Sea salt aerosol, which originally comes from sea spray, is one of the most widely distributed natural aerosols. Sea salt aerosols are characterized as non-light-absorbing, highly hygroscopic, and having coarse particle size. Some sea salt dominated aerosols could have a single scattering albedo as large as ~0.97. [1] Due to the hygroscopy, a sea salt particle can serve as a very efficient cloud condensation nuclei (CCN), altering cloud reflectivity, lifetime, and precipitation process. According to the IPCC report, the total sea salt flux from ocean to atmosphere is ~3300 teragrams (Tg) per year. [2]
Many physical processes over ocean surface can generate sea salt aerosols. One common cause is the bursting of air bubbles, which are entrained by the wind stress during the whitecap formation. Another is tearing of drops from wave tops. [3] Wind speed is the key factor to determine the production rate in both mechanisms. Sea salt particle number concentration can reach 50 cm−3 or more with high winds (>10 m s−1), compared to ~10 cm−3 or less under moderate wind regimes. [3] Due to the dependence on wind speed, it could be expected that sea-salt particle production and its impacts on climate may vary with climate change.
Sea salt aerosols are mainly constituted of sodium chloride (NaCl), but other chemical ions which are common in sea water, such as K+, Mg2+, Ca2+, SO42− and so on, can also be found. A recent study revealed that sea salt aerosols also contain a substantial amount of organic matter. [4] [5] Mostly, organic materials are internally mixed due to the drying of air bubbles at the organic-rich sea surface. [3] The fraction of organic components increases with the decreasing particle size. The contained organic materials change the optical properties of sea salt as well as the hygroscopicity, especially when some insoluble organic matter is induced.
Size of sea salt aerosols ranges widely from ~0.05 to 10 μm in diameter, with most of masses concentrated in super-micron range (coarse mode), and highest number concentration in sub-micron range. Correspondingly, sea salt aerosols have a wide range of atmospheric lifetimes. As the sea salt aerosols are hygroscopic, their particle sizes may vary with humidity by up to a factor of 2. Sea salt aerosols influence the sulfate aerosol formation in different ways due to the different sizes. Very small sea salt aerosols, which are below the critical diameter for droplet activation at low supersaturations, can serve as nuclei for the growth of sulfate particles, while larger sea salt particles serve as a sink for gaseous hydrogen sulfate (H2SO4) molecules, reducing the amount of sulfate available for the formation of accumulation mode particles. [3]
Sea salt aerosols can alter the Earth radiation budget through directly scattering solar radiation (direct effect), and indirectly changing the cloud albedo by serving as CCN (indirect effect). Different models give different predictions of annual mean radiative forcing induced by sea salt direct effect, but most of the previous studies give a number around 0.6-1.0 W m−2. [6] [7] Radiative forcing caused by indirect effects show even greater variations in model prediction because of the parameterization of aerosol indirect effect. However, model results [6] [7] present a stronger indirect effect on the Southern Hemisphere.
Like all other soluble aerosols, increasing normal-sized sea salts suppresses the precipitation process in warm clouds by increasing cloud droplet number concentration and reducing the cloud droplet size. Also, they invigorate precipitation in mix-phase clouds because once the suppressed smaller cloud droplets are lifted above freezing level, more latent heat content would be released due to the freezing of cloud drops. [8] Besides that, adding giant sea salt aerosols to polluted clouds can accelerate the precipitation process because giant CCNs could be nucleated into large particles which collect other smaller cloud drops and grow into rain droplets. [9] Cloud drops formed on giant sea salt aerosols may grow much more rapidly by condensation that cloud drops formed on small soluble aerosol particles, as giant sea salt cloud drops may remain concentrated solution drops for long times after they are carried into cloud. Such drops may have condensational growth rates more than two times faster than drops formed on small aerosol particles, and unlike normal cloud drops, drops formed on the largest of the giant sea salt aerosols may even grow by condensation in otherwise subsaturated cloudy downdrafts. [10]
Cirrus is a genus of high cloud made of ice crystals. Cirrus clouds typically appear delicate and wispy with white strands. Cirrus are usually formed when warm, dry air rises, causing water vapor deposition onto rocky or metallic dust particles at high altitudes. Globally, they form anywhere between 4,000 and 20,000 meters above sea level, with the higher elevations usually in the tropics and the lower elevations in more polar regions.
