The Wothlytype was an alternative photographic printing process, the eponymous 1864 invention of the German Jacob Wothly, in which a mixture of uranium ammonio-nitrate (uranyl nitrate) and silver nitrate in collodion formed a light-sensitive layer.
It was a short-lived positive printing process proposed to remedy the recognised impermanence of albumen paper, and compared to which, it was considerably more light-sensitive. [1] [2]
Wothlytype printing-out-paper was superseded by collodio-chloride papers before the end of the 1860s.
The Wothlytype enabled positive prints to be made directly on paper. The photographic emulsion consisted of a special uranium collodion that replaced the iodide, the chlorine or silver bromide. [3] After exposure, the image was directly visible and was fixed immediately. Toning could be achieved in varying tones from deep blue-black to purple black. Sensitivity, efficiency and economy (reducing to degree the use of expensive silver) were advantages over competing processes. In addition, the collodion layer could also be transferred to ivory, wood, glass, porcelain and similar materials.
First, the uranium collodion was applied to the paper, which was done with a brush, sponge or in a sensitizing bath, depending on the type of paper. After exposure, the images were immersed in an acidic bath for cleaning. The prints were washed to remove the acid, then immersed in a toning bath and then in a fixer. These two operations could also be combined. Finally, the images were washed a second time.
The British patent made public these details in the specification;
To one pound of plain collodion add from two to three ounces of nitrate of uranium and from 20 to 60 grains of nitrate of silver. The paper is prepared for printing by simply pouring the above sensitized collodion upon its surface, and hanging the sheets to dry in the dark. The printing is accomplished by exposing the paper to light under the negative in the usual manner, and for about the usual time required for silvered paper; print until the desired depth is reached. It is not necessary, as in the ordinary process, to print the positive to a greater intensity of color than the fixed picture is intended to have. After printing immerse the picture in a bath of acetic acid for about ten minutes, or until that portion of the salts not acted upon by the light has been dissolved. The picture is now fixed and finished by thorough washing or rubbing with a sponge or brush, or by rinsing in pure water; then dry. Changes in the tone of the picture to suit the taste may be made before drying, by using a bath of chloride of gold, or of hyposulphite of soda. [4]
Richard Kingham published further instructions for the amateur in 1865. [5]
Wothly was a portrait photographer in business before 1853 and working in ambrotypes, whose studio was in Theaterplatz in Aachen. He went on in 1860 to make improvements to Woodward's solar camera. [6] Even before Wothly, numerous photographers had tried to use uranium salts in photography without lasting success. Wothly in 1864 introduced his new uranium platinum collodion process for positive paper images, in which he used platinum and palladium compounds to reduce the uranium salt. The Wothlytype was patented in Germany, America (15 August 1865), [7] Belgium (15 February 1865/No. 17147), England, France (24 September 1864), [8] [9] [10] Portugal [1] and Spain.
For France and Belgium, the Société française de Wothlytypie, founded specifically for this purpose by Emmanuel Mangel du Mesnil, took over licensing and distribution. [11]
The Photographic News of 7 October 1864 (in an article reproduced in The Times and Scientific American [12] ) hailed it, and its novel use of collodion on paper, as a valuable improvement;
The new process which has been discovered in Germany by Herr Wothly, and from him has been named 'Wothlytype,' discards nitrate of silver, and discards albumen. For the former it uses a double salt of uranium, the name of which is at present kept secret; for the latter it uses collodion. We have explained that by the ordinary method, the paper to be printed is sized with albumen, and the surface of the albumen receives the silver preparation, which is sensitive to the light, and shows the printed image. The paper thus does not receive the image, but is, as it were, a mere bed on which lies the material that does receive it. By the substitution of collodion for albumen, a different result is reached. In the first place, the film of collodion on the paper yields a beautiful smooth surface on which to receive the image, and the result is, that pictures are printed upon it with wonderful delicacy. In the second place, the collodion, before it is washed upon the paper, is rendered sensitive by being combined with the salt of uranium. The sensitiveness, therefore, is not on the surface alone of the collodion film, it is in the film itself, and so completely passes through it, that even if it be peeled away from the paper, the image which it receives will be found on the paper beneath. The vehicle thus employed is not less superior to all others yet known for receiving the negative image on paper, than it is to all others yet known for receiving the negative image on glass. The metallic salt which combines with it has also rare merits. In the first place, the manipulations are very simple and easy – far more so than in the silver printing process, and thus the labour