Baotite

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Baotite
Baotite-661893.jpg
Baotite from Sheep Creek, Mineral Point District, Ravalli County, Montana
General
Category Cyclosilicate
Formula
(repeating unit)
Ba4Ti4(Ti,Nb,Fe)4(Si4O12)O16Cl
IMA symbol Bao [1]
Strunz classification 9.CE.15
Crystal system Tetragonal
Crystal class Dipyramidal (4/m)
H-M symbol: (4/m)
Space group I41/a
Identification
Colorlight brown to black
Crystal habit anhedral to subhedral, prismatic and striated parallel to (001)
Cleavage fair on {110}
Fracture hackly
Tenacity brittle
Mohs scale hardness6
Luster vitreous
Density 4.42-4.71 g/mL (measured),
4.69 g/mL (calculated)
Optical propertiesUniaxial (+)
Refractive index nω = 1.94,
nε > 2.00
Pleochroism strong
Absorption spectra E > O
References [2] [3]

Baotite Ba 4 Ti 4(Ti, Nb, Fe)4(Si 4 O 12)O16 Cl is a rare mineral recognized as having a unique four-fold silicate ring. [4] Crystals are tetragonal, though commonly deformed to the extent of appearing monoclinic. Named for the locality of first discovery, Baotou, China, baotite has been found in hydrothermal veins and alkalic rocks in various locations around the world.

Contents

Structure

Simonov first determined the crystal structure of baotite in which (Ti, Nb, Fe)-octahedra share edges, forming chains and cross-linking at the corners forming a 4-fold screw axis in the (001); these columns are analogous to those in rutile. [5] Four silicate tetrahedra share corners creating characteristic rings in the plane perpendicular to the c axis. [6] The barium cation is between the rings and rutile columns, while chloride fills the void between each pair of rings. [7] Chlorine's presence is not necessary for the structure to balance electrostatically.

Geologic occurrence

The first sample of baotite was found with galena, pyrite, albite, aegirine and alkali amphiboles in a quartz vein cutting quartzite [8] at the Bayan Obo Mine in China. Grains from Ravalli County, Montana were found in a thin calcite crust on masses of eschynite within a carbonatic vein. [9] Baotite also occurs at Haast River, New Zealand as an accessory phase of carbonatite, fenite and hydrothermal fluid veins associated with a dike swarm. [7] The dike intrusion of mantle-derived magmas [7] can likely be attributed to the close proximity of the Alpine fault plate boundary across South Island, New Zealand.

Related Research Articles

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<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

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<span class="mw-page-title-main">Brookite</span>

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<span class="mw-page-title-main">Parthéite</span>

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<span class="mw-page-title-main">Huttonite</span> Thorium nesosilicate mineral

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<span class="mw-page-title-main">Vlasovite</span> Silicate mineral

Vlasovite is a rare inosilicate (chain silicate) mineral with sodium and zirconium, with the chemical formula Na2ZrSi4O11. It was discovered in 1961 at Vavnbed Mountain in the Lovozero Massif, in the Northern Region of Russia. The researchers who first identified it, R P Tikhonenkova and M E Kazakova, named it for Kuzma Aleksevich Vlasov (1905–1964), a Russian mineralogist and geochemist who studied the Lovozero massif, and who was the founder of the Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Moscow, Russia.

<span class="mw-page-title-main">Cookeite</span> Mineral species of the silicate group and the phyllosilicate subgroup, part of the chlorite family.

Cookeite is a mineral species of the silicate group and the phyllosilicate subgroup, part of the chlorite family, with the formula LiAl4(Si3Al)O10(OH)8. This soft, low-density mineral of variable color has a crystalline structure made up of alternating layers LiAl2(OH)6 and Al2O4(OH)2Si8O12 having several polytypes. Cookeite is often found as a product of hydrothermal alteration of silicates in pegmatites. It forms at relatively low temperatures (below 200 °C) and variable pressures.

<span class="mw-page-title-main">Ixiolite</span>

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<span class="mw-page-title-main">Tumchaite</span>

Tumchaite, Na2(Zr,Sn)Si4O11·H2O, is a colorless to white monoclinic phyllosilicate mineral. It is associated with calcite, dolomite, and pyrite in the late dolomite-calcite carbonatites. It can be transparent to translucent; has a vitreous luster; and has perfect cleavage on {100}. Its hardness is 4.5, between fluorite and apatite. Tumchaite is isotypic with penkvilksite. The structure of the mineral is identified by silicate sheets parallel {100}, formed by alternation of clockwise and counterclockwise growing spiral chains of corner-sharing SiO4 tetrahedra. Tumchaite is named for the river Tumcha near Vuoriyarvi massif.

<span class="mw-page-title-main">Lomonosovite</span> Phosphate–silicate mineral

Lomonosovite is a phosphate–silicate mineral with the idealized formula Na10Ti4(Si2O7)2(PO4)2O4 early Na5Ti2(Si2O7)(PO4)O2 or Na2Ti2Si2O9*Na3PO4.

<span class="mw-page-title-main">Wöhlerite</span> Silicate mineral

Wöhlerite, also known as woehlerite or wohlerite, is a member of the amphibole supergroup, and the wöhlerite subgroup within it. It was named after German chemist Friedrich Wöhler. It was first described by Scheerer in 1843, but the crystal structure was later solved by Mellino & Merlino in 1979. Once approved, it was grandfathered by the IMA.

Uranopolycrase is an oxide mineral first discovered in the Fonte del Prete vein of a pegmatite vein in San Piero in Campo, Elba Island, Tuscany, Italy. Uranopolycrase is a member of the Euxenite Group and is the uranium bearing analog of polycrase-(Y). The type specimen is almost entirely metamict. The ideal formula for uranopolycrase is (U,Y)(Ti,Nb)2O6. The mineral has been approved by the Commission on New Minerals and Mineral Names of the International Mineralogical Association to be named uranopolycrase for its similarity to polycrase-(Y) and was approved 5 December, 1991.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. Anthony, J.W., Bideaux, R., Bladh, K., and Nichols, M. (2003) Baotite Ba4(Ti,Nb)8Si4O28Cl. Handbook of Mineralogy, Mineral Data Publishing (Republished by the Mineralogical Society of America).*Fact sheet
  4. Chakhmouradian, A.R. and Mitchell, R.H. (2002) The mineralogy of Ba- and Zr-rich alkaline pegmatites from Gordon Butte, Crazy Mountains (Montana, USA): comparisons between potassic and sodic agpaitic pegmatites. Contributions to Mineralogy and Petrography, 143, 93-114.
  5. Simonov, V.I. (1960) Baotite, a mineral with a metasillicate ring (Si4O12). Kristallografiya, 5, 544-546 (in Russian). Abs. in American Mineralogist, 46, 466, 1961.
  6. Shinno, I. and Li, Z. (1998) Mössbauer studies of baotite and bafertisite. Hyperfine Interactions, 116, 189-196.
  7. 1 2 3 Cooper, A.F. (1996) Nb-rich baotite in carbonatites and fenites at Haast River, New Zealand. Mineralogical Magazine, 60, 473-482.
  8. Peng, C.J. (1959) The discovery of several new minerals of rare elements. Ti-Chin Ko-hsuch, 10 (in Chinese). Abs. in American Mineralogist, 45, 754, 1960.
  9. Heinrich, E.W., Boyer, W.H. and Crowley, F.A. (1962) Baotite (Pou-t’ou-k’uang) from Ravalli County, Montana. American Mineralogist, 47, 987-993.