Players
| Player | W–L (Total) | W–L (Singles) | W–L (Doubles) | Ties | Debut |
|---|---|---|---|---|---|
| Beatriz Haddad Maia | 13–5 | 9–3 | 4–2 | 10 | 2017 |
| Laura Pigossi | 8–4 | 4–2 | 4–2 | 6 | 2019 |
| Luisa Stefani | 6–2 | 0–0 | 6–2 | 4 | 2019 |
| Carolina Alves | 5–3 | 3–1 | 2–2 | 4 | 2019 |
| Ingrid Gamarra Martins | 2–1 | 0–0 | 2–1 | 2 | 2020 |
| Teliana Pereira | 22–15 | 17–10 | 5–5 | 19 | 2007 |
| Gabriela Cé | 20–12 | 15–8 | 5–4 | 16 | 2014 |
| Paula Gonçalves | 17–10 | 7–6 | 10–4 | 14 | 2012 |
| Maria Fernanda Alves | 16–12 | 11–8 | 5–4 | 14 | 2002 |
| Leticia Sobral | 9–4 | 1–1 | 8–3 | 7 | 2001 |
| Andrea Vieira | 28–14 | 20–8 | 8–6 | 23 | 1984 |
| Vanessa Menga | 7–5 | 2–2 | 5–3 | 6 | 1995 |
| Nanda Alves | 20–11 | 13–6 | 7–5 | 15 | 1996 |
| Patrícia Medrado | 31–20 | 20–10 | 11–10 | 26 | 1974 |
| Cláudia Monteiro | 18–12 | 10–7 | 8–5 | 15 | 1976 |
| Gisele Miró | 13–7 | 9–4 | 4–3 | 10 | 1985 |
| Carla Tiene | 9–9 | 2–3 | 7–6 | 10 | 2001 |
| Joana Cortez | 6–4 | 1–0 | 5–4 | 5 | 1997 |
| Roberta Burzagli | 7–5 | 5–3 | 2–2 | 6 | 1987 |