Cloud albedo is a measure of the albedo or reflectivity of a cloud. Clouds regulate the amount of solar radiation absorbed by a planet and its solar surface irradiance. Generally, increased cloud cover correlates to a higher albedo and a lower absorption of solar energy. Cloud albedo strongly influences the Earth's energy budget, accounting for approximately half of Earth's albedo. Cloud albedo depends on the total mass of water, the size and shape of the droplets or particles and their distribution in space. Thick clouds reflect a large amount of incoming solar radiation, translating to a high albedo. Thin clouds tend to transmit more solar radiation and, therefore, have a low albedo. Changes in cloud albedo caused by variations in cloud properties have a significant effect on global climate.
An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. The term aerosol commonly refers to the particulate/air mixture, as opposed to the particulate matter alone. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, dust, steam from a kettle, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an anthropogenic aerosol.
Fog is a visible aerosol consisting of tiny water droplets or ice crystals suspended in the air at or near the Earth's surface. Fog can be considered a type of low-lying cloud usually resembling stratus, and is heavily influenced by nearby bodies of water, topography, and wind conditions. In turn, fog affects many human activities, such as shipping, travel, and warfare.
Global dimming refers to a decline in the amount of sunlight reaching the Earth's surface, a measure also known as global direct solar irradiance. It was observed soon after the first systematic measurements of solar irradiance began in the 1950s, and continued until 1980s, with an observed reduction of 4–5% per decade, even though solar activity did not vary more than the usual at the time. Instead, global dimming had been attributed to an increase in atmospheric particulate matter, predominantly sulfate aerosols, as the result of rapidly growing air pollution due to post-war industrialization. After 1980s, reductions in particulate emissions have also caused a "partial" reversal of the dimming trend, which has sometimes been described as a global brightening. This reversal is not yet complete, and it has also been globally uneven, as some of the brightening over the developed countries in the 1980s and 1990s had been counteracted by the increased dimming from the industrialization of the developing countries and the expansion of the global shipping industry, although they have also been making rapid progress in cleaning up air pollution in the recent years.
Nephology is the study of clouds and cloud formation. British meteorologist Luke Howard was a major researcher within this field, establishing a cloud classification system. While this branch of meteorology still exists today, the term nephology, or nephologist is rarely used. The term came into use at the end of the nineteenth century, and fell out of common use by the middle of the twentieth. Recently, interest in nephology has surged as many meteorologists have begun to focus on the relationship between clouds and global warming which is a major source of uncertainty regarding "...estimates and interpretations of the Earth’s changing energy budget."
Cloud condensation nuclei (CCNs), also known as cloud seeds, are small particles typically 0.2 µm, or one hundredth the size of a cloud droplet. CCNs are a unique subset of aerosols in the atmosphere on which water vapour condenses. This can affect the radiative properties of clouds and the overall atmosphere. Water requires a non-gaseous surface to make the transition from a vapour to a liquid; this process is called condensation.
Cloud physics is the study of the physical processes that lead to the formation, growth and precipitation of atmospheric clouds. These aerosols are found in the troposphere, stratosphere, and mesosphere, which collectively make up the greatest part of the homosphere. Clouds consist of microscopic droplets of liquid water, tiny crystals of ice, or both, along with microscopic particles of dust, smoke, or other matter, known as condensation nuclei. Cloud droplets initially form by the condensation of water vapor onto condensation nuclei when the supersaturation of air exceeds a critical value according to Köhler theory. Cloud condensation nuclei are necessary for cloud droplets formation because of the Kelvin effect, which describes the change in saturation vapor pressure due to a curved surface. At small radii, the amount of supersaturation needed for condensation to occur is so large, that it does not happen naturally. Raoult's law describes how the vapor pressure is dependent on the amount of solute in a solution. At high concentrations, when the cloud droplets are small, the supersaturation required is smaller than without the presence of a nucleus.
Sea spray are aerosol particles formed from the ocean, mostly by ejection into Earth's atmosphere by bursting bubbles at the air-sea interface. Sea spray contains both organic matter and inorganic salts that form sea salt aerosol (SSA). SSA has the ability to form cloud condensation nuclei (CCN) and remove anthropogenic aerosol pollutants from the atmosphere. Coarse sea spray has also been found to inhibit the development of lightning in storm clouds.
In the physics of aerosols, deposition is the process by which aerosol particles collect or deposit themselves on solid surfaces, decreasing the concentration of the particles in the air. It can be divided into two sub-processes: dry and wet deposition. The rate of deposition, or the deposition velocity, is slowest for particles of an intermediate size. Mechanisms for deposition are most effective for either very small or very large particles. Very large particles will settle out quickly through sedimentation (settling) or impaction processes, while Brownian diffusion has the greatest influence on small particles. This is because very small particles coagulate in few hours until they achieve a diameter of 0.5 micrometres. At this size they no longer coagulate. This has a great influence in the amount of PM-2.5 present in the air.
