Nano tape

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Commercially available nano tape. Nano tape.jpg
Commercially available nano tape.
Nano tape used to hang household items. Nano tape used to hang household items.jpg
Nano tape used to hang household items.

Nano tape, also called gecko tape; marketed under the name Insanity Tape, is a synthetic adhesive tape consisting of arrays of carbon nanotubes transferred onto a backing material of flexible polymer tape. These arrays are called synthetic setae and mimic the nanostructures found on the toes of a gecko; this is an example of biomimicry. The adhesion is achieved not with chemical adhesives, but via van der Waals forces, which are weak electric forces generated between two atoms or molecules that are very close to each other. So far there is little evidence to support nano tape being recyclable in the same way as plastic bottles, but it is reusable. More data is needed to know how environmentally safe nano tape is. [1] [2]

Contents

Explanation

Geckos show a remarkable ability to climb smooth vertical surfaces at high speeds, exhibiting both strong attachment and easy rapid removal, or shear adhesion, of their feet. [3]

On a gecko's foot, micrometer-sized elastic hairs called setae are split into nanometer-sized structures called spatulas. The shear adhesion is achieved by forming and breaking van der Waals forces between these microscopic structures and the substrate. [4]

Nano tapes mimic these structures with carbon nanotube bundles, which simulate setae, and individual nanotubes, which simulate spatulas, to achieve macroscopic shear adhesion and to translate the weak van der Waals interactions into high shear forces. The shear adhesion allows the tape to be easily peeled off, in the manner a gecko lifts its foot. Since the carbon nanotube arrays leave no residue on the substrate, the tape can be reused many times. [5]

History

Nano tape is one of the first developments of synthetic setae, which arose from a collaboration between the Manchester Centre for Mesoscience and Nanotechnology, and the Institute for Microelectronics Technology in Russia. Work started in 2001 and two years later results were published in Nature Materials. [6]

The group prepared flexible fibers of polyimide as the synthetic setae structures on the surface of a 5  μm thick film of the same material using electron beam lithography and dry etching in an oxygen plasma. The fibres were 2 μm long, with a diameter of around 500 nm and a periodicity of 1.6 μm, and covered an area of roughly 1 cm2 (see figure on the left). Initially, the team used a silicon wafer as a substrate, but found that the tape's adhesive power increased by almost 1,000 times if they used a soft bonding substrate such as Scotch tape. This is because the flexible substrate yields a much higher ratio of the number of setae in contact with the surface over the total number of setae.[ citation needed ]

The result of this "gecko tape" was tested by attaching a sample to the hand of a 15 cm high plastic Spider-Man figure weighing 40 g, which enabled it to stick to a glass ceiling, as is shown in the figure. The tape, which had a contact area of around 0.5 square centimetres (50 mm2) with the glass, was able to carry a load of more than 100 grams (3.5 oz). However, the adhesion coefficient was only 0.06, which is low compared with real geckos (8~16).[ citation needed ]

Commercial use

Commercial nano tape is usually sold as double-sided tape that is useful for hanging lightweight items such as pictures and decorative items on smooth walls without punching holes in the wall. Using superaligned carbon nanotubes, some nano tapes can stay sticky in extreme temperatures. [2]

Related Research Articles

<span class="mw-page-title-main">Adhesive</span> Non-metallic material used to bond various materials together

Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.

<span class="mw-page-title-main">Gecko</span> Lizard belonging to the infraorder Gekkota

Geckos are small, mostly carnivorous lizards that have a wide distribution, found on every continent except Antarctica. Belonging to the infraorder Gekkota, geckos are found in warm climates throughout the world. They range from 1.6 to 60 centimetres.

<span class="mw-page-title-main">Van der Waals force</span> Interactions between groups of atoms that do not arise from chemical bonds

In molecular physics and chemistry, the van der Waals force is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; they are comparatively weak and therefore more susceptible to disturbance. The van der Waals force quickly vanishes at longer distances between interacting molecules.

In biology, setae are any of a number of different bristle- or hair-like structures on living organisms.

<span class="mw-page-title-main">Adhesion</span> Molecular property

Adhesion is the tendency of dissimilar particles or surfaces to cling to one another.

