Classical limit

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The classical limit or correspondence limit is the ability of a physical theory to approximate or "recover" classical mechanics when considered over special values of its parameters. [1] The classical limit is used with physical theories that predict non-classical behavior.

Contents

Quantum theory

A heuristic postulate called the correspondence principle was introduced to quantum theory by Niels Bohr: in effect it states that some kind of continuity argument should apply to the classical limit of quantum systems as the value of the Planck constant normalized by the action of these systems becomes very small. Often, this is approached through "quasi-classical" techniques (cf. WKB approximation). [2]

More rigorously, [3] the mathematical operation involved in classical limits is a group contraction, approximating physical systems where the relevant action is much larger than the reduced Planck constant ħ, so the "deformation parameter" ħ/S can be effectively taken to be zero (cf. Weyl quantization.) Thus typically, quantum commutators (equivalently, Moyal brackets) reduce to Poisson brackets, [4] in a group contraction.

In quantum mechanics, due to Heisenberg's uncertainty principle, an electron can never be at rest; it must always have a non-zero kinetic energy, a result not found in classical mechanics. For example, if we consider something very large relative to an electron, like a baseball, the uncertainty principle predicts that it cannot really have zero kinetic energy, but the uncertainty in kinetic energy is so small that the baseball can effectively appear to be at rest, and hence it appears to obey classical mechanics. In general, if large energies and large objects (relative to the size and energy levels of an electron) are considered in quantum mechanics, the result will appear to obey classical mechanics. The typical occupation numbers involved are huge: a macroscopic harmonic oscillator with ω = 2 Hz, m = 10 g, and maximum amplitude x0 = 10 cm, has S  E/ω mωx2
0
/2 ≈ 10−4 kg·m2/s
 = ħn, so that n  1030. Further see coherent states. It is less clear, however, how the classical limit applies to chaotic systems, a field known as quantum chaos.

Quantum mechanics and classical mechanics are usually treated with entirely different formalisms: quantum theory using Hilbert space, and classical mechanics using a representation in phase space. One can bring the two into a common mathematical framework in various ways. In the phase space formulation of quantum mechanics, which is statistical in nature, logical connections between quantum mechanics and classical statistical mechanics are made, enabling natural comparisons between them, including the violations of Liouville's theorem (Hamiltonian) upon quantization. [5] [6]

In a crucial paper (1933), Dirac [7] explained how classical mechanics is an emergent phenomenon of quantum mechanics: destructive interference among paths with non-extremal macroscopic actions S » ħ obliterate amplitude contributions in the path integral he introduced, leaving the extremal action Sclass, thus the classical action path as the dominant contribution, an observation further elaborated by Feynman in his 1942 PhD dissertation. [8] (Further see quantum decoherence.)

Time-evolution of expectation values

One simple way to compare classical to quantum mechanics is to consider the time-evolution of the expected position and expected momentum, which can then be compared to the time-evolution of the ordinary position and momentum in classical mechanics. The quantum expectation values satisfy the Ehrenfest theorem. For a one-dimensional quantum particle moving in a potential , the Ehrenfest theorem says [9]

Although the first of these equations is consistent with the classical mechanics, the second is not: If the pair were to satisfy Newton's second law, the right-hand side of the second equation would have read

.

But in most cases,

.

If for example, the potential is cubic, then is quadratic, in which case, we are talking about the distinction between and , which differ by .

An exception occurs in case when the classical equations of motion are linear, that is, when is quadratic and is linear. In that special case, and do agree. In particular, for a free particle or a quantum harmonic oscillator, the expected position and expected momentum exactly follows solutions of Newton's equations.

For general systems, the best we can hope for is that the expected position and momentum will approximately follow the classical trajectories. If the wave function is highly concentrated around a point , then and will be almost the same, since both will be approximately equal to . In that case, the expected position and expected momentum will remain very close to the classical trajectories, at least for as long as the wave function remains highly localized in position. [10]

Now, if the initial state is very localized in position, it will be very spread out in momentum, and thus we expect that the wave function will rapidly spread out, and the connection with the classical trajectories will be lost. When the Planck constant is small, however, it is possible to have a state that is well localized in both position and momentum. The small uncertainty in momentum ensures that the particle remains well localized in position for a long time, so that expected position and momentum continue to closely track the classical trajectories for a long time.

Relativity and other deformations

Other familiar deformations in physics involve:

See also

Related Research Articles

The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, which are a kind of linear space. Such are distinguished from mathematical formalisms for physics theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces, and operators on these spaces. In brief, values of physical observables such as energy and momentum were no longer considered as values of functions on phase space, but as eigenvalues; more precisely as spectral values of linear operators in Hilbert space.

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<span class="mw-page-title-main">Uncertainty principle</span> Foundational principle in quantum physics

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<span class="mw-page-title-main">Schrödinger equation</span> Description of a quantum-mechanical system

The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the subject. The equation is named after Erwin Schrödinger, who postulated the equation in 1925, and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933.

<span class="mw-page-title-main">Phase space</span> Mathematical construction for dynamical systems

In dynamical system theory, a phase space is a space in which all possible states of a system are represented, with each possible state corresponding to one unique point in the phase space. For mechanical systems, the phase space usually consists of all possible values of position and momentum variables. It is the outer product of direct space and reciprocal space. The concept of phase space was developed in the late 19th century by Ludwig Boltzmann, Henri Poincaré, and Josiah Willard Gibbs.

