Polythiophenes (PTs) are polymerized thiophenes, a sulfur heterocycle. The parent PT is an insoluble colored solid with the formula (C4H2S)n. The rings are linked through the 2- and 5-positions. Poly(alkylthiophene)s have alkyl substituents at the 3- or 4-position(s). They are also colored solids, but tend to be soluble in organic solvents.
Amidines are organic compounds with the functional group RC(NR)NR2, where the R groups can be the same or different. They are the imine derivatives of amides (RC(O)NR2). The simplest amidine is formamidine, HC(=NH)NH2.
The polyiodides are a class of polyhalogen anions composed entirely of iodine atoms. The most common and simplest member is the triiodide ion, I−
3. Other known larger polyiodides include [I4]2−, [I5]−, [I6]2−, [I7]−, [I8]2−, [I9]−, [I10]2−, [I10]4−, [I11]3−, [I12]2−, [I13]3−, [I14]4-, [I16]2−, [I22]4−, [I26]3−, [I26]4−, [I28]4− and [I29]3−. All these can be considered as formed from the interaction of the I–, I2, and I−
3 building blocks.
In organic chemistry, the Kumada coupling is a type of cross coupling reaction, useful for generating carbon–carbon bonds by the reaction of a Grignard reagent and an organic halide. The procedure uses transition metal catalysts, typically nickel or palladium, to couple a combination of two alkyl, aryl or vinyl groups. The groups of Robert Corriu and Makoto Kumada reported the reaction independently in 1972.
Richard Frederick Heck was an American chemist noted for the discovery and development of the Heck reaction, which uses palladium to catalyze organic chemical reactions that couple aryl halides with alkenes. The analgesic naproxen is an example of a compound that is prepared industrially using the Heck reaction.
Henry James Snaith is a professor in physics in the Clarendon Laboratory at the University of Oxford. Research from his group has led to the creation of a new research field, based on halide perovskites for use as solar absorbers. Many individuals who were PhD students and postdoctoral researchers in Snaith's group have now established research groups, independent research portfolios and commercial enterprises. He co-founded Oxford Photovoltaics in 2010 to commercialise perovskite based tandem solar cells.
Methylammonium lead halides (MALHs) are solid compounds with perovskite structure and a chemical formula of CH3NH3PbX3, where X = I, Br or Cl. They have potential applications in solar cells, lasers, light-emitting diodes, photodetectors, radiation detectors, scintillator, magneto-optical data storage and hydrogen production.
Mercouri Kanatzidis is a Charles E. and Emma H. Morrison Professor of chemistry and professor of materials science and engineering at Northwestern University and Senior Scientist at Argonne National Laboratory.
Mahdi Muhammad Abu-Omar is a Palestinian-American chemist, currently the Duncan and Suzanne Mellichamp Professor of Green Chemistry in the Departments of Chemistry & Biochemistry and Chemical Engineering at University of California, Santa Barbara.
Arnold Guloy is an American chemist who is Professor of Chemistry at the University of Houston. He is an expert in the area Zintl phases chemistry, crystal growth, materials discovery, and superconductivity.
Dmitrii "Dima" F. Perepichka is the Chair of Chemistry Department and Sir William C. MacDonald Chair Professor in Chemistry at McGill University. His research interest are primarily in the area of organic electronics. He has contributed in the understanding of structural electronics effects of organic conjugated materials at molecular, supramolecular, and macromolecular levels via the study of small molecules, supramolecular (co-)assemblies, polymers, covalent organic frameworks, and on-surface assemblies/polymers.
Luis M. Campos is an Associate Professor in the Department of Chemistry at Columbia University. Campos leads a research team focused on nanostructured materials, macromolecular systems, and single-molecule electronics.
Rachel Claire Evans is a Welsh chemist based at the University of Cambridge and a fellow of Jesus College, Cambridge. She works on photoactive polymer-hybrid materials for solar devices, including organic photovoltaics and stimuli-responsive membranes.
Eilaf Egap is an assistant professor of Materials Science at Rice University. She works on imaging techniques and biomaterials for early diagnostics and drug delivery. She was a Massachusetts Institute of Technology MLK Visiting Scholar in 2011.
Perovskite nanocrystals are a class of semiconductor nanocrystals, which exhibit unique characteristics that separate them from traditional quantum dots. Perovskite nanocrystals have an ABX3 composition where A = cesium, methylammonium (MA), or formamidinium (FA); B = lead or tin; and X = chloride, bromide, or iodide.
Hemamala Indivari Karunadasa is an assistant professor of chemistry at Stanford University. She works on hybrid organic – inorganic materials, such as perovskites, for clean energy and large area lighting.
Heather D. Maynard is the Dr Myung Ki Hong Professor in Polymer Science at the University of California, Los Angeles. She works on protein-polymer conjugates and polymeric drugs. Maynard is a Fellow of the Royal Society of Chemistry and the American Association for the Advancement of Science.
Luisa Whittaker-Brooks is an American chemist who is an associate professor at the University of Utah. She was named a L'Oréal-UNESCO For Women in Science honouree in 2013 and one of Chemical & Engineering News' Talented 12 in 2017.
Mohammad Khaja Nazeeruddin is an Indian-Swiss chemist and materials scientist who conducts research on Perovskite solar cells, dye-sensitized solar cells, and light-emitting diodes. He is a professor at EPFL and the director of the Laboratory for Molecular Engineering of Functional Materials at School of Basic Sciences.
Methylammonium tin halides are solid compounds with perovskite structure and a chemical formula of CH3NH3SnX3, where X = I, Br or Cl. They are promising lead-free alternatives to lead perovskites as photoactive semiconductor materials. Tin-based perovskites have shown excellent mobility in transistors which gives them an opportunity to be explored more for solar cell applications.
