No. in
series | Title | Written by | Original air date |
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| 1 | "My Crime Is Your Crime" | Denis Marks | September 14, 1968 (1968-09-14) |
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| "A Bird Out of Hand" | George Kashdan |
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- My Crime Is Your Crime: Batman and Robin are thrown for a loop when they arrest the Joker and the Penguin for crimes they did not commit.
- A Bird Out of Hand: The Penguin unexpectedly goes straight.
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| 2 | "The Cool, Cruel Mr. Freeze" | Denis Marks | September 21, 1968 (1968-09-21) |
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| "The Joke's on Robin" | George Kashdan |
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- The Cool, Cruel Mr. Freeze: Mr. Freeze causes havoc in his quest to ransom $1 billion from the city and he uses a captured whale for his caper.
- The Joke's on Robin: Robin seems to lose his skills after he rescues a man from drowning thanks to the Joker. This segment features Batgirl.
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| 3 | "How Many Herring in a Wheelbarrow?" | Bill Keenen | September 28, 1968 (1968-09-28) |
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| "In Again, Out Again Penguin" |
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- How Many Herring in a Wheelbarrow?: The Joker raids technology firms to build a powerful solar mirror he can use as a laser weapon.
- In Again, Out Again Penguin: The Penguin commits crimes, even though he is supposedly incarcerated, and frames Batman and Robin for them.
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| 4 | "The Nine Lives of Batman" | Denis Marks | October 5, 1968 (1968-10-05) |
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| "Long John Joker" | Bob Haney |
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- The Nine Lives of Batman: Catwoman traps Batman and exposes him to a radioactive gas that will allow her to identify him in his secret identity.
- Long John Joker: The Joker makes a movie about pirates as cover to find the haul from a long-forgotten armored car theft. This segment features Batgirl.
The first segment of this episode features edited dialogue — in the show's syndicated run, as Catwoman and her henchmen pillage a jewelry exchange, it includes a line of narration, "The feline felon and her terrible tabbies indulge in an orgy of theft". This was changed in subsequent prints to "a spree of stealing". |
| 5 | "Bubi, Bubi, Who's Got the Ruby?" | Bill Keenen | October 12, 1968 (1968-10-12) |
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| "1001 Faces of the Riddler" | George Kashdan |
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- Bubi, Bubi, Who's Got the Ruby?: Bruce Wayne is captured by the Penguin in the robbery of a valuable ruby. Unfortunately for Penguin, Catwoman is also after the ruby. This segment features Batgirl.
- 1001 Faces of the Riddler: The Riddler becomes an expert at disguises to fool Batman and Robin.
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| 6 | "The Big Birthday Caper" | Bob Haney | October 19, 1968 (1968-10-19) |
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| "Two Penguins Too Many" | Bill Keenen |
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- The Big Birthday Caper: The Riddler and the Penguin try to expose Batman by staging a mammoth birthday party for him and wealthy businessman Bruce Wayne.
- Two Penguins Too Many: Real penguins wind up helping the Penguin and the Joker to outwit Batman and Robin.
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| 7 | "Partners in Peril" | George Kashdan | October 26, 1968 (1968-10-26) |
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| "The Underworld Underground Caper" | Bill Butler |
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- Partners in Peril: A deadly contest is staged by the Joker, the Penguin, and the Riddler to one-up each other and gain control of Gotham City's criminal empire. This segment features Batgirl.
- The Underworld Underground Caper: The Riddler and Catwoman use an underground drill to commit robberies to trap Batman and Robin.
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| 8 | "Hizzoner the Joker" | Denis Marks | November 2, 1968 (1968-11-02) |
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| "Freeze's Frozen Vikings" |
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- Hizzoner the Joker: The Joker runs for mayor of Gotham City and is able to win.
- Freeze's Frozen Vikings: Mr. Freeze uses a Viking hoax to commit robberies.
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| 9 | "The Crime Computer" | Denis Marks | November 9, 1968 (1968-11-09) |
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| "The Great Scarecrow Scare" | Bill Butler |
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- The Crime Computer: The Penguin seizes a mammoth computer to use to outwit Batman and Robin.