<span class="mw-page-title-main">Nanoelectromechanical systems</span> Class of devices for nanoscale functionality

Nanoelectromechanical systems (NEMS) are a class of devices integrating electrical and mechanical functionality on the nanoscale. NEMS form the next logical miniaturization step from so-called microelectromechanical systems, or MEMS devices. NEMS typically integrate transistor-like nanoelectronics with mechanical actuators, pumps, or motors, and may thereby form physical, biological, and chemical sensors. The name derives from typical device dimensions in the nanometer range, leading to low mass, high mechanical resonance frequencies, potentially large quantum mechanical effects such as zero point motion, and a high surface-to-volume ratio useful for surface-based sensing mechanisms. Applications include accelerometers and sensors to detect chemical substances in the air.

<span class="mw-page-title-main">Lamella (surface anatomy)</span> Anatomical structure

In surface anatomy, a lamella is a thin plate-like structure, often one amongst many lamellae very close to one another, with open space between. Aside from respiratory organs, they appear in other biological roles including filter feeding and the traction surfaces of geckos.

<span class="mw-page-title-main">Synthetic setae</span> Artificial dry adhesives

Synthetic setae emulate the setae found on the toes of a gecko and scientific research in this area is driven towards the development of dry adhesives. Geckos have no difficulty mastering vertical walls and are apparently capable of adhering themselves to just about any surface. The five-toed feet of a gecko are covered with elastic hairs called setae and the ends of these hairs are split into nanoscale structures called spatulae. The sheer abundance and proximity to the surface of these spatulae make it sufficient for van der Waals forces alone to provide the required adhesive strength. Following the discovery of the gecko's adhesion mechanism in 2002, which is based on van der Waals forces, biomimetic adhesives have become the topic of a major research effort. These developments are poised to yield families of novel adhesive materials with superior properties which are likely to find uses in industries ranging from defense and nanotechnology to healthcare and sport.

<span class="mw-page-title-main">Buckypaper</span> Thin sheet made of aggregated carbon nanotubes

Buckypaper is a thin sheet made from an aggregate of carbon nanotubes or carbon nanotube grid paper. The nanotubes are approximately 50,000 times thinner than a human hair. Originally, it was fabricated as a way to handle carbon nanotubes, but it is also being studied and developed into applications by several research groups, showing promise as vehicle armor, personal armor, and next-generation electronics and displays.

<span class="mw-page-title-main">Pressure-sensitive adhesive</span> Type of non reactive adhesive

Pressure-sensitive adhesive is a type of nonreactive adhesive which forms a bond when pressure is applied to bond the adhesive with a surface. No solvent, water, or heat is needed to activate the adhesive. It is used in pressure-sensitive tapes, labels, glue dots, stickers, sticky note pads, automobile trim, and a wide variety of other products.

<span class="mw-page-title-main">Molecular self-assembly</span> Movement of molecules into a defined arrangement without outside influence

In chemistry and materials science, molecular self-assembly is the process by which molecules adopt a defined arrangement without guidance or management from an outside source. There are two types of self-assembly: intermolecular and intramolecular. Commonly, the term molecular self-assembly refers to the former, while the latter is more commonly called folding.

Dry glue is an adhesion product based upon the adaptations of geckos' feet that allow them to climb sheer surfaces such as vertical glass. Synthetic equivalents use carbon nanotubes as synthetic setae on reusable adhesive patches.

A device generating linear or rotational motion using carbon nanotube(s) as the primary component, is termed a nanotube nanomotor. Nature already has some of the most efficient and powerful kinds of nanomotors. Some of these natural biological nanomotors have been re-engineered to serve desired purposes. However, such biological nanomotors are designed to work in specific environmental conditions. Laboratory-made nanotube nanomotors on the other hand are significantly more robust and can operate in diverse environments including varied frequency, temperature, mediums and chemical environments. The vast differences in the dominant forces and criteria between macroscale and micro/nanoscale offer new avenues to construct tailor-made nanomotors. The various beneficial properties of carbon nanotubes makes them the most attractive material to base such nanomotors on.

<span class="mw-page-title-main">Gecko feet</span> Hairy feature allowing suction

The feet of geckos have a number of specializations. Their surfaces can adhere to any type of material with the exception of Teflon (PTFE). This phenomenon can be explained with three elements:

The chemistry of pressure-sensitive adhesives describes the chemical science associated with pressure-sensitive adhesives (PSA). PSA tapes and labels have become an important part of everyday life. These rely on adhesive material affixed to a backing such as paper or plastic film.