Ship tracks are clouds that form around the exhaust released by ships into the still ocean air. Water molecules collect around the tiny particles (aerosols) from exhaust to form a cloud seed. More and more water accumulates on the seed until a visible cloud is formed. In the case of ship tracks, the cloud seeds are stretched over a long narrow path where the wind has blown the ship's exhaust, so the resulting clouds resemble long strings over the ocean. Ship tracks are a type of homogenitus cloud.
The Twomey effect describes how additional cloud condensation nuclei (CCN), possibly from anthropogenic pollution, may increase the amount of solar radiation reflected by clouds. This is an indirect effect by such particles, as distinguished from direct effects (forcing) due to enhanced scattering or absorbing radiation by such particles not in clouds.
Marine cloud brightening also known as marine cloud seeding and marine cloud engineering is a proposed solar radiation management climate engineering technique that would make clouds brighter, reflecting a small fraction of incoming sunlight back into space in order to offset anthropogenic global warming. Along with stratospheric aerosol injection, it is one of the two solar radiation management methods that may most feasibly have a substantial climate impact. The intention is that increasing the Earth's albedo, in combination with greenhouse gas emissions reduction, carbon dioxide removal, and adaptation, would reduce climate change and its risks to people and the environment. If implemented, the cooling effect is expected to be felt rapidly and to be reversible on fairly short time scales. However, technical barriers remain to large-scale marine cloud brightening. There are also risks with such modification of complex climate systems.
Stratospheric aerosol injection is a proposed method of solar geoengineering to reduce global warming. This would introduce aerosols into the stratosphere to create a cooling effect via global dimming and increased albedo, which occurs naturally from volcanic winter. It appears that stratospheric aerosol injection, at a moderate intensity, could counter most changes to temperature and precipitation, take effect rapidly, have low direct implementation costs, and be reversible in its direct climatic effects. The Intergovernmental Panel on Climate Change concludes that it "is the most-researched [solar geoengineering] method, with high agreement that it could limit warming to below 1.5 °C (2.7 °F)." However, like other solar geoengineering approaches, stratospheric aerosol injection would do so imperfectly and other effects are possible, particularly if used in a suboptimal manner.
Tropical convective clouds play an important part in the Earth's climate system. Convection and release of latent heat transports energy from the surface into the upper atmosphere. Clouds have a higher albedo than the underlying ocean, which causes more incoming solar radiation to be reflected back to space. Since the tops of tropical systems are much cooler than the surface of the Earth, the presence of high convective clouds cools the climate system.
Particulates or atmospheric particulate matter are microscopic particles of solid or liquid matter suspended in the air. The term aerosol commonly refers to the particulate/air mixture, as opposed to the particulate matter alone. Sources of particulate matter can be natural or anthropogenic. They have impacts on climate and precipitation that adversely affect human health, in ways additional to direct inhalation.
The Albrecht effect describes how a larger density of cloud condensation nuclei (CCN), possibly from anthropogenic pollution, may increase cloud lifetime and hence increase the amount of solar radiation reflected from clouds. Because it does not directly interact with incoming or outgoing radiation, it has an indirect effect on climate.
Kimberly A. Prather is an American atmospheric chemist. She is a distinguished chair in atmospheric chemistry and a distinguished professor at the Scripps Institution of Oceanography and department of chemistry and biochemistry at UC San Diego. Her work focuses on how humans are influencing the atmosphere and climate. In 2019, she was elected a member of the National Academy of Engineering for technologies that transformed understanding of aerosols and their impacts on air quality, climate, and human health. In 2020, she was elected as a member of the National Academy of Sciences. She is also an elected Fellow of the American Philosophical Society, American Geophysical Union, the American Association for the Advancement of Science, American Philosophical Society, and the American Academy of Arts and Sciences.
The North Atlantic Aerosols and Marine Ecosystems Study (NAAMES) was a five-year scientific research program that investigated aspects of phytoplankton dynamics in ocean ecosystems, and how such dynamics influence atmospheric aerosols, clouds, and climate. The study focused on the sub-arctic region of the North Atlantic Ocean, which is the site of one of Earth's largest recurring phytoplankton blooms. The long history of research in this location, as well as relative ease of accessibility, made the North Atlantic an ideal location to test prevailing scientific hypotheses in an effort to better understand the role of phytoplankton aerosol emissions on Earth's energy budget.
Colin Dermot O'Dowd is an Irish physicist and atmospheric scientist.