Paleo-inspiration

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Paleo-inspiration is a paradigm shift that leads scientists and designers to draw inspiration from ancient materials (from art, archaeology, natural history or paleo-environments) to develop new systems or processes, particularly with a view to sustainability.

Contents

Paleo-inspiration has already contributed to numerous applications in fields as varied as green chemistry, the development of new artist materials, composite materials, microelectronics, and construction materials. [1]

Semantics and definitions

While this type of application has been known for a long time, the concept itself was coined by teams from the French National Centre for Scientific Research, the Massachusetts Institute of Technology and the Bern University of Applied Sciences from the term Bioinspiration. They published the concept in a seminal paper published online in 2017 by the journal Angewandte Chemie . [2]

Different names have been used to designate the corresponding systems, in particular: paleo-inspired, [2] antiqua-inspired, [1] antiquity-inspired [3] or archaeomimetic. [4] The use of these different names illustrates the extremely large time gap between the sources of inspiration, from millions of years ago when considering palaeontological systems and fossils, to much more recent archaeological or artistic material systems.

Properties sought

Distinct physico-chemical and mechanical properties are sought.

They may concern intrinsic properties of the paleo-inspired materials:

They can also concern processes:

The paleo-inspired approach

This approach combines several key stages.

Practical applications

Sustainable building materials

Emblematic examples include the microscopic study of the mineral phases present in Roman concretes to reproduce their durability in aggressive environments, particularly in the marine environment. [7]

Durable colouring materials

A notable discovery is the elucidation of the atomic structure of Maya blue, a composite pigment combining a clay with an organic dye, which has led teams to produce pigments of other colours by combining clays with distinct organic dyes, such as "Maya violet". [8]

Related Research Articles

<span class="mw-page-title-main">Hematite</span> Common iron oxide mineral

Hematite, also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of Fe
2
O
3
. It has the same crystal structure as corundum (Al
2
O
3
) and ilmenite (FeTiO
3
). With this it forms a complete solid solution at temperatures above 950 °C (1,740 °F).

<span class="mw-page-title-main">Biomimetics</span> Imitation of biological systems for the solving of human problems

Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from Ancient Greek: βίος (bios), life, and μίμησις (mīmēsis), imitation, from μιμεῖσθαι (mīmeisthai), to imitate, from μῖμος (mimos), actor. A closely related field is bionics.

<span class="mw-page-title-main">Pigment</span> Colored material

A pigment is a powder used to add color or change visual appearance. Pigments are completely or nearly insoluble and chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli.

<span class="mw-page-title-main">Diagenesis</span> Physico-chemical changes in sediments occurring after their deposition

Diagenesis is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion, while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens.

<span class="mw-page-title-main">Titanium dioxide</span> Chemical compound often used as a white pigment, Including in food and paints.

Titanium dioxide, also known as titanium(IV) oxide or titania, is the inorganic compound with the chemical formula TiO
2
. When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insoluble in water, although mineral forms can appear black. As a pigment, it has a wide range of applications, including paint, sunscreen, and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million tonnes. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide have been valued at a price of $13.2 billion.

<span class="mw-page-title-main">Zinc oxide</span> White powder insoluble in water

Zinc oxide is an inorganic compound with the formula ZnO. It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement, lubricants, paints, sunscreens, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, semi conductors, and first-aid tapes. Although it occurs naturally as the mineral zincite, most zinc oxide is produced synthetically.

<span class="mw-page-title-main">Copper phthalocyanine</span> Synthetic blue pigment from the group of phthalocyanine dyes

Copper phthalocyanine (CuPc), also called phthalocyanine blue, phthalo blue and many other names, is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. Its brilliant blue is frequently used in paints and dyes. It is highly valued for its superior properties such as light fastness, tinting strength, covering power and resistance to the effects of alkalis and acids. It has the appearance of a blue powder, insoluble in most solvents including water.

<span class="mw-page-title-main">Dyeing</span> Process of adding color to textile products like fibers, yarns, and fabrics

Dyeing is the application of dyes or pigments on textile materials such as fibers, yarns, and fabrics with the goal of achieving color with desired color fastness. Dyeing is normally done in a special solution containing dyes and particular chemical material. Dye molecules are fixed to the fiber by absorption, diffusion, or bonding with temperature and time being key controlling factors. The bond between the dye molecule and fiber may be strong or weak, depending on the dye used. Dyeing and printing are different applications; in printing, color is applied to a localized area with desired patterns. In dyeing, it is applied to the entire textile.

