669. PMID   16180843.
  6. Esswein, Arthur J.; Dempsey, Jillian L.; Nocera, Daniel G. (2007-04-01). "A RhII−AuII Bimetallic Core with a Direct Metal−Metal Bond". Inorganic Chemistry. 46 (7): 2362–2364. doi:10.1021/ic062203f. ISSN   0020-1669. PMID   17326627.
  7. Wu, Naijun; Dempsey, Jillian; Yehl, Peter M.; Dovletoglou, Angelos; Ellison, Dean; Wyvratt, Jean (2004-10-11). "Practical aspects of fast HPLC separations for pharmaceutical process development using monolithic columns". Analytica Chimica Acta. 523 (2): 149–156. Bibcode:2004AcAC..523..149W. doi:10.1016/j.aca.2004.07.069. ISSN   0003-2670.
  8. Dempsey, Jillian L.; Winkler, Jay R.; Gray, Harry B. (2010-12-08). "Proton-Coupled Electron Flow in Protein Redox Machines". Chemical Reviews. 110 (12): 7024–7039. doi:10.1021/cr100182b. ISSN   0009-2665. PMC   3005815 . PMID   21082865.
  9. Dempsey, Jillian L.; Brunschwig, Bruce S.; Winkler, Jay R.; Gray, Harry B. (2009-12-21). "Hydrogen Evolution Catalyzed by Cobaloximes". Accounts of Chemical Research. 42 (12): 1995–2004. doi:10.1021/ar900253e. ISSN   0001-4842. PMID   19928840.
  10. Dempsey, Jillian L.; Winkler, Jay R.; Gray, Harry B. (2010-01-27). "Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts". Journal of the American Chemical Society. 132 (3): 1060–1065. doi:10.1021/ja9080259. ISSN   0002-7863. PMID   20043639.
  11. Dempsey, Jillian L.; Winkler, Jay R.; Gray, Harry B. (2010-12-01). "Mechanism of H2 Evolution from a Photogenerated Hydridocobaloxime". Journal of the American Chemical Society. 132 (47): 16774–16776. doi:10.1021/ja109351h. ISSN   0002-7863. PMID   21067158.
  12. Dempsey, Jillian L.; Winkler, Jay R.; Gray, Harry B. (2011-10-05). "Redox reactivity of photogenerated osmium(II) complexes". Dalton Transactions. 40 (40): 10633–10636. doi:10.1039/C1DT11138H. ISSN   1477-9234. PMID   21892445.
  13. "Gamelin Research Group". University of Washington. Archived from the original on 2018-04-27. Retrieved 2018-04-26.
  14. White, Michael A.; Dempsey, Jillian L.; Carroll, Gerard M.; Gallagher, James D.; Gamelin, Daniel R. (2013-09-01). "Photoconductive ZnO films with embedded quantum dot or ruthenium dye sensitizers". APL Materials. 1 (3): 032107. Bibcode:2013APLM....1c2107W. doi: 10.1063/1.4820428 .
  15. Bradshaw, Liam R.; May, Joseph W.; Dempsey, Jillian L.; Li, Xiaosong; Gamelin, Daniel R. (2014-03-19). "Ferromagnetic excited-state Mn${}^{2+}$ dimers in Zn${}_{1\ensuremath{-}x}$MnxSe quantum dots observed by time-resolved magnetophotoluminescence". Physical Review B. 89 (11): 115312. doi:10.1103/PhysRevB.89.115312.
  16. Davenport, Matt (2017-08-15). "Jillian Dempsey – Talented 12". Chemical and Engineering News. Retrieved 2018-04-26.
  17. "2015 Packard Fellowships in Science and Engineering Awarded to Eighteen Researchers". The David and Lucile Packard Foundation. 2015-10-15. Retrieved 2018-04-26.
  18. "Dempsey, Jillian Lee". The David and Lucile Packard Foundation. Retrieved 2018-04-26.
  19. "CAREER: Mechanistic Investigations of Excited-State Proton-Coupled Electron Transfer Reactions". National Science Foundation. Retrieved 2018-04-26.