Californium tetrafluoride

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Californium tetrafluoride
Kristallstruktur Yttrium(III)-fluorid.png
Names
Other names
Californium tetrafluoride
Identifiers
3D model (JSmol)
  • InChI=1S/Cf.4FH/h;4*1H/q+4;;;;/p-4
    Key: OXMFOZUWMXDEGZ-UHFFFAOYSA-J
  • [Cf+4].[F-].[F-].[F-].[F-]
Properties
CfF4
Molar mass 327 g·mol−1
Appearancelight green solid
Density g/cm3
Structure
monoclinic
Related compounds
Related compounds
Berkelium tetrafluoride
Einsteinium tetrafluoride
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Radioactive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Californium tetrafluoride is a binary inorganic compound of californium and fluorine with the formula CfF4. [1]

Contents

Synthesis

The compound can be prepared from Cf2O3 and F2 at 400 °C. [2]

2Cf2O3 + 8F2 → 4CfF4 + 3O2

Also, β-decay of BkF4.

Physical properties

Californium tetrafluoride is a light green solid. Possesses a monoclinic UF4 structure. [3] [2]


Chemical properties

CfF4 decomposes to californium trifluoride when heated:

2CfF4 → 2CfF3 + 2F

Related Research Articles

<span class="mw-page-title-main">Berkelium</span> Chemical element, symbol Bk and atomic number 97

Berkelium is a synthetic chemical element; it has symbol Bk and atomic number 97. It is a member of the actinide and transuranium element series. It is named after the city of Berkeley, California, the location of the Lawrence Berkeley National Laboratory where it was discovered in December 1949. Berkelium was the fifth transuranium element discovered after neptunium, plutonium, curium and americium.

<span class="mw-page-title-main">Zirconium tetrafluoride</span> Chemical compound

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula (ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride' is a component of ZBLAN fluoride glass.

<span class="mw-page-title-main">Selenium tetrafluoride</span> Chemical compound

Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.

<span class="mw-page-title-main">Manganese(IV) fluoride</span> Chemical compound

Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine.

A tetrafluoride is a chemical compound with four fluorines in its formula.

<span class="mw-page-title-main">Californium compounds</span>

Few compounds of californium have been made and studied. The only californium ion that is stable in aqueous solutions is the californium(III) cation. The other two oxidation states are IV (strong oxidizing agents) and II (strong reducing agents). The element forms a water-soluble chloride, nitrate, perchlorate, and sulfate and is precipitated as a fluoride, oxalate or hydroxide. If problems of availability of the element could be overcome, then CfBr2 and CfI2 would likely be stable.

<span class="mw-page-title-main">Berkelium compounds</span> Chemical compounds

Berkelium forms a number of chemical compounds, where it normally exists in an oxidation state of +3 or +4, and behaves similarly to its lanthanide analogue, terbium. Like all actinides, berkelium easily dissolves in various aqueous inorganic acids, liberating gaseous hydrogen and converting into the trivalent oxidation state. This trivalent state is the most stable, especially in aqueous solutions, but tetravalent berkelium compounds are also known. The existence of divalent berkelium salts is uncertain and has only been reported in mixed lanthanum chloride-strontium chloride melts. Aqueous solutions of Bk3+ ions are green in most acids. The color of the Bk4+ ions is yellow in hydrochloric acid and orange-yellow in sulfuric acid. Berkelium does not react rapidly with oxygen at room temperature, possibly due to the formation of a protective oxide surface layer; however, it reacts with molten metals, hydrogen, halogens, chalcogens and pnictogens to form various binary compounds. Berkelium can also form several organometallic compounds.

<span class="mw-page-title-main">Germanium tetrafluoride</span> Chemical compound

Germanium tetrafluoride (GeF4) is a chemical compound of germanium and fluorine. It is a colorless gas.

<span class="mw-page-title-main">Hafnium tetrafluoride</span> Chemical compound

Hafnium tetrafluoride is the inorganic compound with the formula HfF4. It is a white solid. It adopts the same structure as zirconium tetrafluoride, with 8-coordinate Hf(IV) centers.

<span class="mw-page-title-main">Chromium(IV) fluoride</span> Chemical compound

Chromium(IV) fluoride is an inorganic compound with the chemical formula CrF4. It has a dark greenish-black color when solid. It rapidly hydrolysizes in presence of moisture in air or directly in water.

<span class="mw-page-title-main">Platinum tetrafluoride</span> Chemical compound

Platinum tetrafluoride is the inorganic compound with the chemical formula PtF
4
. In the solid state, the compound features platinum(IV) in octahedral coordination geometry.

<span class="mw-page-title-main">Californium(III) chloride</span> Chemical compound

Californium(III) chloride is an inorganic compound with a chemical formula CfCl3. As in californium oxide (Cf2O3) and other californium halides, including californium(III) fluoride (CfF3) and iodide (CfI3), the californium atom has an oxidation state of +3.

<span class="mw-page-title-main">Californium(III) bromide</span> Chemical compound

Californium(III) bromide is an inorganic compound, a salt with a chemical formula CfBr3. Like in californium oxide (Cf2O3) and other californium halides, including californium(III) fluoride (CfF3), californium(III) chloride, and californium(III) iodide (CfI3), the californium atom has an oxidation state of +3.

<span class="mw-page-title-main">Berkelium tetrafluoride</span> Chemical compound

Berkelium tetrafluoride is a binary inorganic compound of berkelium and fluorine with the chemical formula BkF4.

<span class="mw-page-title-main">Californium(III) fluoride</span> Chemical compound

Californium(III) fluoride is a binary inorganic compound of californium and fluorine with the formula CfF
3

Californium(II) iodide is a binary inorganic compound of californium and iodine with the formula CfI
2
.

<span class="mw-page-title-main">Curium(IV) fluoride</span> Chemical compound

Curium(IV) fluoride is an inorganic chemical compound, a salt of curium and fluorine with the chemical formula CmF4.

<span class="mw-page-title-main">Protactinium tetrafluoride</span> Chemical compound

Protactinium tetrafluoride is a binary inorganic compound of protactinium metal and fluorine with the chemical formula PaF4.

Californium dichloride is a binary inorganic compound of californium metal and chlorine with the chemical formula CfCl2.

References

  1. "WebElements Periodic Table » Californium » californium tetrafluoride". winter.group.shef.ac.uk. Retrieved 3 April 2024.
  2. 1 2 Macintyre, Jane E. Dictionary of Inorganic Compounds, Volume 1. Chapman & Hall. p. 2826. Retrieved 3 April 2024.
  3. Chang, C.-T. P.; Haire, R. G.; Nave, S. E. (1 May 1990). "Magnetic susceptibility of californium fluorides". Physical Review B . 41 (13). doi:10.1103/physrevb.41.9045 . Retrieved 3 April 2024.