A "photoelectrochemical cell" is one of two distinct classes of device. The first produces electrical energy similarly to a dye-sensitized photovoltaic cell, which meets the standard definition of a photovoltaic cell. The second is a photoelectrolytic cell, that is, a device which uses light incident on a photosensitizer, semiconductor, or aqueous metal immersed in an electrolytic solution to directly cause a chemical reaction, for example to produce hydrogen via the electrolysis of water.
Artificial photosynthesis is a chemical process that biomimics the natural process of photosynthesis to convert sunlight, water, and carbon dioxide into carbohydrates and oxygen. The term artificial photosynthesis is commonly used to refer to any scheme for capturing and storing the energy from sunlight in the chemical bonds of a fuel. Photocatalytic water splitting converts water into hydrogen and oxygen and is a major research topic of artificial photosynthesis. Light-driven carbon dioxide reduction is another process studied that replicates natural carbon fixation.
Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen:
The Global Climate and Energy Project (GCEP) at Stanford University, "seeks new solutions to one of the grand challenges of this century: supplying energy to meet the changing needs of a growing world population in a way that protects the environment."
Harry Albert Atwater, Jr. is an American physicist and materials scientist and is the Otis Booth Leadership Chair of the division of engineering and applied science at the California Institute of Technology. Currently he is the Howard Hughes Professor of Applied Physics and Materials Science and the director for the Liquid Sunlight Alliance (LiSA), a Department of Energy Hub program for solar fuels. Atwater's scientific effort focuses on nanophotonic light-matter interactions and solar energy conversion. His current research in energy centers on high efficiency photovoltaics, carbon capture and removal, and photoelectrochemical processes for generation of solar fuels. His research has resulted in world records for solar photovoltaic conversion and photoelectrochemical water splitting. His work also spans fundamental nanophotonic phenomena, in plasmonics and 2D materials, and also applications including active metasurfaces and optical propulsion.
Michael Grätzel is a professor at the École Polytechnique Fédérale de Lausanne where he directs the Laboratory of Photonics and Interfaces. He pioneered research on energy and electron transfer reactions in mesoscopic-materials and their optoelectronic applications. He co-invented with Brian O'Regan the Grätzel cell in 1988.
Daniel George Nocera is an American chemist, currently the Patterson Rockwood Professor of Energy in the Department of Chemistry and Chemical Biology at Harvard University. He is a member of the National Academy of Sciences and the American Academy of Arts and Sciences. In 2006 he was described as a "major force in the field of inorganic photochemistry and photophysics". Time magazine included him in its 2009 list of the 100 most influential people.
Arthur J. Nozik is a researcher at the National Renewable Energy Lab (NREL). He is also a professor at the University of Colorado, which is located in Boulder. He researches semiconductor quantum dots at the National Renewable Energy Laboratory, and is a chemistry professor at the University of Colorado. He also does research for the advancement of solar energy, for which he won the Intergovernmental Renewable Energy Organization (IREO) Award for Science and Technology in 2009.
Andrew Bruce Bocarsly is currently a professor at Princeton University, New Jersey. His primary research interests lie in physical inorganic chemistry. He conducts research in electrochemistry, photochemistry, solids state chemistry, and fuel cells, and is known for his work on alternate energy solutions involving processes and materials for photo-reduction and electro-reduction.
Photoelectrochemistry is a subfield of study within physical chemistry concerned with the interaction of light with electrochemical systems. It is an active domain of investigation. One of the pioneers of this field of electrochemistry was the German electrochemist Heinz Gerischer. The interest in this domain is high in the context of development of renewable energy conversion and storage technology.
Photoelectrochemical reduction of carbon dioxide, also known as photoelectrolysis of carbon dioxide, is a chemical process whereby carbon dioxide is reduced to carbon monoxide or hydrocarbons by the energy of incident light. This process requires catalysts, most of which are semiconducting materials. The feasibility of this chemical reaction was first theorised by Giacomo Luigi Ciamician, an Italian photochemist. Already in 1912 he stated that "[b]y using suitable catalyzers, it should be possible to transform the mixture of water and carbon dioxide into oxygen and methane, or to cause other endo-energetic processes."
A solar fuel is a synthetic chemical fuel produced from solar energy. Solar fuels can be produced through photochemical, photobiological, and electrochemical reactions.
Quantum photoelectrochemistry is the investigation of the quantum mechanical nature of photoelectrochemistry, the subfield of study within physical chemistry concerned with the interaction of light with electrochemical systems, typically through the application of quantum chemical calculations. Quantum photoelectrochemistry provides an expansion of quantum electrochemistry to processes involving also the interaction with light (photons). It therefore also includes essential elements of photochemistry. Key aspects of quantum photoelectrochemistry are calculations of optical excitations, photoinduced electron and energy transfer processes, excited state evolution, as well as interfacial charge separation and charge transport in nanoscale energy conversion systems.
Stacey Bent is a professor of chemical engineering and vice provost for graduate education and postdoctoral affairs (VPGE) at Stanford University. She is the Jagdeep and Roshni Singh Professor of Engineering, the Bert and Candace Forbes University Fellow in Undergraduate Education, and a member of the National Academy of Engineering. She was the director of the TomKat Center for Sustainable Energy and a senior associate dean in the Stanford School of Engineering until 2019. She is best known for contributions to semiconductor processing, materials chemistry, and surface science. Her work has been applied toward applications in semiconductors, solar cells, and catalysts.
Brandi Michelle Cossairt is an American chemist specializing in synthetic inorganic and materials chemistry. She is the Lloyd E. and Florence M. West Endowed Professor of Chemistry at University of Washington.
Light harvesting materials harvest solar energy that can then be converted into chemical energy through photochemical processes. Synthetic light harvesting materials are inspired by photosynthetic biological systems such as light harvesting complexes and pigments that are present in plants and some photosynthetic bacteria. The dynamic and efficient antenna complexes that are present in photosynthetic organisms has inspired the design of synthetic light harvesting materials that mimic light harvesting machinery in biological systems. Examples of synthetic light harvesting materials are dendrimers, porphyrin arrays and assemblies, organic gels, biosynthetic and synthetic peptides, organic-inorganic hybrid materials, and semiconductor materials. Synthetic and biosynthetic light harvesting materials have applications in photovoltaics, photocatalysis, and photopolymerization.
Shannon W. Boettcher is a Professor in the Department of Chemistry and Biochemistry at the University of Oregon. His research is at the intersection of materials science and electrochemistry, with a focus on fundamental aspects of energy conversion and storage. He has been named a DuPont Young Professor, a Cottrell Scholar, a Sloan Fellow, and a Camille-Dreyfus Teacher-Scholar. He is a ISI highly cited researcher. In 2019, he founded the Oregon Center for Electrochemistry and in 2020 launched the nation's first targeted graduate program in electrochemical technology. In 2021 he was named a Blavatnik National Award Finalist.
Emily Warren is an American chemical engineer who is a staff scientist at the National Renewable Energy Laboratory. Her research considers high efficiency crystalline photovoltaics.
Stafford W. Sheehan is an American scientist and entrepreneur, a co-founder and chief technology officer of Air Company. He developed a heterogeneous catalysis process to convert carbon dioxide into ethanol that his company has used to produce vodka and other consumer products as well as jet fuel.
Krishnan Rajeshwar is a chemist, researcher and academic. He is a Distinguished University Professor and Founding Director of the Center for Renewable Energy Science & Technology at The University of Texas at Arlington.
“Powering the Planet: Where in the World Will Our Energy Come From?”, Nate Lewis, 2005, Caltech 