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Ulvöspinel | |
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![]() Ulvöspinel from Apollo 12 landing site, Oceanus Procellarum (Ocean of Storms) | |
General | |
Category | Oxide minerals Spinel group Spinel structural group |
Formula (repeating unit) | TiFe2+2O4 |
IMA symbol | Uspl |
Strunz classification | 4.BB.05 |
Crystal system | Cubic |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fd3m |
Identification | |
Color | Iron-black, brown in reflected light |
Crystal habit | Commonly as an exsolution in magnetite |
Mohs scale hardness | 5.5 – 6. |
Luster | Metallic |
Diaphaneity | Opaque |
Specific gravity | 4.78 |
References | [1] [2] [3] [4] |
Ulvöspinel or ulvite is an iron titanium oxide mineral with formula: Fe 2 Ti O 4 or TiFe2+2O4. It forms brown to black metallic isometric crystals with a Mohs hardness of 5.5 to 6. It belongs to the spinel group of minerals, as does magnetite, Fe3O4.
Ulvöspinel forms as solid solutions with magnetite at high temperatures and reducing conditions, and grains crystallized from some basalt-gabbro magmas are rich in the ulvöspinel component. The ulvöspinel component tends to oxidize to magnetite plus ilmenite during subsolidus cooling of the host rocks, and the ilmenite so produced may form apparent exsolution (trellis type) laminae in magnetite. The texture was once interpreted as indicating solid solution between ilmenite and magnetite, until the oxidation reaction and resultant textures were reproduced in laboratory experiments first described by Buddington and Lindsley (1964, Journal of Petrology 5, p. 310–357). The results are important to plate tectonics because magnetite is an important recorder of rock magnetism.
Ulvöspinel was first described by Fredrik Mogensen (1904–1978) [5] from a dolerite layered intrusion in the Ulvö Islands, Ångermanland, Sweden in 1943. The locality is an iron, titanium and vanadium mining area that has been active since the 17th century. [6] It is common in titaniferous magnetite iron ore deposits. It also occurs in kimberlites, in some reduced iron-bearing basalts and is common in lunar basalts.
Hematite, also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of Fe
2O
3. It has the same crystal structure as corundum (Al
2O
3) and ilmenite (FeTiO
3). With this it forms a complete solid solution at temperatures above 950 °C (1,740 °F).
Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.
Ilmenite is a titanium-iron oxide mineral with the idealized formula FeTiO
3. It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics.
Wüstite is a mineral form of mostly iron(II) oxide found with meteorites and native iron. It has a grey colour with a greenish tint in reflected light. Wüstite crystallizes in the isometric-hexoctahedral crystal system in opaque to translucent metallic grains. It has a Mohs hardness of 5 to 5.5 and a specific gravity of 5.88. Wüstite is a typical example of a non-stoichiometric compound.
Armalcolite is a titanium-rich mineral with the chemical formula (Mg,Fe2+)Ti2O5. It was first found at Tranquility Base on the Moon in 1969 during the Apollo 11 mission, and is named for Armstrong, Aldrin and Collins, the three Apollo 11 astronauts. Together with tranquillityite and pyroxferroite, it is one of three new minerals that were discovered on the Moon. Armalcolite was later identified at various locations on Earth and has been synthesized in the laboratory. (Tranquillityite and pyroxferroite were also later found at various locations on Earth). The synthesis requires low pressures, high temperatures and rapid quenching from about 1,000 °C to the ambient temperature. Armalcolite breaks down to a mixture of magnesium-rich ilmenite and rutile at temperatures below 1,000 °C, but the conversion slows down with cooling. Because of this quenching requirement, armalcolite is relatively rare and is usually found in association with ilmenite and rutile, among other minerals.
Periclase is a magnesium mineral that occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide (MgO). In nature it usually forms a solid solution with wüstite (FeO) and is then referred to as ferropericlase or magnesiowüstite.
Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO2) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass.
Cobaltite is an arsenide and sulfide mineral with the mineral formula CoAsS. It is the naming mineral of the cobaltite group of minerals, whose members structurally resemble pyrite (FeS2).
Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks. Cumulates can be deposited on top of other older cumulates of different composition and colour, typically giving the cumulate rock a layered or banded appearance.
Jacobsite is a manganese iron oxide mineral. It is in the spinel group and forms a solid solution series with magnetite. The chemical formula is (Mn,Mg)Fe2O4 or with oxidation states and substitutions: (Mn2+,Fe2+,Mg)(Fe3+,Mn3+)2O4.
Polydymite, Ni2+Ni23+S4, is a supergene thiospinel sulfide mineral associated with the weathering of primary pentlandite nickel sulfide.
In geology, a redox buffer is an assemblage of minerals or compounds that constrains oxygen fugacity as a function of temperature. Knowledge of the redox conditions (or equivalently, oxygen fugacities) at which a rock forms and evolves can be important for interpreting the rock history. Iron, sulfur, and manganese are three of the relatively abundant elements in the Earth's crust that occur in more than one oxidation state. For instance, iron, the fourth most abundant element in the crust, exists as native iron, ferrous iron (Fe2+), and ferric iron (Fe3+). The redox state of a rock affects the relative proportions of the oxidation states of these elements and hence may determine both the minerals present and their compositions. If a rock contains pure minerals that constitute a redox buffer, then the oxygen fugacity of equilibration is defined by one of the curves in the accompanying fugacity-temperature diagram.
Cafetite is a rare titanium oxide mineral with formula (Ca,Mg)(Fe,Al)
2Ti
4O
12·4(H
2O). It is named for its composition, Ca-Fe-Ti.
Kaersutite is a dark brown to black double chain calcic titanium bearing amphibole mineral with formula: NaCa2(Mg3Ti4+Al)(Si6Al2)O22(O)2.
Corkite is a phosphate mineral in the beudantite subgroup of the alunite group. Corkite is the phosphate analogue of beudantite and with it, a complete solid solution range exists. Corkite will also form a solid solution with kintoreite.
Pseudobrookite is an iron titanium oxide mineral with formula: Fe2TiO5 or (Fe3+,Fe2+)2(Ti,Fe2+)O5.
Ixiolite is an accessory oxide mineral found in granitic pegmatites. It is an oxide with the general chemical formula (Ta,Nb,Sn,Mn,Fe)4O8 or (Ta,Mn,Nb)O2.
Pyrophanite is a manganese titanium oxide mineral with formula: MnTiO3. It is a member of the ilmenite group. It is a deep red to greenish black mineral which crystallizes in the trigonal system.
Dorrite is a silicate mineral that is isostructural to the aenigmatite group. It is most chemically similar to the mineral rhönite [Ca2Mg5Ti(Al2Si4)O20], made distinct by a lack of titanium (Ti) and the presence of Fe3+. Dorrite is named for Dr. John (Jack) A. Dorr, a late professor at the University of Michigan that researched in outcrops where dorrite was found in 1982. This mineral is sub-metallic resembling colors of brownish-black, dark brown, to reddish brown.
Nelsonite is an igneous rock primarily constituted of ilmenite and apatite, with anatase, chlorite, phosphosiderite, talc and/or wavellite appearing as minor components. Rocks are equigranular with a grain size around 2 – 3 mm. The black ilmenite is slightly magnetic while the whitish apatite is not.