Baotite | |
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General | |
Category | Cyclosilicate |
Formula (repeating unit) | Ba4Ti4(Ti,Nb,Fe)4(Si4O12)O16Cl |
IMA symbol | Bao [1] |
Strunz classification | 9.CE.15 |
Crystal system | Tetragonal |
Crystal class | Dipyramidal (4/m) H-M symbol: (4/m) |
Space group | I41/a |
Identification | |
Color | light brown to black |
Crystal habit | anhedral to subhedral, prismatic and striated parallel to (001) |
Cleavage | fair on {110} |
Fracture | hackly |
Tenacity | brittle |
Mohs scale hardness | 6 |
Luster | vitreous |
Density | 4.42-4.71 g/mL (measured), 4.69 g/mL (calculated) |
Optical properties | Uniaxial (+) |
Refractive index | nω = 1.94, nε > 2.00 |
Pleochroism | strong |
Absorption spectra | E > O |
References | [2] [3] |
Baotite Ba 4 Ti 4(Ti, Nb, Fe)4(Si 4 O 12)O16 Cl is a rare mineral recognized as having a unique four-fold silicate ring. [4] Crystals are tetragonal, though commonly deformed to the extent of appearing monoclinic. Named for the locality of first discovery, Baotou, China, baotite has been found in hydrothermal veins and alkalic rocks in various locations around the world.
Simonov first determined the crystal structure of baotite in which (Ti, Nb, Fe)-octahedra share edges, forming chains and cross-linking at the corners forming a 4-fold screw axis in the (001); these columns are analogous to those in rutile. [5] Four silicate tetrahedra share corners creating characteristic rings in the plane perpendicular to the c axis. [6] The barium cation is between the rings and rutile columns, while chloride fills the void between each pair of rings. [7] Chlorine's presence is not necessary for the structure to balance electrostatically.
The first sample of baotite was found with galena, pyrite, albite, aegirine and alkali amphiboles in a quartz vein cutting quartzite [8] at the Bayan Obo Mine in China. Grains from Ravalli County, Montana were found in a thin calcite crust on masses of eschynite within a carbonatic vein. [9] Baotite also occurs at Haast River, New Zealand as an accessory phase of carbonatite, fenite and hydrothermal fluid veins associated with a dike swarm. [7] The dike intrusion of mantle-derived magmas [7] can likely be attributed to the close proximity of the Alpine fault plate boundary across South Island, New Zealand.
Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.
Brookite is the orthorhombic variant of titanium dioxide (TiO2), which occurs in four known natural polymorphic forms (minerals with the same composition but different structure). The other three of these forms are akaogiite (monoclinic), anatase (tetragonal) and rutile (tetragonal). Brookite is rare compared to anatase and rutile and, like these forms, it exhibits photocatalytic activity. Brookite also has a larger cell volume than either anatase or rutile, with 8 TiO2 groups per unit cell, compared with 4 for anatase and 2 for rutile. Iron (Fe), tantalum (Ta) and niobium (Nb) are common impurities in brookite.
Armalcolite is a titanium-rich mineral with the chemical formula (Mg,Fe2+)Ti2O5. It was first found at Tranquility Base on the Moon in 1969 during the Apollo 11 mission, and is named for Armstrong, Aldrin and Collins, the three Apollo 11 astronauts. Together with tranquillityite and pyroxferroite, it is one of three new minerals that were discovered on the Moon. Armalcolite was later identified at various locations on Earth and has been synthesized in the laboratory. (Tranquillityite and pyroxferroite were also later found at various locations on Earth). The synthesis requires low pressures, high temperatures and rapid quenching from about 1,000 °C to the ambient temperature. Armalcolite breaks down to a mixture of magnesium-rich ilmenite and rutile at temperatures below 1,000 °C, but the conversion slows down with cooling. Because of this quenching requirement, armalcolite is relatively rare and is usually found in association with ilmenite and rutile, among other minerals.
Zinnwaldite, KLiFeAl(AlSi3)O10(OH,F)2, potassium lithium iron aluminium silicate hydroxide fluoride is a silicate mineral in the mica group. The IMA status is as a series between siderophyllite (KFe2Al(Al2Si2)O10(F,OH)2) and polylithionite (KLi2AlSi4O10(F,OH)2) and not considered a valid mineral species.
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.
Carbonatite is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification.
Triplite is a rare phosphate mineral with formula: (Mn, Fe)2PO4(F, OH). It occurs in phosphate-rich granitic pegmatites typically as irregular brown opaque masses. Triplite was first described in 1813 for an occurrence in Chanteloube, Limousin, France. The name is from the Greek triplos for triple, in reference to the three cleavage directions. In color and appearance, it is very similar to rhodocrosite, another manganese bearing mineral. Chemically, it is also quite similar to triploidite the difference being that triplite is fluorine dominant while triploidite is hydroxide dominant.
