The metals of antiquity are the seven metals which humans had identified and found use for in prehistoric times in Africa, Europe and throughout Asia: [1] gold, silver, copper, tin, lead, iron, and mercury.
Zinc, arsenic, and antimony were also known during antiquity, but they were not recognised as distinct metals until later. [2] [3] [4] [5] A special case is platinum; it was known to native South Americans around the time Europe was going through classical antiquity, but was unknown to Europeans until the 18th century. Thus, at most eleven elemental metals and metalloids were known by the end of antiquity; this contrasts greatly with the situation today, with over 90 elemental metals known. Bismuth only began to be recognised as distinct around 1500 by the European and Incan civilisations. The first elemental metal with a clearly identifiable discoverer is cobalt, discovered in 1735 by Georg Brandt, by which time the Scientific Revolution was in full swing. [6] (Even then, cobalt might have been prepared before the 13th century by alchemists roasting and reducing its ore, but,in any case, its distinct nature was not recognised.) [7]
Copper was probably the first metal mined and crafted by humans. [8] It was originally obtained as a native metal and later from the smelting of ores. Earliest estimates of the discovery of copper suggest around 9000 BC in the Middle East. It was one of the most important materials to humans throughout the Chalcolithic and Bronze Ages. Copper beads dating from 6000 BC have been found in Çatalhöyük, Anatolia, [9] and the archaeological site of Belovode on the Rudnik mountain in Serbia contains the world's oldest securely dated evidence of copper smelting from 5000 BC. [10] [11] It was recognised as an element by Louis Guyton de Morveau, Antoine Lavoisier, Claude Berthollet, and Antoine-François de Fourcroy in 1787. [6]
It is believed that lead smelting began at least 9,000 years ago, and the oldest known artifact of lead is a statuette found at the temple of Osiris on the site of Abydos dated around 3800 BC. [12] It was recognised as an element by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy in 1787. [6]
The earliest gold artifacts were discovered at the site of Wadi Qana in the Levant. [13] Silver is estimated to have been discovered in Asia Minor shortly after copper and gold. [14]
There is evidence that iron was known from before 5000 BC. [15] The oldest known iron objects used by humans are some beads of meteoric iron, made in Egypt in about 4000 BC. The discovery of smelting around 3000 BC led to the start of the Iron Age around 1200 BC [16] and the prominent use of iron for tools and weapons. [17] It was recognised as an element by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy in 1787. [6]
Tin was first smelted in combination with copper around 3500 BC to produce bronze - and thus giving place to the Bronze Age (except in some places which did not experience a significant Bronze Age, passing directly from the Neolithic Stone Age to the Iron Age). [18] Kestel, in southern Turkey, is the site of an ancient Cassiterite mine that was used from 3250 to 1800 BC. [19] The oldest artifacts date from around 2000 BC. [20] It was recognised as an element by Guyton de Morveau, Lavoisier, Berthollet, and Fourcroy in 1787. [6]
The metals of antiquity generally have low melting points, with iron being the exception.
The other metals discovered before the Scientific Revolution largely fit the pattern, except for high-melting platinum:
While all the metals of antiquity but lead occur natively, only gold and silver are commonly found as the native metal.
The practice of alchemy in the Western world, based on a Hellenistic and Babylonian approach to planetary astronomy, often ascribed a symbolic association between the seven then-known celestial bodies and the metals known to the Greeks and Babylonians during antiquity. Additionally, some alchemists and astrologers believed there was an association, sometimes called a rulership, between days of the week, the alchemical metals, and the planets that were said to hold "dominion" over them. [27] [28] There was some early variation, but the most common associations since antiquity are the following:
Metal | Body | Symbol | Day of week |
---|---|---|---|
Gold | Sun | ☉︎ | Sunday |
Silver | Moon | ☾ | Monday |
Iron | Mars | ♂ | Tuesday |
Mercury | Mercury | ☿ | Wednesday |
Tin | Jupiter | ♃ | Thursday |
Copper | Venus | ♀ | Friday |
Lead | Saturn | ♄ | Saturday |
An alloy is a mixture of chemical elements of which in most cases at least one is a metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Most alloys are metallic and show good electrical conductivity, ductility, opacity, and luster, and may have properties that differ from those of the pure elements such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties such as corrosion resistance or mechanical strength.
Claude Louis Berthollet was a Savoyard-French chemist who became vice president of the French Senate in 1804. He is known for his scientific contributions to the theory of chemical equilibria via the mechanism of reverse chemical reactions, and for his contribution to modern chemical nomenclature. On a practical basis, Berthollet was the first to demonstrate the bleaching action of chlorine gas, and was first to develop a solution of sodium hypochlorite as a modern bleaching agent.
