Cementation (geology)

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Calcite cement in an ooid-rich limestone; Carmel Formation, Jurassic of Utah CarmelOoids.jpg
Calcite cement in an ooid-rich limestone; Carmel Formation, Jurassic of Utah

Cementation involves ions carried in groundwater chemically precipitating to form new crystalline material between sedimentary grains. The new pore-filling minerals forms "bridges" between original sediment grains, thereby binding them together. In this way, sand becomes sandstone, and gravel becomes conglomerate or breccia. Cementation occurs as part of the diagenesis or lithification of sediments. Cementation occurs primarily below the water table regardless of sedimentary grain sizes present. Large volumes of pore water must pass through sediment pores for new mineral cements to crystallize and so millions of years are generally required to complete the cementation process. Common mineral cements include calcite, quartz, and silica phases like cristobalite, iron oxides, and clay minerals; other mineral cements also occur.

Cementation is continuous in the groundwater zone, so much so that the term "zone of cementation" is sometimes used interchangeably. Cementation occurs in fissures or other openings of existing rocks and is a dynamic process more or less in equilibrium with a dissolution or dissolving process.

Cement found on the sea floor is commonly aragonite and can take different textural forms. These textural forms include pendant cement, meniscus cement, isopachous cement, needle cement, botryoidal cement, blocky cement, syntaxial rim cement, and coarse mosaic cement. The environment in which each of the cements is found depends on the pore space available. Cements that are found in phreatic zones include: isopachous, blocky, and syntaxial rim cements. As for calcite cementation, which occurs in meteoric realms (freshwater sources), the cement is produced by the dissolution of less stable aragonite and high-Mg calcite. (Boggs, 2011)

Classifying rocks while using the Folk classification depends on the matrix, which is either sparry (prominently composed of cement) or micritic (prominently composed of mud).

Types of carbonate cement

Beachrock is a type of carbonate beach sand that has been cemented together by a process called synsedimentary cementation. Beachrock may contain meniscus cements or pendant cements. As the water between the narrow spaces of grains drains from the beachrock, a small portion of it is held back by capillary forces, where meniscus cement will form. Pendant cements form on the bottom of grains where water droplets are held.

Hardgrounds are hard crusts of carbonate material that form on the bottom of the ocean floor, below the lowest tide level. Isopachous (which means equal thickness) cement forms in subaqueous conditions where the grains are completely surrounded by water (Boggs, 2006).

Carbonate cements can also be formed by biological organisms such as Sporosarcina pasteurii , which binds sand together given organic compounds and a calcium source (Chou et al., 2010).

Cementing has significant effects on the properties and stability of many soil materials. Cementation is not always easily identified and its effects cannot be easily determined quantitatively. It is known to contribute to clay tenderness and may be responsible for an apparent preconsolidation pressure. The filtration of iron compounds from a very sensitive clay from Labrador, Canada, resulted in a 30 t/m reduction in apparent preconsolidation pressure. [1] Coop and Airey (2003) show that for carbonate soils, cementation develops immediately after deposition and allows the soil to maintain a loose structure. Non-recognition of cementation has resulted in construction disputes. [2] For example, a land on a major Project is marked as glacier on contract drawings. It was so hard that it had to be detonated. The contractor claimed that the soil was cemented during excavation as it was formed due to the clay matrix as well as the gravel. The owner concluded that this was due to the weathering of the pebbles. Proper evaluation of the material before the award of the contract could have avoided the problem. Clay particles adhere to the surfaces of larger silt and sand particles, a process called clay bonding. Eventually, larger grains are embedded in a clay matrix and their influence on geotechnical behavior is limited. The clay confinement maintains a large void ratio even at high effective stresses, allowing the interparticle forces to spring up.

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Limestone Sedimentary rocks made of calcium carbonate

Limestone is a common type of carbonate sedimentary rock. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils, and these provide scientists with information on ancient environments and on the evolution of life.

Sandstone Type of sedimentary rock

Sandstone is a clastic sedimentary rock composed mainly of sand-sized silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.

Shale Fine-grained, clastic sedimentary rock

Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals and tiny fragments of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.

Sedimentary rock Rock formed by the deposition and subsequent cementation of material

Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.

Marl Lime-rich mud or mudstone which contains variable amounts of clays and silt

Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae.

Aragonite Calcium carbonate mineral

Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, CaCO3. It is formed by biological and physical processes, including precipitation from marine and freshwater environments.

Concretion Compact mass formed by precipitation of mineral cement between particles

A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular shapes also occur. The word 'concretion' is derived from the Latin concretio "(act of) compacting, condensing, congealing, uniting", itself from con meaning 'together' and crescere meaning "to grow". Concretions form within layers of sedimentary strata that have already been deposited. They usually form early in the burial history of the sediment, before the rest of the sediment is hardened into rock. This concretionary cement often makes the concretion harder and more resistant to weathering than the host stratum.

Oolite Sedimentary rock formed from ooids

Oolite or oölite is a sedimentary rock formed from ooids, spherical grains composed of concentric layers. The name derives from the Ancient Greek word ᾠόν for egg. Strictly, oolites consist of ooids of diameter 0.25–2 millimetres; rocks composed of ooids larger than 2 mm are called pisolites. The term oolith can refer to oolite or individual ooids.

Matrix (geology) Finer-grained material in a rock within which coarser material is embedded

The matrix or groundmass of a rock is the finer-grained mass of material in which larger grains, crystals, or clasts are embedded.