<span class="mw-page-title-main">Arthropod adhesion</span>

Arthropods, including insects and spiders, make use of smooth adhesive pads as well as hairy pads for climbing and locomotion along non-horizontal surfaces. Both types of pads in insects make use of liquid secretions and are considered 'wet'. Dry adhesive mechanisms primarily rely on Van der Waals' forces and are also used by organisms other than insects. The fluid provides capillary and viscous adhesion and appears to be present in all insect adhesive pads. Little is known about the chemical properties of the adhesive fluids and the ultrastructure of the fluid-producing cells is currently not extensively studied. Additionally, both hairy and smooth types of adhesion have evolved separately numerous times in insects. Few comparative studies between the two types of adhesion mechanisms have been done and there is a lack of information regarding the forces that can be supported by these systems in insects. Additionally, tree frogs and some mammals such as the arboreal possum and bats also make use of smooth adhesive pads. The use of adhesive pads for locomotion across non-horizontal surfaces is a trait that evolved separately in different species, making it an example of convergent evolution. The power of adhesion allows these organisms to be able to climb on almost any substance.

In materials science, vertically aligned carbon nanotube arrays (VANTAs) are a unique microstructure consisting of carbon nanotubes oriented with their longitudinal axis perpendicular to a substrate surface. These VANTAs effectively preserve and often accentuate the unique anisotropic properties of individual carbon nanotubes and possess a morphology that may be precisely controlled. VANTAs are consequently widely useful in a range of current and potential device applications.

Self-cleaning surfaces are a class of materials with the inherent ability to remove any debris or bacteria from their surfaces in a variety of ways. The self-cleaning functionality of these surfaces are commonly inspired by natural phenomena observed in lotus leaves, gecko feet, and water striders to name a few. The majority of self-cleaning surfaces can be placed into three categories:

  1. superhydrophobic
  2. superhydrophilic
  3. photocatalytic.

Sticky pads are friction devices used to prevent objects from sliding on a surface, by effectively increasing the friction between the object and the surface.

Microsuction tape is a material for sticking objects to surfaces such as furniture, dashboards, walls, etc. One side is usually attached to the base surface by a classical adhesive. Objects are attached to the other side by pressing them against the tape. They stick to the tape due to small bubbles (cavities) on the surface of the tape. These contain air, which is squeezed out when the surface of an object is pressed against the surface of the tape. Due to sealing properties of the material, when the object is pulled off the surface, a vacuum is created in the cavities. Due to external air pressure, this creates a force that prevents the object from being removed from the surface, a mechanism similar to that of a suction cup.

References

  1. Bourzacarchive, Katherine (2008-10-09). "Sticky Nanotape". MIT Technology Review.
  2. 1 2 Nanowerk News (2019-07-10). "Carbon nanotube tape stays sticky in extreme temperatures". Nanowerk Newsletter. American Chemical Society.
  3. Autumn, Kellar (2006-01-01). "How Gecko Toes Stick". American Scientist. 94 (2): 124. doi:10.1511/2006.58.124.
  4. Autumn, Kellar; Gravish, Nick (2008-05-13). "Gecko adhesion: evolutionary nanotechnology". Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences. 366 (1870): 1575–1590. Bibcode:2008RSPTA.366.1575A. doi:10.1098/rsta.2007.2173. PMID   18192170. S2CID   16412336.
  5. Ge, Liehui; Sethi, Sunny; Ci, Lijie; Ajayan, Pulickel M.; Dhinojwala, Ali (2007-06-26). "Carbon nanotube-based synthetic gecko tapes". Proceedings of the National Academy of Sciences. 104 (26): 10792–10795. Bibcode:2007PNAS..10410792G. doi: 10.1073/pnas.0703505104 . PMC   1904109 . PMID   17578915.
  6. 1 2 3 Geim, A.K., Dubonos, S.V., Grigorieva, I.V., Novoselov, K.S., Zhukov, A.A. and Shapoval, S.Y. (2003), "Microfabricated adhesive mimicking gecko foot-hair", Nature Materials, v.2, pp.461–3