In quantum chaos, a branch of mathematical physics, quantum ergodicity is a property of the quantization of classical mechanical systems that are chaotic in the sense of exponential sensitivity to initial conditions. Quantum ergodicity states, roughly, that in the high-energy limit, the probability distributions associated to energy eigenstates of a quantized ergodic Hamiltonian tend to a uniform distribution in the classical phase space. This is consistent with the intuition that the flows of ergodic systems are equidistributed in phase space. By contrast, classical completely integrable systems generally have periodic orbits in phase space, and this is exhibited in a variety of ways in the high-energy limit of the eigenstates: typically, some form of concentration occurs in the semiclassical limit .
The model case of a Hamiltonian is the geodesic Hamiltonian on the cotangent bundle of a compact Riemannian manifold. The quantization of the geodesic flow is given by the fundamental solution of the Schrödinger equation
where is the square root of the Laplace–Beltrami operator. The quantum ergodicity theorem of Shnirelman 1974, Zelditch, and Yves Colin de Verdière states that a compact Riemannian manifold whose unit tangent bundle is ergodic under the geodesic flow is also ergodic in the sense that the probability density associated to the nth eigenfunction of the Laplacian tends weakly to the uniform distribution on the unit cotangent bundle as n → ∞ in a subset of the natural numbers of natural density equal to one. Quantum ergodicity can be formulated as a non-commutative analogue of the classical ergodicity (T. Sunada).
Since a classically chaotic system is also ergodic, almost all of its trajectories eventually explore uniformly the entire accessible phase space. Thus, when translating the concept of ergodicity to the quantum realm, it is natural to assume that the eigenstates of the quantum chaotic system would fill the quantum phase space evenly (up to random fluctuations) in the semiclassical limit . The quantum ergodicity theorems of Shnirelman, Zelditch, and Yves Colin de Verdière proves that the expectation value of an operator converges in the semiclassical limit to the corresponding microcanonical classical average. However, the quantum ergodicity theorem leaves open the possibility of eigenfunctions become sparse with serious holes as , leaving large but not macroscopic gaps on the energy manifolds in the phase space. In particular, the theorem allows the existence of a subset of macroscopically nonerdodic states which on the other hand must approach zero measure, i.e., the contribution of this set goes towards zero percent of all eigenstates when . [5]
For example, the theorem do not exclude quantum scarring, as the phase space volume of the scars also gradually vanishes in this limit. [1] [5] [6] [2] A quantum eigenstate is scarred by periodic orbit if its probability density is on the classical invariant manifolds near and all along that periodic orbit is systematically enhanced above the classical, statistically expected density along that orbit. [5] In a simplified manner, a quantum scar refers to an eigenstate of whose probability density is enhanced in the neighborhood of a classical periodic orbit when the corresponding classical system is chaotic. In conventional scarring, the responsive periodic orbit is unstable. [1] [5] [6] [2] The instability is a decisive point that separates quantum scars from a more trivial finding that the probability density is enhanced near stable periodic orbits due to the Bohr's correspondence principle. The latter can be viewed as a purely classical phenomenon, whereas in the former quantum interference is important. On the other hand, in the perturbation-induced quantum scarring, [3] [7] [8] [9] [4] some of the high-energy eigenstates of a locally perturbed quantum dot contain scars of short periodic orbits of the corresponding unperturbed system. Even though similar in appearance to ordinary quantum scars, these scars have a fundamentally different origin., [3] [7] [4] In this type of scarring, there are no periodic orbits in the perturbed classical counterpart or they are too unstable to cause a scar in a conventional sense. Conventional and perturbation-induced scars are both a striking visual example of classical-quantum correspondence and of a quantum suppression of chaos (see the figure). In particular, scars are a significant correction to the assumption that the corresponding eigenstates of a classically chaotic Hamiltonian are only featureless and random. In some sense, scars can be considered as an eigenstate counterpart to the quantum ergodicity theorem of how short periodic orbits provide corrections to the universal random matrix theory eigenvalue statistics.