- The Great Scarecrow Scare: The Scarecrow steals a painting and captures Batgirl as part of his plot to dispose of the Dynamic Duo.
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| 10 | "A Game of Cat and Mouse" | Bill Keenen | November 16, 1968 (1968-11-16) |
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| "Beware of Living Dolls" | Bob Haney |
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- A Game of Cat and Mouse: Catwoman steals the Crown Jewels, which the Joker is also after.
- Beware of Living Dolls: Dollman uses his dolls to pull off a crime spree.
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| 11 | "Will the Real Robin Please Stand Up" | Oscar Bensol | November 23, 1968 (1968-11-23) |
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| "He Who Swipes the Ice, Goes to the Cooler" | Bill Keenen |
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- Will the Real Robin Please Stand Up: A youth who bears a stunning resemblance to Robin is used by Catwoman when he ends up with amnesia.
- He Who Swipes the Ice, Goes to the Cooler: Mr. Freeze's diamond heist goes wrong.
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| 12 | "Simon the Pieman" | Denis Marks | November 30, 1968 (1968-11-30) |
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| "A Mad, Mad Tea Party" | George Kashdan |
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- Simon the Pieman: A flamboyant criminal pastry chef named Simon the Pieman and his gang steal valuables under the cover of the fairgrounds after they had gotten the Joker, the Penguin, the Riddler, Catwoman, and Mr. Freeze out of the way. This segment features Batgirl.
- A Mad, Mad Tea Party: The Mad Hatter starts an Alice in Wonderland-based gang in a plot to steal a priceless antique teapot to use as part of his mad tea party.
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| 13 | "From Catwoman with Love" | Bob Haney | December 7, 1968 (1968-12-07) |
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| "Perilous Playthings" | Oscar Bensol |
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- From Catwoman with Love: Catwoman sends Batman a cat for Valentine's Day, a cat with a collar that gives off radio waves. This segment features Batgirl.
- Perilous Playthings: Catwoman and her henchmen crash the production of Tom Thumb in Toyland and use toy-based plots to defeat the Dynamic Duo.
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| 14 | "A Perfidious Pieman Is Simon" | Oscar Bensol | December 14, 1968 (1968-12-14) |
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| "Cool, Cruel Christmas Caper" | Bob Haney |
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- A Perfidious Pieman Is Simon: Simon the Pieman steals four million Turkish coins and is pursued to an electrical plant. Features Batgirl.
- Cool, Cruel Christmas Caper: Mr. Freeze disguises himself as Santa Claus.
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| 15 | "The Fiendishly Frigid Fraud" | Denis Marks | December 21, 1968 (1968-12-21) |
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| "Enter the Judge" |
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- The Fiendishly Frigid Fraud: A freak bombardment of meteors made of pure ice allows Mr. Freeze to stage a mammoth hoax.
- Enter the Judge: An international criminal who is incarcerated on the island prison Satan Island ends up escaping disguised as a judge when his pardon is denied. Now he is going around crashing criminal trials, gaining the Cosgrove gang and other low-level crooks as his jury henchmen in a plot to eliminate all crimefighters.
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| 16 | "The Jigsaw Jeopardy" | Oscar Bensol | December 28, 1968 (1968-12-28) |
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| "Wrath of the Riddler" |
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- The Jigsaw Jeopardy: The Riddler plans to blow up Gotham City's art gallery and winds up trapping The Caped Crusaders as well. This segment fatures Batgirl.
- Wrath of the Riddler: The Riddler uses a construction site as his hideout. This segment features Batgirl.
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| 17 | "It Takes Two to Make a Team" | Denis Marks | January 4, 1969 (1969-01-04) |
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| "Opera Buffa" | Bob Haney |
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- It Takes Two to Make a Team: The Joker, the Penguin, and the Riddler are after an Inca treasure map. They plan to break up the Dynamic Duo by making Robin jealous of Batgirl.
- Opera Buffa: The Joker seemingly traps Batman and Robin, but is haunted by their apparent ghosts when he tries to steal a valuable tiara at an opera.
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