South Africa competed at the 2004 Summer Olympics in Athens, Greece, from 13 to 29 August 2004. This was the nation's sixteenth overall and fourth consecutive appearance at the Summer Olympics in the post-apartheid era. The South African Sports Confederation and Olympic Committee (SASCOC) sent a total of 106 athletes to the Games, 66 men and 40 women, to compete in 19 sports. Field hockey was the only team-based sport in which South Africa had its representation at these Games. There was only a single competitor in archery, canoeing, diving, artistic and rhythmic gymnastics, judo, sailing, shooting, taekwondo, and wrestling.
The men's 200 metres at the 2004 Summer Olympics as part of the athletics program was held at the Athens Olympic Stadium from August 24 to 26. There were 54 competitors from 41 nations. The event was won by 0.22 seconds by Shawn Crawford of the United States, the nation's 17th victory in the men's 200 metres after missing the podium entirely four years prior. His teammates Bernard Williams (silver) and Justin Gatlin (bronze) completed the sixth American sweep in the event and first since 1984.
The men's 3000 metres steeplechase at the 2004 Summer Olympics as part of the athletics program were held at the Athens Olympic Stadium from August 21 to 24. The athletes competed in a three-heat qualifying round in which the top three from each heat, together with the six fastest losing runners, were given a place in the final race. The winning margin was 0.30 seconds.
Brazil competed at the 2004 Summer Olympics in Athens, Greece, from 13 to 29 August 2004. This was the nation's nineteenth appearance at the Summer Olympics, excluding the 1928 Summer Olympics in Amsterdam. The Brazilian Olympic Committee sent the nation's largest ever delegation in history to the Games. A total of 243 athletes, 124 men and 119 women, competed in 24 sports.
The Maldives competed at the 2004 Summer Olympics in Athens, Greece, from 13 to 29 August 2004. The delegation's participation in the Athens Olympics marked the Maldives' fifth appearance at the Summer Olympics since their debut at the 1988 Summer Olympics in Seoul, South Korea. Four athletes competed across two sports; Sultan Saeed and Shifana Ali in track and field, and Hassan Mubah and Aminath Rouya Hussain in swimming. None of the track or swimming athletes advanced past the first round in their events, and no Maldivian has won a medal in any events. Sultan Saeed bore the Maldives' flag during the parade of nations of the opening ceremony.
Chad competed at the 2004 Summer Olympics in Athens, Greece, from 13 to 29 August 2004. The country's participation at Athens marked its tenth appearance in the Summer Olympics since its debut at the 1964 Summer Games in Tokyo, Japan. The delegation included two track and field athletes; Djikoloum Mobele in the men's 100 metres and Kaltouma Nadjina in the women's 400 metres. Both athletes participated at the Games through wild card places since they did not meet the required standards to qualify. Nadjina progressed past the first round of her competition, but was eliminated in the semi-finals.
Brunei, as Brunei Darussalam, competed at the 2004 Summer Olympics in Athens, Greece, which took place between 13 and 29 August 2004. The country's participation in Athens marked its fourth appearance at the Summer Olympics since its debut in the 1988 Summer Olympics.
Malawi sent a delegation to compete at the 1996 Summer Olympics in Atlanta, United States from 19 July to 4 August 1996. This was the African nation's fifth appearance at a Summer Olympic Games. The Malawian delegation consisted of two competitors in the sport of athletics; Henry Moyo failed to advance past the first round heats of the 5,000 meters, and John Mwathiwa finished 65th in the marathon.
Mathias Ntawulikura is a retired Rwandan long-distance runner. He reached the World Athletics Championships final and participated in the Olympic Games in the 5000 metres (1988) and 10,000 metres and marathon. He also participated five times in the IAAF World Cross Country Championships.
Adama Njie is a retired Gambian middle-distance runner who specialised in the 800 metres. She represented her country in three Olympic Games and one Commonwealth Games, and was the flag-bearer for the Gambia at the 2000 Summer Olympics.
Djibouti first participated at the Olympic Games in 1984, and have competed in every Summer Olympic Games, apart from the 2004 edition, since then. They have never competed in the Winter Olympic Games.
