Nahcolite

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Nahcolite
Nahcolite-20212.jpg
Nahcolite from California (size: 9.5 x 8 x 4 cm)
General
Category Carbonate mineral
Formula Sodium bicarbonate (NaHCO3)
IMA symbol Nah [1]
Strunz classification 5.AA.15
Dana classification 13.01.01.01
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/n
Unit cell a = 7.47, b = 9.68
c = 3.48 [Å]; β = 93.38°; Z = 4
Identification
ColourWhite to colourless, may be grey to brown
Crystal habit Elongated crystals, fibrous masses, friable porous aggregates
Twinning Common on [101]
Cleavage {101} perfect, {111} good, {100} distinct
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness2.5
Lustre Vitreous – resinous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.21
Optical propertiesBiaxial (−)
Refractive index nα = 1.377 nβ = 1.503 nγ = 1.583
Birefringence δ = 0.206
Ultraviolet fluorescence Short UV=blue-white cream-yellow, Long UV=cream-yellow
Solubility Soluble in water
References [2] [3] [4]

Nahcolite is a soft, colourless or white carbonate mineral with the composition of sodium bicarbonate (Na H C O 3) also called thermokalite. It crystallizes in the monoclinic system. [4]

Nahcolite was first described in 1928 for an occurrence in a lava tunnel at Mount Vesuvius, Italy. [2] Its name refers to the elements which compose it: Na, H, C, and O. [5] It occurs as a hot spring and saline lake precipitate or efflorescence; in differentiated alkalic massifs; in fluid inclusions as a daughter mineral phase and in evaporite deposits. [2] [4]

It occurs in association with trona, thermonatrite, thenardite, halite, gaylussite, burkeite, northupite and borax. [3] It has been reported in a Roman conduit at Stufe de Nerone, Campi Flegrei, near Naples; in the United States from Searles Lake, San Bernardino County, California; in the Green River Formation, Colorado and Utah; in the Tincalayu deposit, Salar del Hombre Muerto, Salta Province, Argentina; on Mt. Alluaiv, Lovozero Massif and Khibiny Massif, Kola Peninsula, Russia; and around Mount Erebus, Victoria Land, Antarctica. [3]

Nahcolite deposition model in the Uinta-Piceance basin system, United States Nahcolite deposition model.png
Nahcolite deposition model in the UintaPiceance basin system, United States

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Nahcolite on Mindat.org
  3. 1 2 3 Nahcolite in the Handbook of Mineralogy
  4. 1 2 3 Nahcolite data on Webmineral
  5. Richard V. Gaines, H. Catherine W. Skinner, Eugene E. Foord, Brian Mason, and Abraham Rosenzweig: Dana's new mineralogy, John Wiley & Sons, 1997