Metals of antiquity

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German amulet to protect against disease (18th century); it is made from an alloy of the seven alchemical metals: lead, tin, iron, gold, copper, mercury and silver. Amulet to protect against health problems, Germany, 1701-190 Wellcome L0058949.jpg
German amulet to protect against disease (18th century); it is made from an alloy of the seven alchemical metals: lead, tin, iron, gold, copper, mercury and silver.
Metal production in the ancient Middle East Metal production in Ancient Middle East.svg
Metal production in the ancient Middle East

The metals of antiquity are the seven metals which humans had identified and found use for in prehistoric times in Africa, Europe and throughout Asia: [1] gold, silver, copper, tin, lead, iron, and mercury. These seven are the metals from which the classical world was forged.

Contents

Zinc, arsenic, and antimony were also known during antiquity, but they were not recognised as distinct metals until later. [2] [3] [4] [5] A special case is platinum; it was known to native South Americans around the time Europe was going through classical antiquity, but was unknown to Europeans until the 18th century. Thus, at most eleven elemental metals and metalloids were known by the end of antiquity; this contrasts greatly with the situation today, with over 90 elemental metals known. Bismuth only began to be recognised as distinct around 1500 by the European and Incan civilisations. The first elemental metal with a clearly identifiable discoverer is cobalt, discovered in 1735 by Georg Brandt, by which time the Scientific Revolution was in full swing. [6] (Even then, cobalt might have been prepared before the 13th century by alchemists roasting and reducing its ore, but in any case its distinct nature was not recognised.) [7]

History

Copper was probably the first metal mined and crafted by humans. [8] It was originally obtained as a native metal and later from the smelting of ores. Earliest estimates of the discovery of copper suggest around 9000 BC in the Middle East. It was one of the most important materials to humans throughout the Chalcolithic and Bronze Ages. Copper beads dating from 6000 BC have been found in Çatalhöyük, Anatolia [9] and the archaeological site of Belovode on the Rudnik mountain in Serbia contains the world's oldest securely dated evidence of copper smelting from 5000 BC. [10] [11] It was recognised as an element by Louis Guyton de Morveau, Antoine Lavoisier, Claude Berthollet, and Antoine-François de Fourcroy in 1787. [6]

It is believed that lead smelting began at least 9,000 years ago, and the oldest known artifact of lead is a statuette found at the temple of Osiris on the site of Abydos dated around 3800 BC. [12] It was recognised as an element by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy in 1787. [6]

The earliest gold artifacts were discovered at the site of Wadi Qana in the Levant. [13] Silver is estimated to have been discovered in Asia Minor shortly after copper and gold. [14]

There is evidence that iron was known from before 5000 BC. [15] The oldest known iron objects used by humans are some beads of meteoric iron, made in Egypt in about 4000 BC. The discovery of smelting around 3000 BC led to the start of the Iron Age around 1200 BC [16] and the prominent use of iron for tools and weapons. [17] It was recognised as an element by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy in 1787. [6]

Tin was first smelted in combination with copper around 3500 BC to produce bronze (and thus giving place to the Bronze Age (except in some places which did not experience a significant Bronze Age, passing directly from the Neolithic Stone Age to the Iron Age)). [18] Kestel, in southern Turkey, is the site of an ancient Cassiterite mine that was used from 3250 to 1800 BC. [19] The oldest artifacts date from around 2000 BC. [20] It was recognised as an element by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy in 1787. [6]

Characteristics

Melting point

The metals of antiquity generally have low melting points, with iron being the exception.

The other metals discovered before the Scientific Revolution largely fit the pattern, except for high-melting platinum:

Extraction

While all the metals of antiquity but tin and lead occur natively, only gold and silver are commonly found as the native metal.

Symbolism

The practice of alchemy in the Western world, based on a Hellenistic and Babylonian approach to planetary astronomy, often ascribed a symbolic association between the seven then-known celestial bodies and the metals known to the Greeks and Babylonians during antiquity. Additionally, some alchemists and astrologers believed there was an association, sometimes called a rulership, between days of the week, the alchemical metals, and the planets that were said to hold "dominion" over them. [27] [28] There was some early variation, but the most common associations since antiquity are the following:

MetalBodySymbolDay of week
GoldSun☉︎Sunday
SilverMoonMonday
IronMarsTuesday
MercuryMercuryWednesday
TinJupiterThursday
CopperVenusFriday
LeadSaturnSaturday

See also

Related Research Articles

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An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.