Conglomerate (geology) Coarse-grained clastic sedimentary rock with mainly rounded to subangular clasts

Conglomerate is a clastic sedimentary rock that is composed of a substantial fraction of rounded to subangular gravel-size clasts. A conglomerate typically contain a matrix of finer-grained sediments, such as sand, silt, or clay, which fills the interstices between the clasts. The clasts and matrix are typically cemented by calcium carbonate, iron oxide, silica, or hardened clay.

Dolomite (rock) Sedimentary carbonate rock that contains a high percentage of the mineral dolomite

Dolomite (also known as dolomite rock, dolostone or dolomitic rock) is a sedimentary carbonate rock that contains a high percentage of the mineral dolomite, CaMg(CO3)2. It occurs widely, often in association with limestone and evaporites, though it is less abundant than limestone and rare in Cenozoic rock beds (beds less than about 66 million years in age). The first geologist to distinguish dolomite rock from limestone was Belsazar Hacquet in 1778.

The Folk classification, in geology, is a technical descriptive classification of sedimentary rocks devised by Robert L. Folk, an influential sedimentary petrologist and Professor Emeritus at the University of Texas.

Clastic rock Sedimentary rocks made of mineral or rock fragments

Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic with reference to sedimentary rocks as well as to particles in sediment transport whether in suspension or as bed load, and in sediment deposits.

This glossary of geology is a list of definitions of terms and concepts relevant to geology, its sub-disciplines, and related fields. For other terms related to the Earth sciences, see Glossary of geography terms.

Cone-in-cone structures

Cone-in-cone structures are secondary sedimentary structures that form in association with deeper burial and diagenesis. They consist of concentric inter-bedded cones of calcite or more rarely gypsum, siderite or pyrite. Although several mechanisms may be responsible for the formation of cone-in-cone structures, displacive crystal mechanism is preferred. It accounts for the most uniform and consistent explanation of growth and why cone-in-cone can occur with such variable composition.

Iron-rich sedimentary rocks Sedimentary rocks containing 15 wt.% or more iron

Iron-rich sedimentary rocks are sedimentary rocks which contain 15 wt.% or more iron. However, most sedimentary rocks contain iron in varying degrees. The majority of these rocks were deposited during specific geologic time periods: The Precambrian, the early Paleozoic, and the middle to late Mesozoic. Overall, they make up a very small portion of the total sedimentary record.

Shallow water marine environment

Shallow water marine environment refers to the area between the shore and deeper water, such as a reef wall or a shelf break. This environment is characterized by oceanic, geological and biological conditions, as described below. The water in this environment is shallow and clear, allowing the formation of different sedimentary structures, carbonate rocks, coral reefs, and allowing certain organisms to survive and become fossils.

Microbiologically induced calcite precipitation

Microbiologically induced calcium carbonate precipitation (MICP) is a bio-geochemical process that induces calcium carbonate precipitation within the soil matrix. Biomineralization in the form of calcium carbonate precipitation can be traced back to the Precambrian period. Calcium carbonate can be precipitated in three polymorphic forms, which in the order of their usual stabilities are calcite, aragonite and vaterite. The main groups of microorganisms that can induce the carbonate precipitation are photosynthetic microorganisms such as cyanobacteria and microalgae; sulfate-reducing bacteria; and some species of microorganisms involved in nitrogen cycle. Several mechanisms have been identified by which bacteria can induce the calcium carbonate precipitation, including urea hydrolysis, denitrification, sulfate production, and iron reduction. Two different pathways, or autotrophic and heterotrophic pathways, through which calcium carbonate is produced have been identified. There are three autotrophic pathways, which all result in depletion of carbon dioxide and favouring calcium carbonate precipitation. In heterotrophic pathway, two metabolic cycles can be involved: the nitrogen cycle and the sulfur cycle. Several applications of this process have been proposed, such as remediation of cracks and corrosion prevention in concrete, biogrout, sequestration of radionuclides and heavy metals.

Egg taphonomy Study of the decomposition and fossilization of eggs

Egg taphonomy is the study of the decomposition and fossilization of eggs. The processes of egg taphonomy begin when the egg either hatches or dies. Eggshell fragments are robust and can often travel great distances before burial. More complete egg specimens gradually begin to fill with sediment, which hardens as minerals precipitate out of water percolating through pores or cracks in the shell. Throughout the fossilization process the calcium carbonate composing the eggshell generally remains unchanged, allowing scientists to study its original structure. However, egg fossils buried under sediments at great depth can be subjected to heat, pressure and chemical processes that can alter the structure of its shell through a process called diagenesis.

Automicrite is autochthonous micrite, that is, a carbonate mud precipitated in situ and made up of fine-grained calcite or aragonite micron-sized crystals. It precipitates on the sea floor or within the sediment as an authigenic mud thanks to physicochemical, microbial, photosynthetic and biochemical processes. It has peculiar fabrics and uniform mineralogical and chemical composition.

References

  1. Kenney TC, Moum J and Berre T (1967) An experimental study of bonds in natural clay. Proceedings of Geotechnical Conference, Oslo, Norway (Jørstad FA (ed.)). Norwegian Geotechnical Institute, Oslo, Norway, pp. 65–69.
  2. Coop, M. R. & Airey, D. W. (2003). Carbonate sands. In Characterisation and engineering properties of natural soils (eds T. S. Tan, K. K. Phoon, D.W. Hight and S. Leroueil), pp. 1049–1086. Lisse, the Netherlands: Swets & Zeitlinger