Cape Verde competed at the 2008 Summer Olympics in Beijing, China. Their participation marked their fourth Olympic appearance. Two Cape Verdeans competed in the Olympic games: Nelson Cruz participated as a marathon runner, and Wania Monteiro participated in gymnastics. Another athlete, Lenira Santos, was selected to compete in athletics but was forced to pull out due to injury. Monteiro was selected as the flag bearer for both the opening and closing ceremonies. Neither of the Cape Verdeans progressed beyond the first round.
Burundi participated in the 2008 Summer Olympics, held in Beijing, China from 8 to 24 August 2008. It was Burundi's fourth appearance in the summer Olympics since its debut in 1996. The Burundi team included three athletes: runners Joachim Nshimirimana and Francine Niyonizigiye, as well as swimmer Elsie Uwamahoro. Niyonizigiye, a marathon runner, was flag bearer for the opening ceremony. None of the Burundi athletes progressed further than the qualifying round.
Djibouti took part in the 2008 Summer Olympics, which were held in Beijing, China from 8 to 24 August 2008. The country's participation at Beijing marked its sixth appearance in the Summer Olympics since its debut in 1984. The Djibouti delegation included two athletes in 2008; Mahamoud Farah, a middle-distance runner, and Fathia Ali Bouraleh, a sprinter. Hussein Ahmed Salah, Djibouti's only Olympic medalist, was selected as the flag bearer for both the opening and closing ceremonies despite not competing in 2008. None of the Djiboutian athletes progressed further than the heat round.
Namibia competed at the 2012 Summer Olympics in London, United Kingdom from July 27 to August 12, 2012. This was the nation's sixth consecutive appearance at the Olympics.
Cape Verde competed at the 2012 Summer Olympics which were held in London, United Kingdom from 27 July to 12 August 2012. The country's participation at London marked its fifth appearance in the Summer Olympics since its debut in 1996. The delegation included Ruben Sança, a long-distance runner; Lidiane Lopes, a sprinter; and Adysângela Moniz, a judoka. Moniz and Sança were also selected as the flag bearers for the opening and closing ceremonies respectively. Of the three Cape Verdean athletes, only Moniz progressed further than the first round.
Ratapong "Nuk" Sirisanont is a Thai former swimmer, who specialized in breaststroke, but also competed in long-distance freestyle and individual medley. He is a four-time Olympian, a three-time Asian Games participant, and a seven-time SEA Games athlete (1991–2003). Regarded as Thailand's top swimmer, he has won a total of sixteen medals at the Southeast Asian Games since 1995, and six at the Asian Games, including two golds in the 200 and 400 m individual medley. At the 1996 Summer Olympics in Atlanta, Sirisanont became the first Thai swimmer to reach the final twice. Sirisanont is also one of three Southeast Asian swimmers, along with Malaysia's Alex Lim and Philippines' Miguel Molina, to train for the California Golden Bears in the United States, under head coach Nort Thornton.
Janko Gojković is a Bosnian former swimmer, who specialized in sprint freestyle and butterfly events. He is a three-time Olympian, and a member of the Bosnian swimming team since the breakup of SFR Yugoslavia in 1991. He held numerous Bosnian records in the 100 m butterfly, and achieved top finishes from the European Championships. After his sporting career ended in 2000, Gojković worked in various swim clubs across Great Britain and some parts of Eastern Europe.
Inga Petrauskaitė-Juodeškienė is a retired Lithuanian long-distance runner. She represented her nation Lithuania in two editions of the Olympic Games, and also set her own personal best of 2:31:30 in the women's division at the 2002 Frankfurt Marathon in Frankfurt, Germany. Before turning her sights to marathon in 2002, Juodeskiene ran a national record of 15:28.66 in the women's 5000 metres at the IAAF Permit Meet in Heusden-Zolder, Belgium that guaranteed her a spot on the Lithuanian team for the 2000 Summer Olympics.
Djibouti competed at the 2016 Summer Olympics in Rio de Janeiro, Brazil, from 5 to 21 August 2016. The nation's participation marked its eighth appearance at the Summer Olympics. Djibouti did not field any athletes at the 2004 Summer Olympics in Athens.
Central African Republic 