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point, it is one of the most important model systems in quantum mechanics. Furthermore, it is one of the few quantum-mechanical systems for which an exact, analytical solution is known.
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the subject. The equation is named after Erwin Schrödinger, who postulated the equation in 1925, and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933.
In physics, an operator is a function over a space of physical states onto another space of physical states. The simplest example of the utility of operators is the study of symmetry. Because of this, they are very useful tools in classical mechanics. Operators are even more important in quantum mechanics, where they form an intrinsic part of the formulation of the theory.
Quantum chaos is a branch of physics which studies how chaotic classical dynamical systems can be described in terms of quantum theory. The primary question that quantum chaos seeks to answer is: "What is the relationship between quantum mechanics and classical chaos?" The correspondence principle states that classical mechanics is the classical limit of quantum mechanics, specifically in the limit as the ratio of Planck's constant to the action of the system tends to zero. If this is true, then there must be quantum mechanisms underlying classical chaos. If quantum mechanics does not demonstrate an exponential sensitivity to initial conditions, how can exponential sensitivity to initial conditions arise in classical chaos, which must be the correspondence principle limit of quantum mechanics?
In classical and quantum mechanics, geometric phase is a phase difference acquired over the course of a cycle, when a system is subjected to cyclic adiabatic processes, which results from the geometrical properties of the parameter space of the Hamiltonian. The phenomenon was independently discovered by S. Pancharatnam (1956), in classical optics and by H. C. Longuet-Higgins (1958) in molecular physics; it was generalized by Sir Michael Berry in (1984). It is also known as the Pancharatnam–Berry phase, Pancharatnam phase, or Berry phase. It can be seen in the conical intersection of potential energy surfaces and in the Aharonov–Bohm effect. Geometric phase around the conical intersection involving the ground electronic state of the C6H3F3+ molecular ion is discussed on pages 385–386 of the textbook by Bunker and Jensen. In the case of the Aharonov–Bohm effect, the adiabatic parameter is the magnetic field enclosed by two interference paths, and it is cyclic in the sense that these two paths form a loop. In the case of the conical intersection, the adiabatic parameters are the molecular coordinates. Apart from quantum mechanics, it arises in a variety of other wave systems, such as classical optics. As a rule of thumb, it can occur whenever there are at least two parameters characterizing a wave in the vicinity of some sort of singularity or hole in the topology; two parameters are required because either the set of nonsingular states will not be simply connected, or there will be nonzero holonomy.
The adiabatic theorem is a concept in quantum mechanics. Its original form, due to Max Born and Vladimir Fock (1928), was stated as follows:
The old quantum theory is a collection of results from the years 1900–1925 which predate modern quantum mechanics. The theory was never complete or self-consistent, but was rather a set of heuristic corrections to classical mechanics. The theory is now understood as the semi-classical approximation to modern quantum mechanics. The main and final accomplishments of the old quantum theory were the determination of the modern form of the periodic table by Edmund Stoner and the Pauli Exclusion Principle which were both premised on the Arnold Sommerfeld enhancements to the Bohr model of the atom.
Quantum Darwinism is a theory meant to explain the emergence of the classical world from the quantum world as due to a process of Darwinian natural selection induced by the environment interacting with the quantum system; where the many possible quantum states are selected against in favor of a stable pointer state. It was proposed in 2003 by Wojciech Zurek and a group of collaborators including Ollivier, Poulin, Paz and Blume-Kohout. The development of the theory is due to the integration of a number of Zurek's research topics pursued over the course of twenty-five years including: pointer states, einselection and decoherence.
In physics, thermalisation is the process of physical bodies reaching thermal equilibrium through mutual interaction. In general the natural tendency of a system is towards a state of equipartition of energy and uniform temperature that maximizes the system's entropy. Thermalisation, thermal equilibrium, and temperature are therefore important fundamental concepts within statistical physics, statistical mechanics, and thermodynamics; all of which are a basis for many other specific fields of scientific understanding and engineering application.
