Microcrystalline waxes are a type of wax produced by de-oiling petrolatum, as part of the petroleum refining process. In contrast to the more familiar paraffin wax which contains mostly unbranched alkanes, microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. [1] It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes, and has a higher molecular weight and melting point. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in cosmetic formulations. [2]
Microcrystalline waxes when produced by wax refiners are typically produced to meet a number of ASTM specifications. These include congeal point (ASTM D938), needle penetration (ASTM D1321), color (ASTM D6045), and viscosity (ASTM D445). Microcrystalline waxes can generally be put into two categories: "laminating" grades and "hardening" grades. The laminating grades typically have a melting point of 140–175 F (60 – 80 °C) and needle penetration of 25 or above. The hardening grades will range from about 175–200 F (80 – 93 °C), and have a needle penetration of 25 or below. Color in both grades can range from brown to white, depending on the degree of processing done at the refinery level.
Microcrystalline waxes are derived from the refining of the heavy distillates from lubricant oil production. This by-product must then be de-oiled at a wax refinery. Depending on the end use and desired specification, the product may then have its odor removed and color removed (which typically starts as a brown or dark yellow). This is usually done by means of a filtration method or by hydro-treating the wax material.
Microcrystalline wax is often used in industries such as tire and rubber, candles, adhesives, corrugated board, cosmetics, castings, and others. Refineries may use blending facilities to combine paraffin and microcrystalline waxes; this is prevalent in the tire and rubber industries.
Microcrystalline waxes have considerable application in the custom making of jewelry and small sculptures. Different formulations produce waxes from those soft enough to be molded by hand to those hard enough to be carved with rotary tools. The melted wax can be cast to make multiple copies that are further carved with details. Jewelry suppliers sell wax molded into the basic forms of rings as well as details that can be heat welded together and tubes and sheets for cutting and building the wax models. Rings may be attached to a wax "tree" so that many can be cast in one pouring.
A brand of microcrystalline wax, Renaissance Wax, is also used extensively in museum and conservation settings for protection and polishing of antique woods, ivory, gemstones, and metal objects. It was developed by The British Museum in the 1950s to replace the potentially unstable natural waxes that were previously used such as beeswax and carnauba.
Microcrystalline waxes are excellent materials to use when modifying the crystalline properties of paraffin wax. The microcrystalline wax has significantly more branching of the carbon chains that are the backbone of paraffin wax. This is useful when some desired functional changes in the paraffin are needed, such as flexibility, higher melt point, and increased opacity. They are also used as slip agents in printing ink.
Microcrystalline wax is used in such sports as ice hockey, skiing and snowboarding. It is applied to the friction tape of an ice hockey stick to prevent degradation of the tape due to water destroying the glue on the tape and also to increase control of the hockey puck due to the wax’s adhesive quality. It is also applied to the underside of skis and snowboards as glide wax to reduce friction and increase the gliding ability of the board, making it easier to control; stickier grades of kick or grip wax are also used on cross-country skis to allow the ski to alternately grip the snow and slip across it as the skier shifts their weight while striding.
Microcrystalline wax was used in the final phases of the restoration of the Cosmatesque pavement, Westminster Abbey, London.
Microcrystalline wax is also a key component in the manufacture of petrolatum. The branched structure of the carbon chain backbone allows oil molecules to be incorporated into the crystal lattice structure. The desired properties of the petrolatum can be modified by using microcrystalline wax bases of different congeal points (ASTM D938) and needle penetration (ASTM D1321).
However, key industries that utilize petrolatum, such as the personal care, cosmetic, and candle industries, have pushed for more materials that are considered "green" and based on renewable resources. As an alternative, hybrid petrolatum can be used. Hybrid petrolatum utilizes a complex mixture of vegetable oils and waxes and combines them with petroleum and micro wax-based technologies. This allows a formulator to incorporate higher percentages of renewable resources while maintaining the beneficial properties of the petrolatum.
In organic chemistry, an alkane, or paraffin, is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula CnH2n+2. The alkanes range in complexity from the simplest case of methane, where n = 1, to arbitrarily large and complex molecules, like pentacontane or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane.
Kerosene, or paraffin, is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from κηρός (kērós) meaning "wax", and was registered as a trademark by Nova Scotia geologist and inventor Abraham Gesner in 1854 before evolving into a generic trademark. It is sometimes spelled kerosine in scientific and industrial usage.
Paraffin wax is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to melt above approximately 37 °C (99 °F), and its boiling point is above 370 °C (698 °F). Common applications for paraffin wax include lubrication, electrical insulation, and candles; dyed paraffin wax can be made into crayons.
Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C (104 °F), melting to give low viscosity liquids. Waxes are insoluble in water but soluble in nonpolar organic solvents such as hexane, benzene and chloroform. Natural waxes of different types are produced by plants and animals and occur in petroleum.
