Engineered cementitious composite

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Engineered Cementitious Composite (ECC), also called Strain Hardening Cement-based Composites (SHCC) or more popularly as bendable concrete, is an easily molded mortar-based composite reinforced with specially selected short random fibers, usually polymer fibers. [1] Unlike regular concrete, ECC has a tensile strain capacity in the range of 3–7%, [1] compared to 0.01% for ordinary portland cement (OPC) paste, mortar or concrete. ECC therefore acts more like a ductile metal material rather than a brittle glass material (as does OPC concrete), leading to a wide variety of applications.

Contents

Development

ECC, unlike common fiber reinforced concrete, is a family of micromechanically designed materials. [2] [3] As long as a cementitious material is designed/developed based on micromechanics and fracture mechanics theory to feature large tensile ductility, it can be called an ECC. Therefore, ECC is not a fixed material design, but a broad range of topics under different stages of research, development, and implementations. The ECC material family is expanding. The development of an individual mix design of ECC requires special efforts by systematically engineering of the material at nano-, micro-, macro- and composite scales.

ECC looks similar to ordinary Portland cement-based concrete, except that it can deform (or bend) under strain. [1] A number of research groups are developing ECC science, including those at the University of Michigan, University of California, Irvine, Delft University of Technology, the University of Tokyo, the Czech Technical University, University of British Columbia, and Stanford University. Traditional concrete's lack of durability and failure under strain, both stemming from brittle behavior, have been a pushing factor in the development of ECC.

Properties

ECC has a variety of unique properties, including tensile properties superior to other fiber-reinforced composites, ease of processing on par with conventional cement, the use of only a small volume fraction of fibers (~ 2%), tight crack width, and a lack of anisotropically weak planes. [4] These properties are due largely to the interaction between the fibers and cementing matrix, which can be custom-tailored through micromechanics design. Essentially, the fibers create many microcracks with a very specific width, rather than a few very large cracks (as in conventional concrete.) This allows ECC to deform without catastrophic failure.

This microcracking behavior leads to superior corrosion resistance (the cracks are so small and numerous that it is difficult for aggressive media to penetrate and attack the reinforcing steel) as well as to self-healing. [5] [6] [7] In the presence of water (during a rainstorm, for instance) unreacted cement particles recently exposed due to cracking hydrate and form a number of products (calcium silicate hydrates (C-S-H), calcite, etc.) that expand and fill in the crack. These products appear as a white ‘scar’ material filling in the crack. This self-healing behavior not only seals the crack to prevent transport of fluids, but mechanical properties are regained. This self-healing has been observed in a variety of conventional cement and concretes; however, above a certain crack width self healing becomes less effective. It is the tightly controlled crack widths seen in ECC that ensure all cracks thoroughly heal when exposed to the natural environment.

When combined with a more conductive material, all cement materials can increase and be used for damage-sensing. This is essentially based on the fact that conductivity will change as damage occurs; the addition of conductive material is meant to raise the conductivity to a level where such changes will be easily identified. Though not a material property of ECC itself, semi-conductive ECC for damage-sensing [8] [9] are being developed.

Types

There are a number of different varieties of ECC, including:

Field applications

ECC have found use in a number of large-scale applications in Japan, Korea, Switzerland, Australia and the U.S.[3]. These include:

Comparison to other composite materials

PropertiesFRCCommon HPFRCCECC
Design MethodologyN.A.Use high VfMicromechanics based, minimize Vf for cost and processibility
FiberAny type, Vf usually less than 2%; df for steel ~ 500 micrometreMostly steel, Vf usually > 5%; df ~ 150 micrometreTailored, polymer fibers, Vf usually less than 2%; df < 50 micrometre
MatrixCoarse aggregatesFine aggregatesControlled for matrix toughness, flaw size; fine sand
InterfaceNot controlledNot controlledChemical and frictional bonds controlled for bridging properties
Mechanical PropertiesStrain-softening:Strain-hardening:Strain-hardening:
Tensile strain0.1%<1.5%>3% (typical); 8% max
Crack widthUnlimitedTypically several hundred micrometres, unlimited beyond 1.5% strainTypically < 100 micrometres during strain-hardening [1]

Note: FRC=Fiber-Reinforced Cement. HPFRCC=High-Performance Fiber Reinforced Cementitious Composites

See also

Related Research Articles

<span class="mw-page-title-main">Concrete</span> Composite construction material

Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminum combined. Globally, the ready-mix concrete industry, the largest segment of the concrete market, is projected to exceed $600 billion in revenue by 2025. This widespread use results in a number of environmental impacts. Most notably, the production process for cement produces large volumes of greenhouse gas emissions, leading to net 8% of global emissions. Other environmental concerns include widespread illegal sand mining, impacts on the surrounding environment such as increased surface runoff or urban heat island effect, and potential public health implications from toxic ingredients. Significant research and development is being done to try to reduce the emissions or make concrete a source of carbon sequestration, and increase recycled and secondary raw materials content into the mix to achieve a circular economy. Concrete is expected to be a key material for structures resilient to climate disasters, as well as a solution to mitigate the pollution of other industries, capturing wastes such as coal fly ash or bauxite tailings and residue.

