Pyrolytic carbon is a material similar to graphite, but with some covalent bonding between its graphene sheets as a result of imperfections in its production.
It is used in high temperature applications such as missile nose cones, rocket motors, heat shields, laboratory furnaces, in graphite-reinforced plastic, coating nuclear fuel particles, and in biomedical prostheses.
Physical properties
Pyrolytic graphite samples usually have a single cleavage plane, similar to mica, because the graphene sheets crystallize in a planar order, as opposed to[clarification needed] pyrolytic carbon, which forms microscopic randomly oriented zones. Because of this, pyrolytic graphite exhibits several unusual anisotropic properties. It is more thermally conductive along the cleavage plane than pyrolytic carbon, making it one of the best planar thermal conductors available.
Pyrolytic graphite forms mosaic crystals with controlled mosaicities up to a few degrees.
Pyrolytic graphite is also more diamagnetic (χ = −4×10−4) against the cleavage plane, exhibiting the greatest diamagnetism (by weight) of any room-temperature diamagnet. In comparison[dubious–discuss], pyrolytic graphite has a relative permeability of 0.9996, whereas bismuth has a relative permeability of 0.9998 (table).
Magnetic levitation
Pyrolytic graphite levitating over permanent magnets
Few materials can be made to magnetically levitate stably above the magnetic field from a permanent magnet. Although magnetic repulsion is obviously and easily achieved between any two magnets, the shape of the field causes the upper magnet to push off sideways, rather than remaining supported, rendering stable levitation impossible for magnetic objects (see Earnshaw's theorem). Strongly diamagnetic materials, however, can levitate above powerful magnets.
With the easy availability of rare-earth permanent magnets developed in the 1970s and 1980s, the strong diamagnetism of pyrolytic graphite makes it a convenient demonstration material for this effect.
In 2012, a research group in Japan demonstrated that pyrolytic graphite can respond to laser light or sufficiently powerful natural sunlight by spinning or moving in the direction of the field gradient.[2][3] The carbon's magnetic susceptibility weakens upon sufficient illumination, leading to an unbalanced magnetization of the material and movement when using a specific geometry.
Used to coat graphite cuvettes (tubes) in graphite furnace atomic absorption furnaces to decrease heat stress, thus increasing cuvette lifetimes.
Pyrolytic carbon is used for several applications in electronic thermal management: thermal-interface material, heat spreaders (sheets) and heat sinks (fins).
Because blood clots do not easily form on it, it is often advisable to line a blood-contacting prosthesis with this material in order to reduce the risk of thrombosis. For example, it finds use in artificial hearts and artificial heart valves. Blood vesselstents, by contrast, are often lined with a polymer that has heparin as a pendant group, relying on drug action to prevent clotting. This is at least partly because of pyrolytic carbon's brittleness and the large amount of permanent deformation, which a stent undergoes during expansion.
Pyrolytic carbon is also in medical use to coat anatomically correct orthopedic implants, a.k.a. replacement joints. In this application it is currently marketed under the name "PyroCarbon". These implants have been approved by the U.S. Food and Drug Administration for use in the hand for metacarpophalangeal (knuckle) replacements. They are produced by two companies: Tornier (BioProfile) and Ascension Orthopedics.[5] On September 23, 2011, Integra LifeSciences acquired Ascension Orthopedics. The company's pyrolytic carbon implants have been used to treat patients with different forms of osteoarthritis.[6][7] In January 2021, Integra LifeSciences sold its orthopedics company to Smith+Nephew for $240 million.[8]
↑ Kobayashi, Masayuki; Abe, Jiro (2012-12-26). "Optical Motion Control of Maglev Graphite". Journal of the American Chemical Society. 134 (51): 20593–20596. doi:10.1021/ja310365k. ISSN0002-7863. PMID23234502.
Diamagnetism is the property of materials that are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. Diamagnetism is a quantum mechanical effect that occurs in all materials; when it is the only contribution to the magnetism, the material is called diamagnetic. In paramagnetic and ferromagnetic substances, the weak diamagnetic force is overcome by the attractive force of magnetic dipoles in the material. The magnetic permeability of diamagnetic materials is less than the permeability of vacuum, μ0. In most materials, diamagnetism is a weak effect which can be detected only by sensitive laboratory instruments, but a superconductor acts as a strong diamagnet because it entirely expels any magnetic field from its interior.
Graphite is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large scale for uses in pencils, lubricants, and electrodes. Under high pressures and temperatures it converts to diamond. It is a good conductor of both heat and electricity.
Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, magnetism is one of two aspects of electromagnetism.
The Meissner effect is the expulsion of a magnetic field from a superconductor during its transition to the superconducting state when it is cooled below the critical temperature. This expulsion will repel a nearby magnet.
Earnshaw's theorem states that a collection of point charges cannot be maintained in a stable stationary equilibrium configuration solely by the electrostatic interaction of the charges. This was first proven by British mathematician Samuel Earnshaw in 1842. It is usually cited in reference to magnetic fields, but was first applied to electrostatic fields.
Electrodynamic suspension (EDS) is a form of magnetic levitation in which there are conductors which are exposed to time-varying magnetic fields. This induces eddy currents in the conductors that creates a repulsive magnetic field which holds the two objects apart.
Levitation is the process by which an object is held aloft in a stable position, without mechanical support via any physical contact.
