Bavenite

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Bavenite
Bavenite2 Cadalso.jpg
Bavenite. Aggregate of lamellar crystals, with pyrite microcrystals on them.Cadalso de los Vidrios (Madrid), Spain. 13 mm
General
Category Mineral
Formula
(repeating unit)
Ca4Be2Al2Si9O26(OH)2
IMA symbol Bvn
Strunz classification 9.DF.25
Dana classification 70.5.3.1
Crystal system Orthorhombic
Crystal class Pyramidal
H-M Symbol: mm2
Space group Am2a
Unit cell 2,250.52
Identification
ColorWhite, Green, Pink, Brown
Cleavage Perfect on {001}
Fair on {100}
Fracture Uneven
Mohs scale hardness5.5
Luster Vitreous - Pearly
Streak White
Diaphaneity Transparent to translucent
Density 2.7
Optical propertiesBiaxial (+)
Refractive index nα = 1.578 - 1.586
nβ = 1.579 - 1.586
nγ = 1.583 - 1.593
Birefringence 0.005 - 0.007
2V angle 22° - 60°
Dispersion Moderate
r < v
Ultraviolet fluorescence None
Solubility Unsoluble in acids

Bavenite is a calcium beryllium aluminosilicate, and it is a part of the Bavenite-Bohseite series. Its name originates from its type locality, which is Baveno, Italy. This mineral is approved by the IMA, and got grandfathered, meaning it is still believed to refer to a valid mineral species. [1] It was discovered in 1901 in a pink granite mined in Lago Maggiore. When bavenite was discovered, it was considered as a member of the zeolite series. Later it was removed from the series as unlike zeolites, bavenite loses the water stored in its crystal lattice in a way higher temperature, between 210 and 320 °C. It is a cheap mineral considering its rarity. [2]

Contents

Properties

Bavenite mainly consists of oxygen (48.11%), silicon (27.75%) and calcium (17.65%), and otherwise contains aluminum (3.48%), beryllium (2.81%) and hydrogen (0.22%). This mineral is weakly piezoelectric, and is not radioactive. It is a lamellar mineral, meaning it grows in layers that part into thin sheets. However, it is massive, meaning it is shapeless, so singular crystals can't be distinguished. It can also appear in radial aggregates, meaning it has a center from which crystals radiate without producing a stellar form. Crystals that grow in radial aggregates are separated and have different lengths generally. [3] In this case, crystal needles can grow from 1 mm to a few cms in size. It also appears as felted masses. Bavenite can be determined only with the help of infrared or x-ray. It is white usually, but other color variants can occur as well. [2] Due to the variation of the chemical composition of bavenite, different substitution mechanisms had been brought up. However, Canille managed to solve its structure thanks to Berry, who suggested direct Be ⇌ Al with electroneutrality. The T(3) site is occupied by Si and Be, and Be and Al were assigned to the T(2) and T(4) tetrahedra. Cannillo also proposed additional minor Be to replace Al at T(4). [4]

Environment

Bavenite is usually associated with beryl, phenakite, bertrandite, quartz, epidote, stibnite, albite, orthoclase, titanite, clinozoisite and tremolite. Although it was discovered in igneous rocks, later it was found in pegmatites as well. Bavenite can also occur in the Alps, where it was created as a product of the hydrothermal weathering of beryllyium-bearing minerals (mostly beryl) through metamorphism. In the latter case, the mineral occurs with zeolite and prehnite. [2] It can also form by low-temperature alteration of beryl and beryllium-bearing minerals, and generally forms in more alkali environments. [5] It can occur on quartz and feldspar in miarolitic pegmatites as a coating. It also occurs as a pseudomorph of beryl. There's a known case of it occurring from pneumatolytically altered syenites, where it grew into singular crystals on albite, up to 1.5 cms of size per crystal. The mineral was not pseudomorphic in this case. [4]

It is known in around 300 locations worldwide, with more than half located in the Alps. [1] The specimens from the Baveno quarries, the typical locality, are notable. In Spain, very high-quality specimens, relevant on a global scale, have been found in miarolitic cavities in the granite of several quarries in Cadalso de los Vidrios (Madrid). In the quarries of La Cabrera (Madrid), it appears as cottony-looking aggregates formed by capillary crystals. [6]

Related Research Articles

<span class="mw-page-title-main">Beryl</span> Gemstone: beryllium aluminium silicate

Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.

