Nahcolite

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Nahcolite
Nahcolite-20212.jpg
Nahcolite from California (size: 9.5 x 8 x 4 cm)
General
Category Carbonate mineral
Formula
(repeating unit)
Sodium bicarbonate (NaHCO3)
IMA symbol Nah [1]
Strunz classification 5.AA.15
Dana classification13.01.01.01
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/n
Unit cell a = 7.47, b = 9.68
c = 3.48 [Å]; β = 93.38°; Z = 4
Identification
ColourWhite to colourless, may be grey to brown
Crystal habit Elongated crystals, fibrous masses, friable porous aggregates
Twinning Common on [101]
Cleavage {101} perfect, {111} good, {100} distinct
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness2.5
Lustre Vitreous – resinous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.21
Optical propertiesBiaxial (−)
Refractive index nα = 1.377 nβ = 1.503 nγ = 1.583
Birefringence δ = 0.206
Ultraviolet fluorescence Short UV=blue-white cream-yellow, Long UV=cream-yellow
Solubility Soluble in water
References [2] [3] [4]

Nahcolite is a soft, colourless or white carbonate mineral with the composition of sodium bicarbonate (Na H C O 3) also called thermokalite. It crystallizes in the monoclinic system. [4]

Nahcolite was first described in 1928 for an occurrence in a lava tunnel at Mount Vesuvius, Italy. [2] Its name refers to the elements which compose it: Na, H, C, and O. [5] It occurs as a hot spring and saline lake precipitate or efflorescence; in differentiated alkalic massifs; in fluid inclusions as a daughter mineral phase and in evaporite deposits. [2] [4]

It occurs in association with trona, thermonatrite, thenardite, halite, gaylussite, burkeite, northupite and borax. [3] It has been reported in a Roman conduit at Stufe de Nerone, Campi Flegrei, near Naples; in the U. S. from Searles Lake, San Bernardino County, California; in the Green River Formation, Colorado and Utah; in the Tincalayu deposit, Salar del Hombre Muerto, Salta Province, Argentina; on Mt. Alluaiv, Lovozero Massif and Khibiny Massif, Kola Peninsula, Russia; and around Mount Erebus, Victoria Land, Antarctica. [3]

Nahcolite deposition model in the Uinta-Piceance basin system, United States Nahcolite deposition model.png
Nahcolite deposition model in the UintaPiceance basin system, United States

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References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Nahcolite on Mindat.org
  3. 1 2 3 Nahcolite in the Handbook of Mineralogy
  4. 1 2 3 Nahcolite data on Webmineral
  5. Richard V. Gaines, H. Catherine W. Skinner, Eugene E. Foord, Brian Mason, and Abraham Rosenzweig: Dana's new mineralogy, John Wiley & Sons, 1997