Iron-55

Last updated
Iron-55, 55Fe
General
Symbol 55Fe
Names iron-55, 55Fe, Fe-55
Protons (Z)26
Neutrons (N)29
Nuclide data
Half-life (t1/2)2.737 years
Decay products 55Mn
Decay modes
Decay mode Decay energy (MeV)
Electron capture 0.00519
Isotopes of iron
Complete table of nuclides

Iron-55 (55Fe) is a radioactive isotope of iron with a nucleus containing 26 protons and 29 neutrons. It decays by electron capture to manganese-55 and this process has a half-life of 2.737 years. The emitted X-rays can be used as an X-ray source for various scientific analysis methods, such as X-ray diffraction. Iron-55 is also a source for Auger electrons, which are produced during the decay.

Contents

Decay

Iron-55 decays via electron capture to manganese-55 with a half-life of 2.737 years. [1] The electrons around the nucleus rapidly adjust themselves to the lowered charge without leaving their shell, and shortly thereafter the vacancy in the "K" shell left by the nuclear-captured electron is filled by an electron from a higher shell. The difference in energy is released by emitting Auger electrons of 5.19 keV, with a probability of about 60%, K-alpha-1 X-rays with energy of 5.89875 keV and a probability about 16.2%, K-alpha-2 X-rays with energy of 5.88765 keV and a probability of about 8.2%, or K-beta X-rays with nominal energy of 6.49045 keV and a probability about 2.85%. The energies of the K-alpha-1 and -2 X-rays are so similar that they are often specified as mono-energetic radiation with 5.9 keV photon energy. Its probability is about 28%. [2] The remaining 12% is accounted for by lower-energy Auger electrons and a few photons from other, minor transitions.

Use

The K-alpha X-rays emitted by the manganese-55 after the electron capture have been used as a laboratory source of X-rays in various X-ray scattering techniques. The advantages of the emitted X-rays are that they are monochromatic and are continuously produced over a years-long period. [3] No electrical power is needed for this emission, which is ideal for portable X-ray instruments, such as X-ray fluorescence instruments. [4] The ExoMars mission of ESA used, in 2016, [5] [6] such an iron-55 source for its combined X-ray diffraction/X-ray fluorescence spectrometer. [7] The 2011 Mars mission MSL used a functionally similar spectrometer, but with a traditional, electrically powered X-ray source. [8]

The Auger electrons can be applied in electron capture detectors for gas chromatography. The more widely used nickel-63 sources provide electrons from beta decay. [9]

Occurrence

Iron-55 is most effectively produced by irradiation of iron with neutrons. The reaction (54Fe(n,γ)55Fe and 56Fe(n,2n)55Fe) of the two most abundant isotopes iron-54 and iron-56 with neutrons yields iron-55. Most of the observed iron-55 is produced in these irradiation reactions, and it is not a primary fission product. [10] As a result of atmospheric nuclear tests in the 1950s, and until the test ban in 1963, considerable amounts of iron-55 have been released into the biosphere. [11] People close to the test ranges, for example Iñupiat (Alaska Natives) and inhabitants of the Marshall Islands, accumulated significant amounts of radioactive iron. However, the short half-life and the test ban decreased, within several years, the available amount of iron-55 nearly to the pre-nuclear test levels. [11] [12]

Related Research Articles

<span class="mw-page-title-main">Alpha decay</span> Type of radioactive decay

Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. It has a charge of +2 e and a mass of 4 Da. For example, uranium-238 decays to form thorium-234.

<span class="mw-page-title-main">Beta decay</span> Type of radioactive decay

In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle, transforming into an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in so-called positron emission. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron emission to be energetically possible, the energy release or Q value must be positive.

<span class="mw-page-title-main">Neutron</span> Subatomic particle with no charge

The neutron is a subatomic particle, symbol
n
or
n0
, which has a neutral charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, and each has a mass of approximately one dalton, they are both referred to as nucleons. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

<span class="mw-page-title-main">Beta particle</span> Ionizing radiation

A beta particle, also called beta ray or beta radiation, is a high-energy, high-speed electron or positron emitted by the radioactive decay of an atomic nucleus during the process of beta decay. There are two forms of beta decay, β decay and β+ decay, which produce electrons and positrons respectively.

<span class="mw-page-title-main">Electron capture</span> Process in which a proton-rich nuclide absorbs an inner atomic electron

Electron capture is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. This process thereby changes a nuclear proton to a neutron and simultaneously causes the emission of an electron neutrino.

<span class="mw-page-title-main">Radioactive decay</span> Emissions from unstable atomic nuclei

Radioactive decay is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is considered radioactive. Three of the most common types of decay are alpha, beta, and gamma decay. The weak force is the mechanism that is responsible for beta decay, while the other two are governed by the electromagnetism and nuclear force.

