Retrobright (stylized as retr0bright or Retrobrite [1] ) is a hydrogen peroxide-based process for removing yellowing from ABS plastics.
Yellowing in ABS plastic occurs when it is exposed to UV light or excessive heat, which causes photo-oxidation of polymers that breaks polymer chains and causes the plastic to yellow and become brittle. [2]
One method of reversing the yellowed discoloration was first discovered in 2007 in a German retrocomputing forum, [3] before spreading to an English blog where it was further detailed. [4] [5] [6] The process has been continually refined since. [1]
Retrobright consists of hydrogen peroxide, a small amount of the "active oxygen" laundry booster TAED as a catalyst, and a source of UV. [7]
The optimum mixture and conditions for reversing yellowing of plastics:
Xanthan gum or arrowroot can be added to the solution, creating an easier-to-apply gel.[ citation needed ]
 | This section needs additional citations for verification .(April 2024) |
Sodium percarbonate may also be used by dissolving it in water and following the usual steps for hydrogen peroxide, as it is sodium carbonate and hydrogen peroxide in a crystalline form. [8]
Ozone gas can also be used for retrobrighting, as long as an ozone generator, a suitable container of sufficient size and a source of UV are available, but can take longer than other methods. [8]
A simpler but slower process involving merely exposure of the yellowed plastic to bright sunlight has been described, variously called 'Sunbrighting' or 'Lightbrighting'. This has both empirical evidence of effectiveness and the theoretical backing of some published scientific literature, which emphasises exposure to strong visible light while minimising ultraviolet exposure.
The long-term effectiveness of these techniques is unclear. Some have discovered the yellowing reappears, and there are concerns that the process weakens and only bleaches the already damaged plastic. [12] [13] [14]
The usage has also expanded to other retro restoration applications, such as classic and collectible sneaker restoration, where it is referred to by collectors as "sole sauce". [15] [ failed verification ]
Hydrogen peroxide is a chemical compound with the formula H2O2. In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution in water for consumer use and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as both a monopropellant and an oxidizer in rocketry.
Ozone is an inorganic molecule with the chemical formula O
3. It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope O
2, breaking down in the lower atmosphere to O
2 (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the atmosphere, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation.
Ultraviolet (UV) light is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight, and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs, Cherenkov radiation, and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights.
Poly(methyl methacrylate) (PMMA) is the synthetic polymer derived from methyl methacrylate. It is used as an engineering plastic, and it is a transparent thermoplastic. PMMA is also known as acrylic, acrylic glass, as well as by the trade names and brands Crylux, Hesalite, Plexiglas, Acrylite, Lucite, and Perspex, among several others. This plastic is often used in sheet form as a lightweight or shatter-resistant alternative to glass. It can also be used as a casting resin, in inks and coatings, and for many other purposes.
Acrylonitrile butadiene styrene (ABS) (chemical formula (C8H8)x·(C4H6)y·(C3H3N)z ) is a common thermoplastic polymer. Its glass transition temperature is approximately 105 °C (221 °F). ABS is amorphous and therefore has no true melting point.
Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C14H10, consisting of three fused benzene rings. It is a component of coal tar. Anthracene is used in the production of the red dye alizarin and other dyes. Anthracene is colorless but exhibits a blue (400–500 nm peak) fluorescence under ultraviolet radiation.
Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition. Polymers and particularly plastics are subject to degradation at all stages of their product life cycle, including during their initial processing, use, disposal into the environment and recycling. The rate of this degradation varies significantly; biodegradation can take decades, whereas some industrial processes can completely decompose a polymer in hours.
Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA).
Polybutylene terephthalate (PBT) is a thermoplastic engineering polymer that is used as an insulator in the electrical and electronics industries. It is a thermoplastic (semi-)crystalline polymer, and a type of polyester. PBT resists solvents, shrinks very little during forming, is mechanically strong, is heat-resistant up to 150 °C, and can be treated with flame retardants to make it noncombustible. It was developed by Britain's Imperial Chemical Industries (ICI).
In industrial chemistry, a stabilizer or stabiliser is a chemical that is used to prevent degradation.
Photodegradation is the alteration of materials by light. Commonly, the term is used loosely to refer to the combined action of sunlight and air, which cause oxidation and hydrolysis. Often photodegradation is intentionally avoided, since it destroys paintings and other artifacts. It is, however, partly responsible for remineralization of biomass and is used intentionally in some disinfection technologies. Photodegradation does not apply to how materials may be aged or degraded via infrared light or heat, but does include degradation in all of the ultraviolet light wavebands.
Ultraviolet germicidal irradiation (UVGI) is a disinfection technique employing ultraviolet (UV) light, particularly UV-C (180–280 nm), to kill or inactivate microorganisms. UVGI primarily inactivates microbes by damaging their genetic material, thereby inhibiting their capacity to carry out vital functions.
In chemistry, a photoinitiator is a molecule that creates reactive species when exposed to radiation. Synthetic photoinitiators are key components in photopolymers.
Polymer stabilizers are chemical additives which may be added to polymeric materials, such as plastics and rubbers, to inhibit or retard their degradation. Common polymer degradation processes include oxidation, UV-damage, thermal degradation, ozonolysis, combinations thereof such as photo-oxidation, as well as reactions with catalyst residues, dyes, or impurities. All of these degrade the polymer at a chemical level, via chain scission, uncontrolled recombination and cross-linking, which adversely affects many key properties such as strength, malleability, appearance and colour.
Accelerated photo-ageing of polymers in SEPAP units is the controlled polymer degradation and polymer coating degradation under lab or natural conditions.
In polymer chemistry photo-oxidation is the degradation of a polymer surface due to the combined action of light and oxygen. It is the most significant factor in the weathering of plastics. Photo-oxidation causes the polymer chains to break, resulting in the material becoming increasingly brittle. This leads to mechanical failure and, at an advanced stage, the formation of microplastics. In textiles the process is called phototendering.
Twin-wall plastic, specifically twin-wall polycarbonate, is an extruded multi-wall polymer product created for applications where its strength, thermally insulative properties, and moderate cost are ideal. Polycarbonate, which is most commonly formed through the reaction of Bisphenol A and Carbonyl Chloride, is an extremely versatile material. It is significantly lighter than glass, while managing to be stronger, more flexible, and more impact resistant. Twin-wall polycarbonate is used most commonly for green houses, where it can support itself in a structurally sound configuration, limit the amount of UV light due to its nominal translucence, and can withstand the rigors of daily abuse in an outdoor environment. The stagnant air in the cellular space between sheets provides insulation, and additional cell layers can be extruded to enhance insulative properties at the cost of light transmission.
Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be molded, extruded or pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to their widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives.
Conservation and restoration of objects made from plastics is work dedicated to the conservation of objects of historical and personal value made from plastics. When applied to cultural heritage, this activity is generally undertaken by a conservator-restorer.
UV curing is the process by which ultraviolet light initiates a photochemical reaction that generates a crosslinked network of polymers through radical polymerization or cationic polymerization. UV curing is adaptable to printing, coating, decorating, stereolithography, and in the assembly of a variety of products and materials. UV curing is a low-temperature, high speed, and solventless process as curing occurs via polymerization. Originally introduced in the 1960s, this technology has streamlined and increased automation in many industries in the manufacturing sector.