<span class="mw-page-title-main">Claude Louis Berthollet</span> French chemist (1748–1822)

Claude Louis Berthollet was a Savoyard-French chemist who became vice president of the French Senate in 1804. He is known for his scientific contributions to theory of chemical equilibria via the mechanism of reverse chemical reactions, and for his contribution to modern chemical nomenclature. On a practical basis, Berthollet was the first to demonstrate the bleaching action of chlorine gas, and was first to develop a solution of sodium hypochlorite as a modern bleaching agent.

<span class="mw-page-title-main">Metal</span> Type of material

A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.

<span class="mw-page-title-main">Metallurgy</span> Field of science that studies the physical and chemical behavior of metals

Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys.

<span class="mw-page-title-main">Smelting</span> Use of heat and a reducing agent to extract metal from ore

Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead and zinc. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal behind. The reducing agent is commonly a fossil fuel source of carbon, such as carbon monoxide from incomplete combustion of coke—or, in earlier times, of charcoal. The oxygen in the ore binds to carbon at high temperatures as the chemical potential energy of the bonds in carbon dioxide is lower than that of the bonds in the ore.

<span class="mw-page-title-main">Crucible</span> Container in which substances are heated

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<span class="mw-page-title-main">Antoine-François de Fourcroy</span> French chemist

Antoine François Fourcroy was a French chemist and a contemporary of Antoine Lavoisier. Fourcroy collaborated with Lavoisier, Guyton de Morveau, and Claude Berthollet on the Méthode de nomenclature chimique, a work that helped standardize chemical nomenclature.

<span class="mw-page-title-main">History of metallurgy in the Indian subcontinent</span>

The history of metallurgy in the Indian subcontinent began prior to the 3rd millennium BCE. Metals and related concepts were mentioned in various early Vedic age texts. The Rigveda already uses the Sanskrit term ayas. The Indian cultural and commercial contacts with the Near East and the Greco-Roman world enabled an exchange of metallurgic sciences. The advent of the Mughals further improved the established tradition of metallurgy and metal working in India. During the period of British rule in India, the metalworking industry in India stagnated due to various colonial policies, though efforts by industrialists led to the industry's revival during the 19th century.

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<span class="mw-page-title-main">Louis-Bernard Guyton de Morveau</span> French chemist

Louis-Bernard Guyton, Baron de Morveau was a French chemist, politician, and aeronaut. He is credited with producing the first systematic method of chemical nomenclature.

In metallurgy, non-ferrous metals are metals or alloys that do not contain iron in appreciable amounts.

<span class="mw-page-title-main">Native metal</span> Form of metal

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In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining, the final material is usually identical chemically to the original one, only it is purer. The processes used are of many types, including pyrometallurgical and hydrometallurgical techniques.

<span class="mw-page-title-main">Roman metallurgy</span> Production and usage of metal in ancient Rome

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<span class="mw-page-title-main">Group 11 element</span> Group of elements in the periodic table

Group 11, by modern IUPAC numbering, is a group of chemical elements in the periodic table, consisting of copper (Cu), silver (Ag), gold (Au), and roentgenium (Rg), although no chemical experiments have yet been carried out to confirm that roentgenium behaves like the heavier homologue to gold. Group 11 is also known as the coinage metals, due to their usage in minting coins—while the rise in metal prices mean that silver and gold are no longer used for circulating currency, remaining in use for bullion, copper remains a common metal in coins to date, either in the form of copper clad coinage or as part of the cupronickel alloy. They were most likely the first three elements discovered. Copper, silver, and gold all occur naturally in elemental form.

<span class="mw-page-title-main">Lead smelting</span> Process of refining lead metal

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<span class="mw-page-title-main">Non-ferrous extractive metallurgy</span> Metallurgy process

Non-ferrous extractive metallurgy is one of the two branches of extractive metallurgy which pertains to the processes of reducing valuable, non-iron metals from ores or raw material. Metals like zinc, copper, lead, aluminium as well as rare and noble metals are of particular interest in this field, while the more common metal, iron, is considered a major impurity. Like ferrous extraction, non-ferrous extraction primarily focuses on the economic optimization of extraction processes in separating qualitatively and quantitatively marketable metals from its impurities (gangue).

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Further reading