A dynamical billiard is a dynamical system in which a particle alternates between free motion and specular reflections from a boundary. When the particle hits the boundary it reflects from it without loss of speed. Billiards are Hamiltonian idealizations of the game of billiards, but where the region contained by the boundary can have shapes other than rectangular and even be multidimensional. Dynamical billiards may also be studied on non-Euclidean geometries; indeed, the first studies of billiards established their ergodic motion on surfaces of constant negative curvature. The study of billiards which are kept out of a region, rather than being kept in a region, is known as outer billiard theory.
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a particular energy level is known as the degree of degeneracy of the level. It is represented mathematically by the Hamiltonian for the system having more than one linearly independent eigenstate with the same energy eigenvalue. When this is the case, energy alone is not enough to characterize what state the system is in, and other quantum numbers are needed to characterize the exact state when distinction is desired. In classical mechanics, this can be understood in terms of different possible trajectories corresponding to the same energy.
In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum problems involving rotational symmetry. Such an operator is applied to a mathematical representation of the physical state of a system and yields an angular momentum value if the state has a definite value for it. In both classical and quantum mechanical systems, angular momentum is one of the three fundamental properties of motion.
A stationary state is a quantum state with all observables independent of time. It is an eigenvector of the energy operator. It is also called energy eigenvector, energy eigenstate, energy eigenfunction, or energy eigenket. It is very similar to the concept of atomic orbital and molecular orbital in chemistry, with some slight differences explained below.
In mechanics, a constant of motion is a quantity that is conserved throughout the motion, imposing in effect a constraint on the motion. However, it is a mathematical constraint, the natural consequence of the equations of motion, rather than a physical constraint. Common examples include energy, linear momentum, angular momentum and the Laplace–Runge–Lenz vector.
In mathematics, ergodicity expresses the idea that a point of a moving system, either a dynamical system or a stochastic process, will eventually visit all parts of the space that the system moves in, in a uniform and random sense. This implies that the average behavior of the system can be deduced from the trajectory of a "typical" point. Equivalently, a sufficiently large collection of random samples from a process can represent the average statistical properties of the entire process. Ergodicity is a property of the system; it is a statement that the system cannot be reduced or factored into smaller components. Ergodic theory is the study of systems possessing ergodicity.
In quantum mechanics, given a particular Hamiltonian and an operator with corresponding eigenvalues and eigenvectors given by , the are said to be good quantum numbers if every eigenvector remains an eigenvector of with the same eigenvalue as time evolves.
This is a glossary for the terminology often encountered in undergraduate quantum mechanics courses.
Quantum scarring refers to a phenomenon where the eigenstates of a classically chaotic quantum system have enhanced probability density around the paths of unstable classical periodic orbits. The instability of the periodic orbit is a decisive point that differentiates quantum scars from the more trivial observation that the probability density is enhanced in the neighborhood of stable periodic orbits. The latter can be understood as a purely classical phenomenon, a manifestation of the Bohr correspondence principle, whereas in the former, quantum interference is essential. As such, scarring is both a visual example of quantum-classical correspondence, and simultaneously an example of a (local) quantum suppression of chaos.
The Koopman–von Neumann mechanics is a description of classical mechanics in terms of Hilbert space, introduced by Bernard Koopman and John von Neumann in 1931 and 1932, respectively.
The eigenstate thermalization hypothesis is a set of ideas which purports to explain when and why an isolated quantum mechanical system can be accurately described using equilibrium statistical mechanics. In particular, it is devoted to understanding how systems which are initially prepared in far-from-equilibrium states can evolve in time to a state which appears to be in thermal equilibrium. The phrase "eigenstate thermalization" was first coined by Mark Srednicki in 1994, after similar ideas had been introduced by Josh Deutsch in 1991. The principal philosophy underlying the eigenstate thermalization hypothesis is that instead of explaining the ergodicity of a thermodynamic system through the mechanism of dynamical chaos, as is done in classical mechanics, one should instead examine the properties of matrix elements of observable quantities in individual energy eigenstates of the system.