<span class="mw-page-title-main">Pegmatite</span> Igneous rock with very large interlocked crystals

A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase ( PLAJ-(ee)-ə-klayss, PLAYJ-, -⁠klayz) is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Euclase</span>

Euclase is a beryllium aluminium hydroxide silicate mineral (BeAlSiO4(OH)). It crystallizes in the monoclinic crystal system and is typically massive to fibrous as well as in slender prismatic crystals. It is related to beryl (Be3Al2Si6O18) and other beryllium minerals. It is a product of the decomposition of beryl in pegmatites.

<span class="mw-page-title-main">Brazilianite</span> Yellow-green phosphate mineral

Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.

<span class="mw-page-title-main">Phenakite</span>

Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2SiO4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are either lenticular or prismatic in habit: the lenticular habit is determined by the development of faces of several obtuse rhombohedra and the absence of prism faces. There is no cleavage, and the fracture is conchoidal. The Mohs hardness is high, being 7.5–8; the specific gravity is 2.96. The crystals are sometimes perfectly colorless and transparent, but more often they are greyish or yellowish and only translucent; occasionally they are pale rose-red. In general appearance the mineral is not unlike quartz, for which indeed it has been mistaken. Its name comes from Ancient Greek: φέναξ, romanized: phénax, meaning "deceiver" due to its close visual similarity to quartz, named by Nils Gustaf Nordenskiöld in 1833.

<span class="mw-page-title-main">Pezzottaite</span> Mineral species

Pezzottaite, marketed under the name raspberyl or raspberry beryl, is a mineral species first recognized by the International Mineralogical Association in September 2003. Pezzottaite is a caesium analogue of beryl, a silicate of caesium, beryllium, lithium and aluminium, with the chemical formula Cs(Be2Li)Al2Si6O18. Named after Italian geologist and mineralogist Federico Pezzotta, pezzottaite was first thought to be either red beryl or a new variety of beryl ("caesium beryl"); unlike actual beryl, however, pezzottaite contains lithium and crystallizes in the trigonal crystal system rather than the hexagonal system.

<span class="mw-page-title-main">Lazulite</span> Phosphate mineral

Lazulite ((Mg,Fe2+)Al2(PO4)2(OH)2) is a blue, phosphate mineral containing magnesium, iron, and aluminium phosphate. Lazulite forms one endmember of a solid solution series with the darker iron rich scorzalite.

<span class="mw-page-title-main">Lithiophilite</span>

Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.

<span class="mw-page-title-main">Thomsonite</span> Thomsonite series of the zeolite group

Thomsonite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, thomsonite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named thomsonite-Ca and thomsonite-Sr. Thomsonite-Ca, by far the more common of the two, is a hydrous sodium, calcium and aluminium silicate, NaCa2Al5Si5O20·6H2O. Strontium can substitute for the calcium and the appropriate species name depends on the dominant element. The species are visually indistinguishable and the series name thomsonite is used whenever testing has not been performed. Globally, thomsonite is one of the rarer zeolites.

<span class="mw-page-title-main">Zanazziite</span>

Zanazziite is a complex hydrated phosphate mineral from the roscherite group. It is a magnesium beryllium phosphate mineral. Zanazziite arises as barrel-shaped crystals and can reach up to 4 mm. It grows alongside quartz minerals. It is found in the crevices of Lavra da Ilha pegmatite, near Taquaral, in northeastern Minas Gerais, Brazil. Zanazziite is named after Pier F. Zanazzi. Zanazziite has an ideal chemical formula of Ca2Mg5Be4(PO4)6(OH)4·6H2O.

Miarolitic cavities are typically crystal-lined irregular cavities or vugs most commonly found in granitic pegmatites, and also in a variety of igneous rocks. The central portions of pegmatites are often miarolitic as the pegmatite dike crystallizes from the outside walls toward the center. The volatile portion of the magma is gradually excluded from the forming crystal phases until it becomes trapped within the body and forms the cavities which often contain minerals of elements incompatible with the typical silicate granitic mineralogy.

<span class="mw-page-title-main">Microlite</span>

Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is (Na,Ca)2Ta2O6(O,OH,F). Today it is a name of a group of oxide minerals of a similar stoichiometry having tantalum prevailing over titanium and niobium. The microlite group belongs to a large pyrochlore supergroup that occurs in pegmatites and constitutes an ore of tantalum. It has a Mohs hardness of 5.5 and a variable specific gravity of 4.2 to 6.4. It occurs as disseminated microscopic subtranslucent to opaque octahedral crystals with a refractive index of 2.0 to 2.2. Microlite is also called djalmaite, but both names are now obsolete.