Ionizing radiation, including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel up to 99% of the speed of light, and the electromagnetic waves are on the high-energy portion of the electromagnetic spectrum.

A radioactive tracer, radiotracer, or radioactive label is a chemical compound in which one or more atoms have been replaced by a radionuclide so by virtue of its radioactive decay it can be used to explore the mechanism of chemical reactions by tracing the path that the radioisotope follows from reactants to products. Radiolabeling or radiotracing is thus the radioactive form of isotopic labeling. In biological contexts, use of radioisotope tracers are sometimes called radioisotope feeding experiments.

<span class="mw-page-title-main">Internal conversion</span>

Internal conversion is an atomic decay process where an excited nucleus interacts electromagnetically with one of the orbital electrons of an atom. This causes the electron to be emitted (ejected) from the atom. Thus, in internal conversion, a high-energy electron is emitted from the excited atom, but not from the nucleus. For this reason, the high-speed electrons resulting from internal conversion are not called beta particles, since the latter come from beta decay, where they are newly created in the nuclear decay process.

<span class="mw-page-title-main">Neutron activation</span> Induction of radioactivity by neutron radiation

Neutron activation is the process in which neutron radiation induces radioactivity in materials, and occurs when atomic nuclei capture free neutrons, becoming heavier and entering excited states. The excited nucleus decays immediately by emitting gamma rays, or particles such as beta particles, alpha particles, fission products, and neutrons. Thus, the process of neutron capture, even after any intermediate decay, often results in the formation of an unstable activation product. Such radioactive nuclei can exhibit half-lives ranging from small fractions of a second to many years.

Delayed nuclear radiation is a form of nuclear decay. When an isotope decays into a very short-lived isotope and then decays again to a relatively long-lived isotope, the products of the second decay are delayed. The short-lived isotope is usually a meta-stable nuclear isomer.

<span class="mw-page-title-main">Double electron capture</span> Mode of radioactive decay

Double electron capture is a decay mode of an atomic nucleus. For a nuclide (A, Z) with a number of nucleons A and atomic number Z, double electron capture is only possible if the mass of the nuclide (A, Z−2) is lower.

Naturally occurring nickel (28Ni) is composed of five stable isotopes; 58
Ni
, 60
Ni
, 61
Ni
, 62
Ni
and 64
Ni
, with 58
Ni
being the most abundant. 26 radioisotopes have been characterised with the most stable being 59
Ni
with a half-life of 76,000 years, 63
Ni
with a half-life of 100.1 years, and 56
Ni
with a half-life of 6.077 days. All of the remaining radioactive isotopes have half-lives that are less than 60 hours and the majority of these have half-lives that are less than 30 seconds. This element also has 8 meta states.

Induced radioactivity, also called artificial radioactivity or man-made radioactivity, is the process of using radiation to make a previously stable material radioactive. The husband-and-wife team of Irène Joliot-Curie and Frédéric Joliot-Curie discovered induced radioactivity in 1934, and they shared the 1935 Nobel Prize in Chemistry for this discovery.

Iodine-125 (125I) is a radioisotope of iodine which has uses in biological assays, nuclear medicine imaging and in radiation therapy as brachytherapy to treat a number of conditions, including prostate cancer, uveal melanomas, and brain tumors. It is the second longest-lived radioisotope of iodine, after iodine-129.

<span class="mw-page-title-main">Gamma ray</span> Energetic electromagnetic radiation arising from radioactive decay of atomic nuclei

A gamma ray, also known as gamma radiation (symbol γ or ), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically shorter than those of X-rays. With frequencies above 30 exahertz (3×1019 Hz), it imparts the highest photon energy. Paul Villard, a French chemist and physicist, discovered gamma radiation in 1900 while studying radiation emitted by radium. In 1903, Ernest Rutherford named this radiation gamma rays based on their relatively strong penetration of matter; in 1900 he had already named two less penetrating types of decay radiation (discovered by Henri Becquerel) alpha rays and beta rays in ascending order of penetrating power.

Characteristic X-rays are emitted when outer-shell electrons fill a vacancy in the inner shell of an atom, releasing X-rays in a pattern that is "characteristic" to each element. Characteristic X-rays were discovered by Charles Glover Barkla in 1909, who later won the Nobel Prize in Physics for his discovery in 1917.

Nuclear forensics is the investigation of nuclear materials to find evidence for the source, the trafficking, and the enrichment of the material. The material can be recovered from various sources including dust from the vicinity of a nuclear facility, or from the radioactive debris following a nuclear explosion.

References

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See also