In physics, specifically in quantum mechanics, a coherent state is the specific quantum state of the quantum harmonic oscillator, often described as a state which has dynamics most closely resembling the oscillatory behavior of a classical harmonic oscillator. It was the first example of quantum dynamics when Erwin Schrödinger derived it in 1926, while searching for solutions of the Schrödinger equation that satisfy the correspondence principle. The quantum harmonic oscillator arise in the quantum theory of a wide range of physical systems. For instance, a coherent state describes the oscillating motion of a particle confined in a quadratic potential well. The coherent state describes a state in a system for which the ground-state wavepacket is displaced from the origin of the system. This state can be related to classical solutions by a particle oscillating with an amplitude equivalent to the displacement.

Matrix mechanics is a formulation of quantum mechanics created by Werner Heisenberg, Max Born, and Pascual Jordan in 1925. It was the first conceptually autonomous and logically consistent formulation of quantum mechanics. Its account of quantum jumps supplanted the Bohr model's electron orbits. It did so by interpreting the physical properties of particles as matrices that evolve in time. It is equivalent to the Schrödinger wave formulation of quantum mechanics, as manifest in Dirac's bra–ket notation.

<span class="mw-page-title-main">Path integral formulation</span> Formulation of quantum mechanics

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<span class="mw-page-title-main">Propagator</span> Function in quantum field theory showing probability amplitudes of moving particles

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<span class="mw-page-title-main">Wigner quasiprobability distribution</span> Wigner distribution function in physics as opposed to in signal processing

The Wigner quasiprobability distribution is a quasiprobability distribution. It was introduced by Eugene Wigner in 1932 to study quantum corrections to classical statistical mechanics. The goal was to link the wavefunction that appears in Schrödinger's equation to a probability distribution in phase space.

In quantum mechanics, the momentum operator is the operator associated with the linear momentum. The momentum operator is, in the position representation, an example of a differential operator. For the case of one particle in one spatial dimension, the definition is:

The Ehrenfest theorem, named after Paul Ehrenfest, an Austrian theoretical physicist at Leiden University, relates the time derivative of the expectation values of the position and momentum operators x and p to the expectation value of the force on a massive particle moving in a scalar potential ,

In quantum mechanics, the Wigner–Weyl transform or Weyl–Wigner transform is the invertible mapping between functions in the quantum phase space formulation and Hilbert space operators in the Schrödinger picture.

In mechanics, a constant of motion is a quantity that is conserved throughout the motion, imposing in effect a constraint on the motion. However, it is a mathematical constraint, the natural consequence of the equations of motion, rather than a physical constraint. Common examples include energy, linear momentum, angular momentum and the Laplace–Runge–Lenz vector.

Photon polarization is the quantum mechanical description of the classical polarized sinusoidal plane electromagnetic wave. An individual photon can be described as having right or left circular polarization, or a superposition of the two. Equivalently, a photon can be described as having horizontal or vertical linear polarization, or a superposition of the two.

This is a glossary for the terminology often encountered in undergraduate quantum mechanics courses.

The Koopman–von Neumann mechanics is a description of classical mechanics in terms of Hilbert space, introduced by Bernard Koopman and John von Neumann in 1931 and 1932, respectively.

References

  1. Bohm, D. (1989). Quantum Theory . Dover Publications. ISBN   0-486-65969-0.
  2. Landau, L. D.; Lifshitz, E. M. (1977). Quantum Mechanics: Non-Relativistic Theory. Vol. 3 (3rd ed.). Pergamon Press. ISBN   978-0-08-020940-1.
  3. Hepp, K. (1974). "The classical limit for quantum mechanical correlation functions". Communications in Mathematical Physics . 35 (4): 265–277. Bibcode:1974CMaPh..35..265H. doi:10.1007/BF01646348. S2CID   123034390.
  4. Curtright, T. L.; Zachos, C. K. (2012). "Quantum Mechanics in Phase Space". Asia Pacific Physics Newsletter . 1: 37–46. arXiv: 1104.5269 . doi:10.1142/S2251158X12000069. S2CID   119230734.
  5. Bracken, A.; Wood, J. (2006). "Semiquantum versus semiclassical mechanics for simple nonlinear systems". Physical Review A . 73 (1): 012104. arXiv: quant-ph/0511227 . Bibcode:2006PhRvA..73a2104B. doi:10.1103/PhysRevA.73.012104. S2CID   14444752.
  6. Conversely, in the lesser-known approach presented in 1932 by Koopman and von Neumann, the dynamics of classical mechanics have been formulated in terms of an operational formalism in Hilbert space, a formalism used conventionally for quantum mechanics.
  7. Dirac, P.A.M. (1933). "The Lagrangian in quantum mechanics" (PDF). Physikalische Zeitschrift der Sowjetunion . 3: 64–72.
  8. Feynman, R. P. (1942). The Principle of Least Action in Quantum Mechanics (Ph.D. Dissertation). Princeton University.
    Reproduced in Feynman, R. P. (2005). Brown, L. M. (ed.). Feynman's Thesis: a New Approach to Quantum Theory . World Scientific. ISBN   978-981-256-380-4.
  9. Hall 2013 Section 3.7.5
  10. Hall 2013 p. 78