<span class="mw-page-title-main">Reinforced concrete</span> Concrete with rebar

Reinforced concrete (RC), also called reinforced cement concrete (RCC) and ferroconcrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ductility. The reinforcement is usually, though not necessarily, steel bars (rebar) and is usually embedded passively in the concrete before the concrete sets. However, post-tensioning is also employed as a technique to reinforce the concrete. In terms of volume used annually, it is one of the most common engineering materials. In corrosion engineering terms, when designed correctly, the alkalinity of the concrete protects the steel rebar from corrosion.

<span class="mw-page-title-main">Composite material</span> Material made from a combination of three or more unlike substances

A composite material is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions.

<span class="mw-page-title-main">Compressive strength</span> Capacity of a material or structure to withstand loads tending to reduce size

In mechanics, compressive strength or compression strength is the capacity of a material or structure to withstand loads tending to reduce size. In other words, compressive strength resists compression, whereas tensile strength resists tension. In the study of strength of materials, tensile strength, compressive strength, and shear strength can be analyzed independently.

Self-healing material Substances that can repair themselves

Self-healing materials are artificial or synthetically created substances that have the built-in ability to automatically repair damages to themselves without any external diagnosis of the problem or human intervention. Generally, materials will degrade over time due to fatigue, environmental conditions, or damage incurred during operation. Cracks and other types of damage on a microscopic level have been shown to change thermal, electrical, and acoustical properties of materials, and the propagation of cracks can lead to eventual failure of the material. In general, cracks are hard to detect at an early stage, and manual intervention is required for periodic inspections and repairs. In contrast, self-healing materials counter degradation through the initiation of a repair mechanism that responds to the micro-damage. Some self-healing materials are classed as smart structures, and can adapt to various environmental conditions according to their sensing and actuation properties.

Glass fiber reinforced concrete (GFRC) is a type of fiber-reinforced concrete. The product is also known as glassfibre reinforced concrete or GRC in British English. Glass fiber concretes are mainly used in exterior building façade panels and as architectural precast concrete. Somewhat similar materials are fiber cement siding and cement boards.

Fiber-reinforced concrete or fibre-reinforced concrete (FRC) is concrete containing fibrous material which increases its structural integrity. It contains short discrete fibers that are uniformly distributed and randomly oriented. Fibers include steel fibers, glass fibers, synthetic fibers and natural fibers – each of which lend varying properties to the concrete. In addition, the character of fiber-reinforced concrete changes with varying concretes, fiber materials, geometries, distribution, orientation, and densities.

High-performance fiber-reinforced cementitious composites (HPFRCCs) are a group of fiber-reinforced cement-based composites which possess the unique ability to flex and self-strengthen before fracturing. This particular class of concrete was developed with the goal of solving the structural problems inherent with today’s typical concrete, such as its tendency to fail in a brittle manner under excessive loading and its lack of long-term durability. Because of their design and composition, HPFRCCs possess the remarkable ability to plastically yield and harden under excessive loading, so that they flex or deform before fracturing, a behavior similar to that exhibited by most metals under tensile or bending stresses. Because of this capability, HPFRCCs are more resistant to cracking and last considerably longer than normal concrete. Another extremely desirable property of HPFRCCs is their low density. A less dense, and hence lighter material means that HPFRCCs could eventually require much less energy to produce and handle, deeming them a more economic building material. Because of HPFRCCs’ lightweight composition and ability to strain harden, it has been proposed that they could eventually become a more durable and efficient alternative to typical concrete.

Structural material

Structural engineering depends on the knowledge of materials and their properties, in order to understand how different materials resist and support loads.

Textile-reinforced concrete

Textile-reinforced concrete is a type of reinforced concrete in which the usual steel reinforcing bars are replaced by textile materials. Instead of using a metal cage inside the concrete, this technique uses a fabric cage inside the same.