saved is considerable. Next, the paper, when rendered sensitive for printing, or 'sensitised,' as the photographers say, keeps pertectly for two or even three weeks, an immense boon to amateurs, who can thus have their stock of printing paper 'sensitised' for them; whereas, at present, when the paper receives the sensitive preparation, it has to be used almost immediately, and will not keep more than a day or two. Thirdly, the color and tone obtained are very various, including every shade that can be got by the ordinary silver plan; but, in addition, it has the advantage of being able to print any number of impressions of exactly the same color, and of doing away with all such difficulties as show themselves in mealiness and irregular toning. The precision of result is a great point. By the silver process, the results are never certain, and even when the print comes out perfect from the frame, the subsequent process of washing and fixing go seriously to alter it. Lastly, the permanent character of the new method is very remarkable. Nobody seems to know exactly why the old silver process gives way--whether it be on account of the albumen, or the nitrate of silver, or the hyposulphite of soda. We only know, that so many of the prints prepared by the old method fall away, that no reliance can be placed in those which seem to stand firm. [13]
Despite such claims, William Henry Fox Talbot in The British Journal of Photography shared his disappointment that "that the Wothlytype process produces an image consisting mainly of silver, for the first accounts of it were calculated to give a contrary impression. Nevertheless I believe it to be a valuable contribution to science." The Wothlytype proved also to suffer from fading. [2] John Werge recounted in 1890 how;
... the Wothlytype printing process was introduced to the notice of photographers and the public [in 1864]: first, by a blatant article in the Times, which was both inaccurate and misleading, for it stated that both nitrate of silver and hyposulphite of soda were dispensed within the process; secondly, by the issue of advertisements and prospectuses for the formation of a Limited Liability Company. I went to the Patent Office and examined the specification, and found that both nitrate of silver and hyposulphite of soda were essential to the practice of the process, and that there was no greater guarantee of permanency in the use of the Wothlytype than in ordinary silver printing. [14]
Wothlytype was considered dangerous and controversial. [15] Since Wothly suggested the use of the ingredients and spent years experimenting with improvements to his process, it is unclear whether Wothly's early death in 1873 at the age of 50 was due to his experiments with this radioactive element or, as previously suspected, to the loss of his fortune following the bankruptcy of his banker.
After Wothly's death the Wothlytype disappeared from the market.
Uranyl nitrate is an oxidizing and highly toxic compound. When ingested, it causes severe chronic kidney disease and acute tubular necrosis and is a lymphocyte mitogen. Target organs include the kidneys, liver, lungs and brain. It also represents a severe fire and explosion risk when heated or subjected to shock in contact with oxidizable substances. After uranium was recognized as the cause of the so-called photographer's disease (nephritis and gastritis), this element was hardly ever used in photography.
The following list comprises significant milestones in the development of photography technology.
Calotype or talbotype is an early photographic process introduced in 1841 by William Henry Fox Talbot, using paper coated with silver iodide. Paper texture effects in calotype photography limit the ability of this early process to record low contrast details and textures. The term calotype comes from the Ancient Greek καλός, "beautiful", and τύπος, "impression".
William Henry Fox Talbot FRS FRSE FRAS was an English scientist, inventor, and photography pioneer who invented the salted paper and calotype processes, precursors to photographic processes of the later 19th and 20th centuries. His work in the 1840s on photomechanical reproduction led to the creation of the photoglyphic engraving process, the precursor to photogravure. He was the holder of a controversial patent that affected the early development of commercial photography in Britain. He was also a noted photographer who contributed to the development of photography as an artistic medium. He published The Pencil of Nature (1844–1846), which was illustrated with original salted paper prints from his calotype negatives and made some important early photographs of Oxford, Paris, Reading, and York.
The collodion process is an early photographic process. The collodion process, mostly synonymous with the "collodion wet plate process", requires the photographic material to be coated, sensitized, exposed, and developed within the span of about fifteen minutes, necessitating a portable darkroom for use in the field. Collodion is normally used in its wet form, but it can also be used in dry form, at the cost of greatly increased exposure time. The increased exposure time made the dry form unsuitable for the usual portraiture work of most professional photographers of the 19th century. The use of the dry form was therefore mostly confined to landscape photography and other special applications where minutes-long exposure times were tolerable.