Corrugated fiberboard, corrugated cardboard, or corrugated is a type of packaging material consisting of a fluted corrugated sheet and one or two flat linerboards. It is made on "flute lamination machines" or "corrugators" and is used for making corrugated boxes. The corrugated medium sheet and the linerboard(s) are made of kraft containerboard, a paperboard material usually over 0.25 millimetres (0.01 in) thick.
Petroleum jelly, petrolatum, white petrolatum, soft paraffin, or multi-hydrocarbon, CAS number 8009-03-8, is a semi-solid mixture of hydrocarbons, originally promoted as a topical ointment for its healing properties. Vaseline has been an American brand of petroleum jelly since 1870.
Ski wax is a material applied to the bottom of snow runners, including skis, snowboards, and toboggans, to improve their coefficient of friction performance under varying snow conditions. The two main types of wax used on skis are glide waxes and grip waxes. They address kinetic friction—to be minimized with a glide wax—and static friction—to be achieved with a grip wax. Both types of wax are designed to be matched with the varying properties of snow, including crystal type and size, and moisture content of the snow surface, which vary with temperature and the temperature history of the snow. Glide wax is selected to minimize sliding friction for both alpine and cross-country skiing. Grip wax provides on-snow traction for cross-country skiers, as they stride forward using classic technique.
A moisturizer, or emollient, is a cosmetic preparation used for protecting, moisturizing, and lubricating the skin. These functions are normally performed by sebum produced by healthy skin. The word "emollient" is derived from the Latin verb mollire, to soften.
Amorphous poly alpha olefin is a commodity chemical used in multiple applications.
A label is a piece of paper, plastic film, cloth, metal, or other material affixed to a container or product, on which is written or printed information or symbols about the product or item. Information printed directly on a container or article can also be considered labelling.
Waterproofing is the process of making an object, person or structure waterproof or water-resistant so that it remains relatively unaffected by water or resisting the ingress of water under specified conditions. Such items may be used in wet environments or underwater to specified depths.
Baby oil is an inert oil used to keep skin soft and supple, named for its use on babies and also often used on adults for skincare and massage.
Calumet, Inc. is a publicly traded U.S.-based company that was incorporated in 1919. It specializes in the manufacture of lubricating oils, solvents, waxes, packaged and synthetic specialty products, fuels and fuel-related products. The company operates 12 production, blending, and packaging facilities across North America. This includes locations in Princeton, Cotton Valley, and Shreveport, Louisiana; Burnham, Illinois; Dickinson, Texas; Muncie, Indiana; Karns City, Pennsylvania; and Great Falls, Montana. Calumet's specialized hydrocarbon products are distributed around the world to approximately 2,700 global customers.
A glazing agent is a natural or synthetic substance that provides a waxy, homogeneous coating to prevent water loss from a surface and provide other protection.
A cream is a preparation usually for application to the skin. Creams for application to mucous membranes such as those of the rectum or vagina are also used. Creams may be considered pharmaceutical products, since even cosmetic creams are manufactured using techniques developed by pharmacy and unmedicated creams are highly used in a variety of skin conditions (dermatoses). The use of the finger tip unit concept may be helpful in guiding how much topical cream is required to cover different areas.
Hot-melt adhesive (HMA), also known as hot glue, is a form of thermoplastic adhesive that is commonly sold as solid cylindrical sticks of various diameters designed to be applied using a hot glue gun. The gun uses a continuous-duty heating element to melt the plastic glue, which the user pushes through the gun either with a mechanical trigger mechanism on the gun, or with direct finger pressure. The glue squeezed out of the heated nozzle is initially hot enough to burn and even blister skin. The glue is sticky when hot, and solidifies in a few seconds to one minute. Hot-melt adhesives can also be applied by dipping or spraying, and are popular with hobbyists and crafters both for affixing and as an inexpensive alternative to resin casting.
Higher alkanes refer to alkanes with a high number of carbon atoms. There does not exist a formal definition for when an alkane is classified as a 'higher alkane', but one definition distinguishes the higher alkanes as the n-alkanes that are solid under room temperature.
Fiberboard or fibreboard is a type of engineered wood product that is made out of wood fibers. Types of fiberboard include particle board or low-density fiberboard (LDF), medium-density fiberboard (MDF), and hardboard or high-density fiberboard (HDF).
Adhesive tape is one of many varieties of backing materials coated with an adhesive. Several types of adhesives can be used.
Crude oil is extracted from the bedrock before being processed in several stages, removing natural contaminants and undesirable hydrocarbons. This separation process produces mineral oil, which can in turn be denoted as paraffinic, naphthenic or aromatic. The differences between these different types of oils are not clear-cut, but mainly depend on the predominant hydrocarbon types in the oil. Paraffinic oil, for example, contains primarily higher alkanes, whereas naphthenic oils have a high share of cyclic alkanes in the mixture.