Polythiophenes (PTs) are polymerized thiophenes, a sulfur heterocycle. The parent PT is an insoluble colored solid with the formula (C4H2S)n. The rings are linked through the 2- and 5-positions. Poly(alkylthiophene)s have alkyl substituents at the 3- or 4-position(s). They are also colored solids, but tend to be soluble in organic solvents.
The term molecular recognition refers to the specific interaction between two or more molecules through noncovalent bonding such as hydrogen bonding, metal coordination, hydrophobic forces, van der Waals forces, π-π interactions, halogen bonding, or resonant interaction effects. In addition to these direct interactions, solvents can play a dominant indirect role in driving molecular recognition in solution. The host and guest involved in molecular recognition exhibit molecular complementarity. Exceptions are molecular containers, including e.g. nanotubes, in which portals essentially control selectivity.
James Mitchell Tour is an American chemist and nanotechnologist. He is a Professor of Chemistry, Professor of Materials Science and Nanoengineering, and Professor of Computer Science at Rice University in Houston, Texas.
Phaedon Avouris is a Greek chemical physicist and materials scientist. He is an IBM Fellow and was formerly the group leader for Nanometer Scale Science and Technology at the Thomas J. Watson Research Center in Yorktown Heights, New York.
In chemistry, solvatochromism is the phenomenon observed when the colour of a solution is different when the solute is dissolved in different solvents.
Explosives trace detectors (ETD) are explosive detection equipment able to detect explosives of small magnitude. The detection is accomplished by sampling non-visible "trace" amounts of particulates. Devices similar to ETDs are also used to detect narcotics. The equipment is used mainly in airports and other vulnerable areas considered susceptible to acts of unlawful interference.
The Fido explosives detector is a battery-powered, handheld sensory device that uses amplifying fluorescent polymer (AFP) materials to detect trace levels of high explosives like trinitrotoluene (TNT). It was developed by Nomadics, a subsidiary of ICX Technologies, in the early 2000s as part of the Defense Advanced Research Projects Agency's (DARPA) Dog's Nose program. The Fido explosives detector is considered the first artificial nose capable of detecting landmines in the real world. The device was named after its ability to detect explosive vapors at concentrations of parts per quadrillion, which is comparable to the sensitivity of a bomb-sniffing dog’s nose, i.e. the historical “gold standard” for finding concealed explosives.
Layer-by-layer (LbL) deposition is a thin film fabrication technique. The films are formed by depositing alternating layers of oppositely charged materials with wash steps in between. This can be accomplished by using various techniques such as immersion, spin, spray, electromagnetism, or fluidics.
Carbon nanotube chemistry involves chemical reactions, which are used to modify the properties of carbon nanotubes (CNTs). CNTs can be functionalized to attain desired properties that can be used in a wide variety of applications. The two main methods of CNT functionalization are covalent and non-covalent modifications.
A two-dimensional polymer (2DP) is a sheet-like monomolecular macromolecule consisting of laterally connected repeat units with end groups along all edges. This recent definition of 2DP is based on Hermann Staudinger's polymer concept from the 1920s. According to this, covalent long chain molecules ("Makromoleküle") do exist and are composed of a sequence of linearly connected repeat units and end groups at both termini.
Polyaspartic acid (PASA) is a biodegradable, water-soluble condensation polymer based on the amino acid aspartic acid. It is a biodegradable replacement for water softeners and related applications. PASA can be chemically crosslinked with a wide variety of methods to yield PASA hydrogels. The resulting hydrogels are pH-sensitive such that under acidic conditions, they shrink, while the swelling capacity increases under alkaline conditions.
Zhenan Bao is a chemical engineer. She serves as K. K. Lee Professor of Chemical Engineering at Stanford University, with courtesy appointments in Chemistry and Material Science and Engineering. She served as the Department Chair of Chemical Engineering from 2018 to 2022. Bao is known for her work on organic field-effect transistors and organic semiconductors, for applications including flexible electronics and electronic skin.
Timothy P. Lodge is an American polymer scientist.
A chemiresistor is a material that changes its electrical resistance in response to changes in the nearby chemical environment. Chemiresistors are a class of chemical sensors that rely on the direct chemical interaction between the sensing material and the analyte. The sensing material and the analyte can interact by covalent bonding, hydrogen bonding, or molecular recognition. Several different materials have chemiresistor properties: metal-oxide semiconductors, some conductive polymers, and nanomaterials like graphene, carbon nanotubes and nanoparticles. Typically these materials are used as partially selective sensors in devices like electronic tongues or electronic noses.
In materials and electric battery research, cobalt oxide nanoparticles usually refers to particles of cobalt(II,III) oxide Co
3O
4 of nanometer size, with various shapes and crystal structures.
Niveen M. Khashab is a Lebanese chemist and an associate Professor of chemical Sciences and engineering at King Abdullah University of Science and Technology in Saudi Arabia since 2009. She is a laureate of the 2017 L'Oréal-UNESCO Awards for Women in Science "for her contributions to innovative smart hybrid materials aimed at drug delivery and for developing new techniques to monitor intracellular antioxidant activity." She is also a fellow of the Royal Chemical Society, and a member of the American Chemical Society.
Anne J. McNeil is an American chemist who currently works at the University of Michigan, where she holds the position of Arthur F. Thurnau Professor of Chemistry and Macromolecular Science and Engineering. In 2017, McNeil was named a fellow of the American Association for the Advancement of Science (AAAS).
Klaus Müllen is a German chemist working in the fields of polymer chemistry, supramolecular chemistry and nanotechnology. He is known for the synthesis and exploration of the properties of graphene-like nanostructures and their potential applications in organic electronics.
A chemical sensor array is a sensor architecture with multiple sensor components that create a pattern for analyte detection from the additive responses of individual sensor components. There exist several types of chemical sensor arrays including electronic, optical, acoustic wave, and potentiometric devices. These chemical sensor arrays can employ multiple sensor types that are cross-reactive or tuned to sense specific analytes.
Katherine A. Mirica is an American chemist who is an associate professor at Dartmouth College. Her research considers materials chemistry, with a particular focus on environmental science and microelectronics.