<span class="mw-page-title-main">Bazzite</span> Blue mineral

Bazzite is a beryllium scandium cyclosilicate mineral with chemical formula Be3Sc2Si6O18. It crystallizes in the hexagonal crystal system typically as small blue hexagonal crystals up to 2 cm length. It has a Mohs hardness of 6.5–7 and a specific gravity of 2.77 to 2.85.

Bityite is considered a rare mineral, and it is an endmember to the margarite mica sub-group found within the phyllosilicate group. The mineral was first described by Antoine François Alfred Lacroix in 1908, and later its chemical composition was concluded by Professor Hugo Strunz. Bityite has a close association with beryl, and it generally crystallizes in pseudomorphs after it, or in cavities associated with reformed beryl crystals. The mineral is considered a late-stage constituent in lithium bearing pegmatites, and has only been encountered in a few localities throughout the world. The mineral was named by Lacroix after Mt. Bity, Madagascar from where it was first discovered.

<span class="mw-page-title-main">Tuperssuatsiaite</span>

Tuperssuatsiaite is a rare clay mineral found in Greenland, Namibia and Brazil. It is a hydrated phyllosilicate of sodium and iron.

The Tabataud Quarry is situated in the northwestern French Massif Central. The quarry used to be mined for its granodiorite.

<span class="mw-page-title-main">Leifite</span>

Leifite is a rare tectosilicate. Tectosilicates are built on a framework of tetrahedra with silicon or aluminium at the centre and oxygen at the vertices; they include feldspars and zeolites, but leifite does not belong in either of these categories. It is a member of the leifite group, which includes telyushenkoite (Cs,Na,K)Na6(Be2Al3Si15O39) and eirikite KNa6Be2(Si15Al3)O39F2). Leifite was discovered in 1915, and named after Leif Ericson who was a Norse explorer who lived around 1000 AD, and was probably the first European to land in North America, nearly 500 years before Christopher Columbus. Eirikite was named in 2007 after Eirik Raude, or Erik the Red, (950–1003), who discovered Greenland and who was the father of Leif Ericson. The third mineral in the group, telyushenkoite, was discovered in 2001. It was not named after any of Leif Ericson's family members, but after a professor of geology in Turkmenistan.

Scandiobabingtonite was first discovered in the Montecatini granite quarry near Baveno, Italy in a pegmatite cavity. Though found in pegmatites, the crystals of scandiobabingtonite are sub-millimeter sized, and are tabular shaped. Scandiobabingtonite was the sixth naturally occurring mineral discovered with the rare earth element scandium, and grows around babingtonite, with which it is isostructural, hence the namesake. It is also referred to as scandian babingtonite. The ideal chemical formula for scandiobabingtonite is Ca2(Fe2+,Mn)ScSi5O14(OH).

<span class="mw-page-title-main">Harding Pegmatite Mine</span> Adit mine in New Mexico, US

The Harding Pegmatite Mine is a former adit mine that extracted lithium, tantalum, and beryllium from a Precambrian pegmatite sill. It ceased operations in 1958 and its owner, Arthur Montgomery, donated it to the University of New Mexico, which runs the site as an outdoor geology laboratory with mineral collecting permitted on a small scale.

References

  1. 1 2 "Bavenite". www.mindat.org. Retrieved 2022-04-05.
  2. 1 2 3 "Minerali Collection - Minerali, gemme e pietre preziose". Bavenite. Fabbri Editori.
  3. "Bavenite Mineral Data". www.webmineral.com. Retrieved 2022-04-05.
  4. 1 2 Lussier, A. J.; Hawthorne, F. C. (February 2011). "Short-range constraints on chemical and structural variations in bavenite" (PDF). Mineralogical Magazine. 75 (1): 213–239. Bibcode:2011MinM...75..213L. doi:10.1180/minmag.2011.075.1.213. S2CID   131052456.
  5. "Bavenite in Quartz | Gems & Gemology". www.gia.edu. Retrieved 2022-04-05.
  6. Calvo, Miguel (2018). Minerales y Minas de España. Vol. IX. Silicatos[Minerals and mines of Spain. Vol. 9. Silicates] (in Spanish). Madrid, Spain: Escuela Técnica Superior de Ingenieros de Minas de Madrid. Fundación Gómez Pardo. pp. 348–349.