Miarolitic cavities are typically crystal-lined irregular cavities or vugs most commonly found in granitic pegmatites, and also in a variety of igneous rocks. The central portions of pegmatites are often miarolitic as the pegmatite dike crystallizes from the outside walls toward the center. The volatile portion of the magma is gradually excluded from the forming crystal phases until it becomes trapped within the body and forms the cavities which often contain minerals of elements incompatible with the typical silicate granitic mineralogy.
Partheite or parthéite is a calcium aluminium silicate and a member of the zeolite group of minerals, a group of silicates with large open channels throughout the crystal structure, which allow passage of liquids and gasses through the mineral. It was first discovered in 1979 in rodingitic dikes in an ophiolite zone of the Taurus Mountains in southwest Turkey. The second discovery occurred in gabbro-pegmatites in the Ural Mountains, Russia. Since its discovery and naming, the chemical formula for partheite has been revised from CaAl2Si2O8·2H2O to include not only water but hydroxyl groups as well. The framework of the mineral is interrupted due to these hydroxyl groups attaching themselves to aluminum centered oxygen tetrahedra. This type of interrupted framework is known in only one other zeolite, the mineral roggianite. As a silicate based mineral with the properties of a zeolite, partheite was first described as zeolite-like in 1984 and listed as a zeolite in 1985. Partheite and lawsonite are polymorphs. Associated minerals include prehnite, thomsonite, augite, chlorite and tremolite.
Huttonite is a thorium nesosilicate mineral with the chemical formula ThSiO4 and which crystallizes in the monoclinic system. It is dimorphous with tetragonal thorite, and isostructual with monazite. An uncommon mineral, huttonite forms transparent or translucent cream–colored crystals. It was first identified in samples of beach sands from the West Coast region of New Zealand by the mineralogist Colin Osborne Hutton (1910–1971). Owing to its rarity, huttonite is not an industrially useful mineral.
Vlasovite is a rare inosilicate (chain silicate) mineral with sodium and zirconium, with the chemical formula Na2ZrSi4O11. It was discovered in 1961 at Vavnbed Mountain in the Lovozero Massif, in the Northern Region of Russia. The researchers who first identified it, R P Tikhonenkova and M E Kazakova, named it for Kuzma Aleksevich Vlasov (1905–1964), a Russian mineralogist and geochemist who studied the Lovozero massif, and who was the founder of the Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Moscow, Russia.
Cookeite is a mineral species of the silicate group and the phyllosilicate subgroup, part of the chlorite family, with the formula LiAl4(Si3Al)O10(OH)8. This soft, low-density mineral of variable color has a crystalline structure made up of alternating layers LiAl2(OH)6 and Al2O4(OH)2Si8O12 having several polytypes. Cookeite is often found as a product of hydrothermal alteration of silicates in pegmatites. It forms at relatively low temperatures (below 200 °C) and variable pressures.
Ixiolite is an accessory oxide mineral found in granitic pegmatites. It is an oxide with the general chemical formula (Ta,Nb,Sn,Mn,Fe)4O8 or (Ta,Mn,Nb)O2.
Tumchaite, Na2(Zr,Sn)Si4O11·H2O, is a colorless to white monoclinic phyllosilicate mineral. It is associated with calcite, dolomite, and pyrite in the late dolomite-calcite carbonatites. It can be transparent to translucent; has a vitreous luster; and has perfect cleavage on {100}. Its hardness is 4.5, between fluorite and apatite. Tumchaite is isotypic with penkvilksite. The structure of the mineral is identified by silicate sheets parallel {100}, formed by alternation of clockwise and counterclockwise growing spiral chains of corner-sharing SiO4 tetrahedra. Tumchaite is named for the river Tumcha near Vuoriyarvi massif.
Lomonosovite is a phosphate–silicate mineral with the idealized formula Na10Ti4(Si2O7)2(PO4)2O4 early Na5Ti2(Si2O7)(PO4)O2 or Na2Ti2Si2O9*Na3PO4.
Wöhlerite, also known as woehlerite or wohlerite, is a member of the amphibole supergroup, and the wöhlerite subgroup within it. It was named after German chemist Friedrich Wöhler. It was first described by Scheerer in 1843, but the crystal structure was later solved by Mellino & Merlino in 1979. Once approved, it was grandfathered by the IMA.
Uranopolycrase is an oxide mineral first discovered in the Fonte del Prete vein of a pegmatite vein in San Piero in Campo, Elba Island, Tuscany, Italy. Uranopolycrase is a member of the Euxenite Group and is the uranium bearing analog of polycrase-(Y). The type specimen is almost entirely metamict. The ideal formula for uranopolycrase is (U,Y)(Ti,Nb)2O6. The mineral has been approved by the Commission on New Minerals and Mineral Names of the International Mineralogical Association to be named uranopolycrase for its similarity to polycrase-(Y) and was approved 5 December, 1991.