Joule Unlimited, formerly known as Joule Biotechnologies, [1] was a producer of alternative energy technologies based in Bedford, Massachusetts. The company developed a process to generate hydrocarbon-based fuel by combining non-fresh water, nutrients, cyanobacteria, carbon dioxide, and sunlight. After ten years of operation and building a demonstration plant in New Mexico, the company shut down in August 2017. The company shut down after management was unable to raise money.
The company claimed it would be able to produce more than 20,000 gallons of fuel per acre per year (19,000 m3/km2/annum) [2] in almost refined form using carbon dioxide waste from industrial processes and desert land. [3]
Helioculture uses photosynthetic organisms, but is otherwise distinct from the process that makes fuel from algae. Oils made from algae usually have to be refined into fuel following a batch process, but helioculture secretes fuel directly rather than storing it in their cells - either ethanol or hydrocarbons - that do not need refining. [3] The helioculture process also does not produce biomass. This process is enabled by the discovery of unique genes coding for enzymatic mechanisms that enable the direct synthesis of such key molecules as alkanes, olefins, ethanol [4] and polymers and other high-value chemicals ordinarily derived from petroleum, using bacterial variants. [5] Helioculture allows for brackish water or graywater, nonindustrial waste water from sources such as baths and washing machines, [6] to be used, while traditional biofuels such as cellulosic ethanol require fresh water.
Joule Unlimited claimed that its product would have been cost competitive with crude oil at $50 a barrel ($310/m3). The company also stated that its product could supply all of the transportation fuel for the United States from an area the size of the Texas panhandle. [7]
Joule Unlimited did not reveal the name of the organism that it used, although it acknowledged that the company had modified the organism. [8] In September, 2010, Joule received a patent for genetically altered bacterium. [5]
Joule Unlimited was founded in 2007 within Flagship VentureLabs by Noubar Afeyan and David Berry. In addition to its founders, Joule's Board of Directors included Graham Allison, Anatoly Chubais, Stelios Papadopoulos, Caroline Dorsa, and Ruben Vardanian. [9] Joule's Scientific Advisory Board includes synthetic biologists George M. Church and Jim Collins.
After building a demonstration plant in New Mexico, Joule Unlimited entered into a strategic partnership with Audi in 2012 to accelerate the commercialization of their fuels, ethanol named Sunflow-E and diesel named Sunflow-D. [10] Audi brands them as e-ethanol and e-diesel respectively. [11]
Biofuel is fuel that is produced through contemporary processes from biomass, rather than by the very slow geological processes involved in the formation of fossil fuels, such as oil. Since biomass technically can be used as a fuel directly, some people use the terms biomass and biofuel interchangeably. More often than not, however, the word biomass simply denotes the biological raw material the fuel is made of, or some form of thermally/chemically altered solid end product, like torrefied pellets or briquettes.
Ethanol fuel is ethyl alcohol, the same type of alcohol found in alcoholic beverages, used as fuel. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline. The first production car running entirely on ethanol was the Fiat 147, introduced in 1978 in Brazil by Fiat. Ethanol is commonly made from biomass such as corn or sugarcane. World ethanol production for transport fuel tripled between 2000 and 2007 from 17×109 liters (4.5×109 U.S. gal; 3.7×109 imp gal) to more than 52×109 liters (1.4×1010 U.S. gal; 1.1×1010 imp gal). From 2007 to 2008, the share of ethanol in global gasoline type fuel use increased from 3.7% to 5.4%. In 2011 worldwide ethanol fuel production reached 8.46×1010 liters (2.23×1010 U.S. gal; 1.86×1010 imp gal) with the United States of America and Brazil being the top producers, accounting for 62.2% and 25% of global production, respectively. US ethanol production reached 57.54×109 liters (1.520×1010 U.S. gal; 1.266×1010 imp gal) in 2017–04.
Cellulosic ethanol is ethanol produced from cellulose rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a biofuel. The carbon dioxide that plants absorb as they grow offsets some of the carbon dioxide emitted when ethanol made from them is burned, so cellulosic ethanol fuel has the potential to have a lower carbon footprint than fossil fuels.
Metabolic engineering is the practice of optimizing genetic and regulatory processes within cells to increase the cell's production of a certain substance. These processes are chemical networks that use a series of biochemical reactions and enzymes that allow cells to convert raw materials into molecules necessary for the cell's survival. Metabolic engineering specifically seeks to mathematically model these networks, calculate a yield of useful products, and pin point parts of the network that constrain the production of these products. Genetic engineering techniques can then be used to modify the network in order to relieve these constraints. Once again this modified network can be modeled to calculate the new product yield.
Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines. The general chemical formula for alcohol fuel is CnH2n+1OH.
The bioconversion of biomass to mixed alcohol fuels can be accomplished using the MixAlco process. Through bioconversion of biomass to a mixed alcohol fuel, more energy from the biomass will end up as liquid fuels than in converting biomass to ethanol by yeast fermentation.