A metal is a material that, when polished or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. These properties are all associated with having electrons available at the Fermi level, as against nonmetallic materials which do not. Metals are typically ductile and malleable.
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys.
Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead and zinc. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal behind. The reducing agent is commonly a fossil-fuel source of carbon, such as carbon monoxide from incomplete combustion of coke—or, in earlier times, of charcoal. The oxygen in the ore binds to carbon at high temperatures, as the chemical potential energy of the bonds in carbon dioxide is lower than that of the bonds in the ore.
A crucible is a container in which metals or other substances may be melted or subjected to very high temperatures. Although crucibles have historically tended to be made out of clay, they can be made from any material that withstands temperatures high enough to melt or otherwise alter its contents.
Antoine François Fourcroy was a French chemist and a contemporary of Antoine Lavoisier. Fourcroy collaborated with Lavoisier, Guyton de Morveau, and Claude Berthollet on the Méthode de nomenclature chimique, a work that helped standardize chemical nomenclature.
The history of metallurgy in the Indian subcontinent began prior to the 3rd millennium BCE. Metals and related concepts were mentioned in various early Vedic age texts. The Rigveda already uses the Sanskrit term ayas. The Indian cultural and commercial contacts with the Near East and the Greco-Roman world enabled an exchange of metallurgic sciences. The advent of the Mughals further improved the established tradition of metallurgy and metal working in India. During the period of British rule in India, the metalworking industry in India stagnated due to various colonial policies, though efforts by industrialists led to the industry's revival during the 19th century.
Chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used most frequently worldwide is the one created and developed by the International Union of Pure and Applied Chemistry (IUPAC).
Louis-Bernard Guyton, Baron de Morveau was a French chemist, politician, and aeronaut. He is credited with producing the first systematic method of chemical nomenclature.
In metallurgy, non-ferrous metals are metals or alloys that do not contain iron in appreciable amounts.
In the history of chemistry, the chemical revolution, also called the first chemical revolution, was the reformulation of chemistry during the seventeenth and eighteenth centuries, which culminated in the law of conservation of mass and the oxygen theory of combustion.
A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.
Metals and metal working had been known to the people of modern Italy since the Bronze Age. By 53 BC, Rome had expanded to control an immense expanse of the Mediterranean. This included Italy and its islands, Spain, Macedonia, Africa, Asia Minor, Syria and Greece; by the end of the Emperor Trajan's reign, the Roman Empire had grown further to encompass parts of Britain, Egypt, all of modern Germany west of the Rhine, Dacia, Noricum, Judea, Armenia, Illyria, and Thrace. As the empire grew, so did its need for metals.
Group 11, by modern IUPAC numbering, is a group of chemical elements in the periodic table, consisting of copper (Cu), silver (Ag), gold (Au), and roentgenium (Rg), although no chemical experiments have yet been carried out to confirm that roentgenium behaves like the heavier homologue to gold. Group 11 is also known as the coinage metals, due to their usage in minting coins—while the rise in metal prices mean that silver and gold are no longer used for circulating currency, remaining in use for bullion, copper remains a common metal in coins to date, either in the form of copper clad coinage or as part of the cupronickel alloy. They were most likely the first three elements discovered. Copper, silver, and gold all occur naturally in elemental form.
Plants for the production of lead are generally referred to as lead smelters. Primary lead production begins with sintering. Concentrated lead ore is fed into a sintering machine with iron, silica, limestone fluxes, coke, soda ash, pyrite, zinc, caustics or pollution control particulates. Smelting uses suitable reducing substances that will combine with those oxidizing elements to free the metal. Reduction is the final, high-temperature step in smelting. It is here that the oxide becomes the elemental metal. A reducing environment pulls the final oxygen atoms from the raw metal.
Non-ferrous extractive metallurgy is one of the two branches of extractive metallurgy which pertains to the processes of reducing valuable, non-iron metals from ores or raw material. Metals like zinc, copper, lead, aluminium as well as rare and noble metals are of particular interest in this field, while the more common metal, iron, is considered a major impurity. Like ferrous extraction, non-ferrous extraction primarily focuses on the economic optimization of extraction processes in separating qualitatively and quantitatively marketable metals from its impurities (gangue).
William Arthur Smeaton was a British chemist and historian of science, who wrote more than seventy-five articles and several books on the history of chemistry in France in the 18th and 19th centuries.
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