Collodion is a flammable, syrupy solution of nitrocellulose in ether and alcohol. There are two basic types: flexible and non-flexible. The flexible type is often used as a surgical dressing or to hold dressings in place. When painted on the skin, collodion dries to form a flexible nitrocellulose film. While it is initially colorless, it discolors over time. Non-flexible collodion is often used in theatrical make-up. Collodion was also the basis of most wet-plate photography until it was superseded by modern gelatin emulsions.
The albumen print, also called albumen silver print, was published in January 1847 by Louis Désiré Blanquart-Evrard, and was the first commercially exploitable method of producing a photographic print on a paper base from a negative. It used the albumen found in egg whites to bind the photographic chemicals to the paper and became the dominant form of photographic positives from 1855 to the start of the 20th century, with a peak in the 1860–90 period. During the mid-19th century, the carte de visite became one of the more popular uses of the albumen method. In the 19th century, E. & H. T. Anthony & Company were the largest makers and distributors of albumen photographic prints and paper in the United States.
The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. The "dry plate" gelatin process was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.
An enlarger is a specialized transparency projector used to produce photographic prints from film or glass negatives, or from transparencies.
Photogravure is a process for printing photographs, also sometimes used for reproductive intaglio printmaking. It is a photo-mechanical process whereby a copper plate is grained and then coated with a light-sensitive gelatin tissue which had been exposed to a film positive, and then etched, resulting in a high quality intaglio plate that can reproduce detailed continuous tones of a photograph.
Platinum prints, also called platinotypes, are photographic prints made by a monochrome printing process involving platinum.
The ambrotype also known as a collodion positive in the UK, is a positive photograph on glass made by a variant of the wet plate collodion process. Like a print on paper, it is viewed by reflected light. Like the daguerreotype, which it replaced, and like the prints produced by a Polaroid camera, each is a unique original that could only be duplicated by using a camera to copy it.
A tintype, also known as a melainotype or ferrotype, is a photograph made by creating a direct positive on a thin sheet of metal coated with a dark lacquer or enamel and used as the support for the photographic emulsion. Tintypes enjoyed their widest use during the 1860s and 1870s, but lesser use of the medium persisted into the early 20th century and it has been revived as a novelty and fine art form in the 21st.
The history of photography began with the discovery of two critical principles: camera obscura image projection and the observation that some substances are visibly altered by exposure to light. There are no artifacts or descriptions that indicate any attempt to capture images with light sensitive materials prior to the 18th century.
Uranyl nitrate is a water-soluble yellow uranium salt with the formula UO2(NO3)2 · n H2O. The hexa-, tri-, and dihydrates are known. The compound is mainly of interest because it is an intermediate in the preparation of nuclear fuels.
A Woodburytype is both a printing process and the print that it produces. In technical terms, the process is a photomechanical rather than a photographic one, because sensitivity to light plays no role in the actual printing. The process produces very high quality continuous tone images in monochrome, with surfaces that show a slight relief effect. Essentially, a Woodburytype is a mold produced copy of an original photographic negative with a tonal range similar to a Carbon print.
Monochrome photography is photography where each position on an image can record and show a different amount of light, but not a different hue. It includes all forms of black-and-white photography, which produce images containing shades of neutral grey ranging from black to white. Other hues besides grey, such as sepia, cyan, blue, or brown can also be used in monochrome photography. In the contemporary world, monochrome photography is mostly used for artistic purposes and certain technical imaging applications, rather than for visually accurate reproduction of scenes.
The salt print was the dominant paper-based photographic process for producing positive prints from 1839 until approximately 1860.
Farnham Maxwell-Lyte FRSC was an English chemist and the pioneer of a number of techniques in photographic processing. As a photographer he is known for his views of the French Pyrenees.
Paper texture effects in calotype photography limit the ability of this early process to record low contrast details and textures. A calotype is a photographic negative produced on uncoated paper. An important feature is that a relatively short exposure in a camera produces a latent image that is subsequently made visible by development. Then positive images for viewing are obtained by contact printing. This technique was in use principally from 1840 into the 1850s, when it was displaced by photography on glass. Skilled photographers were able to achieve dramatic results with the calotype process, and the reason for its eclipse may not be evident from viewing reproductions of early work.
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