Butanol may be used as a fuel in an internal combustion engine. It is more similar to gasoline than it is to ethanol. A C4-hydrocarbon, butanol is a drop-in fuel and thus works in vehicles designed for use with gasoline without modification. Both n-butanol and isobutanol have been studied as possible fuels. Both can be produced from biomass as well as from fossil fuels. The chemical properties.depend on the isotope, not on the production method.
Renewable fuels are fuels produced from renewable resources. Examples include: biofuels and Hydrogen fuel. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.
Corn ethanol is ethanol produced from corn biomass and is the main source of ethanol fuel in the United States. Corn ethanol is produced by ethanol fermentation and distillation. It is debatable whether the production and use of corn ethanol results in lower greenhouse gas emissions than gasoline. Approximately 25% of U.S. corn croplands are used for ethanol production.
Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.
Algae fuel, algal biofuel, or algal oil is an alternative to liquid fossil fuels that uses algae as its source of energy-rich oils. Also, algae fuels are an alternative to commonly known biofuel sources, such as corn and sugarcane. When made from seaweed (macroalgae) it can be known as seaweed fuel or seaweed oil.
Syngas fermentation, also known as synthesis gas fermentation, is a microbial process. In this process, a mixture of hydrogen, carbon monoxide, and carbon dioxide, known as syngas, is used as carbon and energy sources, and then converted into fuel and chemicals by microorganisms.
LS-9 Inc was a venture-funded company focused on producing diesel fuel from transgenic organisms. It launched in 2005, took in $81 million in investment, and in 2013 was sold to Renewable Energy Group for $40 million in cash and stock, and an additional $21.5 million if technology and production milestones were met.
Algenol, founded in 2006, headquartered in Fort Myers, Florida, Algenol is an industrial biotechnology company that is commercializing patented algae technology for production of ethanol and other fuels. The technology enables the production of the four most important fuels using a proprietary process involving algae, sunlight, carbon dioxide and salt water.
Gevo, Inc. is a renewable chemicals and advanced biofuels company headquartered in unincorporated Douglas County, Colorado in the Denver-Aurora metropolitan area. Gevo is focused on sustainability, using the business model based on the Circular Economy to incorporate renewable energy from a range of sources, de-fossilization of its processes, regenerative agriculture, sequestration of carbon in the soil, systemwide efficiency, and conservation of resources to enhance all of its products. The company develops bio-based alternatives to petroleum-based products using a combination of biotechnology and classical chemistry. Gevo uses the GREET model from Argonne National Laboratory as a basis for its measure of sustainability with the goal of producing high-protein animal feed, corn-oil products, energy-dense liquid hydrocarbons, from every kernel of corn. Gevo is focused on converting sustainably grown raw materials, specifically no. 2 dent corn, into high-value protein and isobutanol, the primary building block for its renewable hydrocarbons, including sustainable aviation fuel, renewable gasoline, and renewable diesel. Gevo believes these fuels can be directly integrated on a “drop in” basis into existing fuel and chemical products. Gevo's investors include Burrill & Company, Khosla Ventures, Lanxess, Osage University Partners, Total, and Virgin Green Fund, among others.
Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO2) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped into synthetic fuels, which are made by chemically hydrogenating carbon dioxide, and biofuels, which are produced using natural CO2-consuming processes like photosynthesis.
E-diesel is a synthetic diesel fuel created by Audi for use in automobiles. Currently, e-diesel is created by an Audi research facility in partnership with a company named Sunfire. The fuel is created from carbon dioxide, water, and electricity with a process powered by renewable energy sources to create a liquid energy carrier called blue crude which is then refined to generate e-diesel. E-diesel is considered to be a carbon-neutral fuel as it does not extract new carbon and the energy sources to drive the process are from carbon-neutral sources. As of April 2015, an Audi A8 driven by Federal Minister of Education and Research in Germany is using the e-diesel fuel.
Cellulosic sugars are derived from non-food biomass (e.g. wood, agricultural residues, municipal solid waste). The biomass is primarily composed of carbohydrate polymers cellulose, hemicellulose, and an aromatic polymer (lignin). The hemicellulose is a polymer of mainly five-carbon sugars C5H10O5 (xylose). and the cellulose is a polymer of six-carbon sugar C6H12O6 (glucose). Cellulose fibers are considered to be a plant’s structural building blocks and are tightly bound to lignin, but the biomass can be deconstructed using Acid hydrolysis, enzymatic hydrolysis, organosolv dissolution, autohydrolysis or supercritical hydrolysis.
Carbon capture and utilization (CCU) is the process of capturing carbon dioxide (CO2) to be recycled for further usage. Carbon capture and utilization may offer a response to the global challenge of significantly reducing greenhouse gas emissions from major stationary (industrial) emitters. CCU differs from Carbon Capture and Storage (CCS) in that CCU does not aim nor result in permanent geological storage of carbon dioxide. Instead, CCU aims to convert the captured carbon dioxide into more valuable substances or products; such as plastics, concrete or biofuel; while retaining the carbon neutrality of the production processes.