A magnetic bearing is a type of bearing that supports a load using magnetic levitation. Magnetic bearings support moving parts without physical contact. For instance, they are able to levitate a rotating shaft and permit relative motion with very low friction and no mechanical wear. Magnetic bearings support the highest speeds of any kind of bearing and have no maximum relative speed.
Electromagnetic propulsion (EMP) is the principle of accelerating an object by the utilization of a flowing electrical current and magnetic fields. The electrical current is used to either create an opposing magnetic field, or to charge a field, which can then be repelled. When a current flows through a conductor in a magnetic field, an electromagnetic force known as a Lorentz force, pushes the conductor in a direction perpendicular to the conductor and the magnetic field. This repulsing force is what causes propulsion in a system designed to take advantage of the phenomenon. The term electromagnetic propulsion (EMP) can be described by its individual components: electromagnetic – using electricity to create a magnetic field, and propulsion – the process of propelling something. When a fluid is employed as the moving conductor, the propulsion may be termed magnetohydrodynamic drive. One key difference between EMP and propulsion achieved by electric motors is that the electrical energy used for EMP is not used to produce rotational energy for motion; though both use magnetic fields and a flowing electrical current.
Carbon fibre reinforced carbon (CFRC), carbon–carbon (C/C), or reinforced carbon–carbon (RCC) is a composite material consisting of carbon fiber reinforcement in a matrix of graphite. It was developed for the reentry vehicles of intercontinental ballistic missiles, and is most widely known as the material for the nose cone and wing leading edges of the Space Shuttle orbiter. Carbon-carbon brake discs and brake pads have been the standard component of the brake systems of Formula One racing cars since the late 1970s; the first year carbon brakes were seen on a Formula One car was 1976.
Electromagnetic suspension (EMS) is the magnetic levitation of an object achieved by constantly altering the strength of a magnetic field produced by electromagnets using a feedback loop. In most cases the levitation effect is mostly due to permanent magnets as they don't have any power dissipation, with electromagnets only used to stabilize the effect.
In the area of solid state chemistry. graphite intercalation compounds are materials prepared by intercalation of diverse guests into graphite. The materials have the formula (guest)Cn where n can range from 8 to 40's. The distance between the carbon layers increases significantly upon insertion of the guests. Common guests are reducing agents such as alkali metals. Strong oxidants, such as arsenic pentafluoride also intercalate into graphite. Intercalation involves electron transfer into or out of the host. The properties of these materials differ from those of the parent graphite.
AlSiC, pronounced "alsick", is a metal matrix composite consisting of aluminium matrix with silicon carbide particles. It has high thermal conductivity, and its thermal expansion can be adjusted to match other materials, e.g. silicon and gallium arsenide chips and various ceramics. It is chiefly used in microelectronics as substrate for power semiconductor devices and high density multi-chip modules, where it aids with removal of waste heat.
E-Material, also called E Material, is a metal matrix composite consisting of beryllium matrix with beryllium oxide particles. It has high thermal conductivity, and its thermal expansion can be adjusted to match other materials, e.g. silicon and gallium arsenide chips and various ceramics. It is chiefly used in microelectronics as substrate for power semiconductor devices and high density multi-chip modules, where it aids with removal of waste heat. E-materials have low weight and high strength, making them especially suitable for aerospace technology. Their high elastic modulus is favorable for absorbing vibrations and lowering material fatigue of attached modules and wire bonds.
Magnetic levitation (maglev) or magnetic suspension is a method by which an object is suspended with no support other than magnetic fields. Magnetic force is used to counteract the effects of the gravitational force and any other forces.
In nuclear fusion power research, the plasma-facing material (PFM) is any material used to construct the plasma-facing components (PFC), those components exposed to the plasma within which nuclear fusion occurs, and particularly the material used for the lining the first wall or divertor region of the reactor vessel.
Annealed Pyrolytic Graphite (APG), also known as Thermally Annealed Pyrolytic Graphite (TPG), is a form of synthetic graphite that offers excellent in-plane thermal conductivity. As with pyrolytic carbon or pyrolytic graphite (PG), APG is also low in mass, is electrically conductive, and offers diamagnetic properties that allow it to levitate in magnetic fields.
A graphene morphology is any of the structures related to, and formed from, single sheets of graphene. 'Graphene' is typically used to refer to the crystalline monolayer of the naturally occurring material graphite. Due to quantum confinement of electrons within the material at these low dimensions, small differences in graphene morphology can greatly impact the physical and chemical properties of these materials. Commonly studied graphene morphologies include the monolayer sheets, bilayer sheets, graphene nanoribbons and other 3D structures formed from stacking of the monolayer sheets.
Advanced thermoplastic composites (ACM) have a high strength fibres held together by a thermoplastic matrix. Advanced thermoplastic composites are becoming more widely used in the aerospace, marine, automotive and energy industry. This is due to the decreasing cost and superior strength to weight ratios, over metallic parts. Advance thermoplastic composite have excellent damage tolerance, corrosion resistant, high fracture toughness, high impact resistance, good fatigue resistance, low storage cost, and infinite shelf life. Thermoplastic composites also have the ability to be formed and reformed, repaired and fusion welded.
Implant induction welding is a joining method used in plastic manufacturing. The welding process uses an induction coil to excite and heat electromagnetically susceptible material at the joint interface and melt the thermoplastic. The susceptible material can be contained in a gasket placed between the welding surface, or within the actual components of a composite material. Its usage is common for large, unusually shaped, or delicate parts that would be difficult to weld through other methods.
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