Direct Blue 15

Last updated
Direct Blue 15
Direct Blue 15.svg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.017.624 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 219-385-3
PubChem CID
UNII
  • InChI=1S/C34H28N6O16S4.4Na/c1-55-25-9-15(3-5-23(25)37-39-31-27(59(49,50)51)11-17-7-19(57(43,44)45)13-21(35)29(17)33(31)41)16-4-6-24(26(10-16)56-2)38-40-32-28(60(52,53)54)12-18-8-20(58(46,47)48)14-22(36)30(18)34(32)42;;;;/h3-14,37-38H,35-36H2,1-2H3,(H,43,44,45)(H,46,47,48)(H,49,50,51)(H,52,53,54);;;;/q;4*+1/p-4
    Key: JDCJCNVYTGPGAN-UHFFFAOYSA-J
  • COC1=C(C=CC(=C1)C2=CC(=C(C=C2)NN=C3C(=CC4=CC(=CC(=C4C3=O)N)S(=O)(=O)[O-])S(=O)(=O)[O-])OC)NN=C5C(=CC6=CC(=CC(=C6C5=O)N)S(=O)(=O)[O-])S(=O)(=O)[O-].[Na+].[Na+].[Na+].[Na+]
Properties
C34H24N6Na4O16S4
Molar mass 992.79 g·mol−1
Appearancedark blue solid
good
Hazards
GHS labelling:
GHS-pictogram-silhouette.svg
Danger
H350
P201, P202, P281, P308+P313, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Direct Blue 15 is an organic compound that is classified as an azo dye. It is a dark blue water soluble solid. It is a popular substantive dye, which means that it useful for dying cotton and related cellulosic materials. It is produced by azo coupling of o-dianisidine with the appropriate naphthalene disulfonate. [1]

Related Research Articles

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<span class="mw-page-title-main">Congo red</span> Chemical compound

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<span class="mw-page-title-main">Azo compound</span> Organic compounds with a diazenyl group (–N=N–)

Azo compounds are organic compounds bearing the functional group diazenyl.

<span class="mw-page-title-main">Sudan I</span> Chemical compound

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<span class="mw-page-title-main">Mordant red 19</span> Chemical compound

Mordant red 19 is an organic compound with the chemical formula C16H13ClN4O5S. It is classified as an azo dye.

<span class="mw-page-title-main">Azo dye</span> Class of organic compounds used as dye

Azo dyes are organic compounds bearing the functional group R−N=N−R′, in which R and R′ are usually aryl and substituted aryl groups. They are a commercially important family of azo compounds, i.e. compounds containing the C−N=N−C linkage. Azo dyes are synthetic dyes and do not occur naturally. Most azo dyes contain only one azo group but there are some that contain two or three azo groups, called "diazo dyes" and "triazo dyes" respectively. Azo dyes comprise 60–70% of all dyes used in food and textile industries. Azo dyes are widely used to treat textiles, leather articles, and some foods. Chemically related derivatives of azo dyes include azo pigments, which are insoluble in water and other solvents.

In organic chemistry, an azo coupling is an reaction between a diazonium compound and another aromatic compound that produces an azo compound. In this electrophilic aromatic substitution reaction, the aryldiazonium cation is the electrophile, and the activated carbon, serves as a nucleophile. Classical coupling agents are phenols and naphthols. Usually the diazonium reagent attacks at the para position of the coupling agent. When the para position is occupied, coupling occurs at a ortho position, albeit at a slower rate.

Trypan blue is an azo dye. It is a direct dye for cotton textiles. In biosciences, it is used as a vital stain to selectively colour dead tissues or cells blue.

A substantive dye or direct dye is a dye that adheres to its substrate, typically a textile, by non-ionic forces.

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Sudan Yellow 3G, also known as Solvent Yellow 16, C.I. disperse yellow and C.I. 12700, is a yellow azo dye. It is soluble in fats and oils.

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<span class="mw-page-title-main">Sulfanilic acid</span> Chemical compound

Sulfanilic acid (4-aminobenzenesulfonic acid) is an organic compound with the formula H3NC6H4SO3. It is an off-white solid. It is a zwitterion, which explains its high melting point. It is a common building block in organic chemistry.

<span class="mw-page-title-main">Acid Orange 7</span> Chemical compound

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<span class="mw-page-title-main">Direct Blue 1</span> Chemical compound

Direct Blue 1 is an organic compound that is one of many azo dyes. This salt is used as a substantive dye for textiles with high contents of cellulose, i.e. cotton. It is prepared by the azo coupling of the aminonaphthalene and diazotized derivative of o-dianisidine.

<span class="mw-page-title-main">Acid red 88</span> Chemical compound

Acid red 88 is an azo dye. Due to its intense colour, solid samples appear almost black. It is used to dye cotton textiles red. A closely related acid dye is Acid Red 13.

<span class="mw-page-title-main">Acid Red 13</span> Chemical compound

Acid Red 13 is an azo dye. It is produced as a sodium salt. Solid samples appear dark red.

<i>N</i>-Ethyl-<i>N</i>-(2-chloroethyl)aniline Chemical compound

N-Ethyl-N-(2-chloroethyl)aniline is the organic compound with the formula C6H5N(Et)(CH2CH2Cl) (Et = ethyl). It is a low-melting colorless solid that is an alkylating agent. The compound is a precursor to several cationic azo dyes via reaction of the chloroethyl group with tertiary amines or pyridine followed by azo coupling. Examples of derived dyes include C. I. Basic Red 18, Maxilon Red 2GL, and Yoracryl Red 2G.

<i>o</i>-Dianisidine Chemical compound

o-Dianisidine is an organic compound with the formula [(CH3O)(H2N)C6H3]2. A colorless or white solid, it is a bifunctional compound derived via the benzidine rearrangement from o-anisidine.

References

  1. Klaus Hunger; Peter Mischke; Wolfgang Rieper; Roderich Raue; Klaus Kunde; Aloys Engel (2005). "Azo Dyes". Ullmann’s Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a03_245. ISBN   3527306730..