Carbon fiber-reinforced polymers, carbon-fibre-reinforced polymers, carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic, also known as carbon fiber, carbon composite, or just carbon, are extremely strong and light fiber-reinforced plastics that contain carbon fibers. CFRPs can be expensive to produce, but are commonly used wherever high strength-to-weight ratio and stiffness (rigidity) are required, such as aerospace, superstructures of ships, automotive, civil engineering, sports equipment, and an increasing number of consumer and technical applications.

Types of concrete Building material consisting of aggregates cemented by a binder

Concrete is produced in a variety of compositions, finishes and performance characteristics to meet a wide range of needs.

Concrete degradation Damage to concrete affecting its mechanical strength and its durability

Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damages are caused by the formation of expansive products produced by various chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms. Other damaging processes can also involve calcium leaching by water infiltration and different physical phenomena initiating cracks formation and propagation. All these detrimental processes and damaging agents adversely affects the concrete mechanical strength and its durability.

Steel fibre-reinforced shotcrete (SFRS) is shotcrete with steel fibres added. It has higher tensile strength than unreinforced shotcrete and is quicker to apply than weldmesh reinforcement. It has often been used for tunnels.

Concrete has relatively high compressive strength, but significantly lower tensile strength. The compressive strength is typically controlled with the ratio of water to cement when forming the concrete, and tensile strength is increased by additives, typically steel, to create reinforced concrete. In other words we can say concrete is made up of sand, ballast, cement and water.

Nemkumar Banthia Indian-born Canadian civil engineer

Nemkumar Banthia FRSC, is an Indian-born Canadian engineer and professor of civil engineering at the University of British Columbia and the CEO of IC-IMPACTS. He is best known for his research in the fields of cement-based and polymer-based fiber reinforced composites, particularly on testing and standardization, fracture behavior, strain-rate effects, durability and development of sustainable materials.

In materials science, toughening refers to the process of making a material more resistant to the propagation of cracks. When a crack propagates, the associated irreversible work in different materials classes is different. Thus, the most effective toughening mechanisms differ among different materials classes. The crack tip plasticity is important in toughening of metals and long-chain polymers. Ceramics have limited crack tip plasticity and primarily rely on different toughening mechanisms.

The reinforcement of 3D printed concrete is a mechanism where the ductility and tensile strength of printed concrete are improved using various reinforcing techniques, including reinforcing bars, meshes, fibers, or cables. The reinforcement of 3D printed concrete is important for the large-scale use of the new technology, like in the case of ordinary concrete. With a multitude of additive manufacturing application in the concrete construction industry—specifically the use of additively constructed concrete in the manufacture of structural concrete elements—the reinforcement and anchorage technologies vary significantly. Even for non-structural elements, the use of non-structural reinforcement such as fiber reinforcement is not uncommon. The lack of formwork in most 3D printed concrete makes the installation of reinforcement complicated. Early phases of research in concrete 3D printing primarily focused on developing the material technologies of the cementitious/concrete mixes. These causes combined with the non-existence of codal provisions on reinforcement and anchorage for printed elements speak for the limited awareness and the usage of the various reinforcement techniques in additive manufacturing. The material extrusion-based printing of concrete is currently favorable both in terms of availability of technology and of the cost-effectiveness. Therefore, most of the reinforcement techniques developed or currently under development are suitable to the extrusion-based 3D printing technology.

Victor C. Li is the James R. Rice Distinguished University Professor of Engineering and the E.B. Wylie Collegiate Professor of Civil Engineering at the University of Michigan. He is also Director of the Center for Low Carbon Built Environment at the University of Michigan College of Engineering. Li led the team that developed engineered cementitious composites (EEC), popularly known as "bendable concrete." Li argues EEC can increase the durability of infrastructure and reduce its carbon footprint.

<span class="mw-page-title-main">Self-healing concrete</span>

Self-healing concrete is characterized as the capability of concrete to fix its cracks on its own autogenously or autonomously. It not only seals the cracks but also partially or entirely recovers the mechanical properties of the structural elements. This kind of concrete is also known as self-repairing concrete. Because concrete has a poor tensile strength compared to other building materials, it often develops cracks in the surface. These cracks reduce the durability of the concrete because they facilitate the flow of liquids and gases that may contain harmful compounds. If microcracks expand and reach the reinforcement, not only will the concrete itself be susceptible to attack, but so will the reinforcement steel bars. Therefore, it is essential to limit the crack's width and repair it as quickly as feasible. Self-healing concrete would not only make the material more sustainable, but it would also contribute to an increase in the service life of concrete structures and make the material more durable and environmentally friendly.

References

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