<span class="mw-page-title-main">Quinacridone</span> Organic compound used as a pigment

Quinacridone is an organic compound used as a pigment. Numerous derivatives constitute the quinacridone pigment family, which finds extensive use in industrial colorant applications such as robust outdoor paints, inkjet printer ink, tattoo inks, artists' watercolor paints, and color laser printer toner. As pigments, the quinacridones are insoluble. The development of this family of pigments supplanted the alizarin dyes.

<span class="mw-page-title-main">Thermochromism</span> Property of substances to change colour due to a change in temperature

Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a different color when cool enough to drink, or kettles which change color when water is at or near boiling point. Thermochromism is one of several types of chromism.

<span class="mw-page-title-main">Piezochromism</span>

Piezochromism, from the Greek piezô "to squeeze, to press" and chromos "color", describes the tendency of certain materials to change color with the application of pressure. This effect is closely related to the electronic band gap change, which can be found in plastics, semiconductors and hydrocarbons. One simple molecule displaying this property is 5-methyl-2-[(2-nitrophenyl)amino]-3-thiophenecarbonitrile, also known as ROY owing to its red, orange and yellow crystalline forms. Individual yellow and pale orange versions transform reversibly to red at high pressure.

<span class="mw-page-title-main">Priverno</span> Comune in Lazio, Italy

Priverno is a town, comune in the province of Latina, Lazio, central Italy. It was called Piperno until 1927.

<span class="mw-page-title-main">Maya blue</span> Azure blue pigment made in pre-Columbian Mesoamerica

Maya blue is a unique bright azure blue pigment manufactured by cultures of pre-Columbian Mesoamerica, such as the Mayans and Aztecs.

Sulfur concrete, sometimes named thioconcrete or sulfurcrete, is a composite construction material, composed mainly of sulfur and aggregate. Cement and water, important compounds in normal concrete, are not part of sulfur concrete. The concrete is heated above the melting point of elemental sulfur at ca. 140 °C (284 °F) in a ratio of between 12% and 25% sulfur, the rest being aggregate.

<span class="mw-page-title-main">Cultural property radiography</span>

The radiography of cultural property is the use of radiography to understand intrinsic details about objects. Most commonly this involves X-rays of paintings to reveal underdrawing, pentimenti alterations in the course of painting or by later restorers, and sometimes previous paintings on the support. Many pigments such as lead white show well in radiographs.

<span class="mw-page-title-main">YInMn Blue</span> Inorganic blue pigment

YInMn Blue, also known as Oregon Blue or Mas Blue, is an inorganic blue pigment that was discovered by Mas Subramanian and his (then) graduate student, Andrew Smith, at Oregon State University in 2009. The pigment is noteworthy for its vibrant, near-perfect blue color and unusually high NIR reflectance. The chemical compound has a unique crystal structure in which trivalent manganese ions in the trigonal bipyramidal coordination are responsible for the observed intense blue color. Since the initial discovery, the fundamental principles of colour science have been explored extensively by the Subramanian research team at Oregon State University, resulting in a wide range of rationally designed novel green, purple, and orange pigments, all through intentional addition of a chromophore in the trigonal bipyramidal coordination environment.

Admir Masic is a scientist, currently an Associate Professor at the Massachusetts Institute of Technology. His research involves characterization of complex biomineralized and archaeological structural materials with the objective of inspiring the design of more sustainable and durable building materials.

Bioinspiration is the development of novel materials, devices, and structures inspired by solutions found in biological evolution and refinement which has occurred over millions of years. The goal is to improve modeling and simulation of the biological system to attain a better understanding of nature's critical structural features, such as a wing, for use in future bioinspired designs. Bioinspiration differs from biomimicry in that the latter aims to precisely replicate the designs of biological materials. Bioinspired research is a return to the classical origins of science: it is a field based on observing the remarkable functions that characterize living organisms and trying to abstract and imitate those functions.

Light harvesting materials harvest solar energy that can then be converted into chemical energy through photochemical processes. Synthetic light harvesting materials are inspired by photosynthetic biological systems such as light harvesting complexes and pigments that are present in plants and some photosynthetic bacteria. The dynamic and efficient antenna complexes that are present in photosynthetic organisms has inspired the design of synthetic light harvesting materials that mimic light harvesting machinery in biological systems. Examples of synthetic light harvesting materials are dendrimers, porphyrin arrays and assemblies, organic gels, biosynthetic and synthetic peptides, organic-inorganic hybrid materials, and semiconductor materials. Synthetic and biosynthetic light harvesting materials have applications in photovoltaics, photocatalysis, and photopolymerization.

<span class="mw-page-title-main">Tacharanite</span> Calcium aluminium silicate hydrate mineral

Tacharanite is a calcium aluminium silicate hydrate (C-A-S-H) mineral of general chemical formula Ca12Al2Si18O33(OH)36 with some resemblance to the calcium silicate hydrate (C-S-H) mineral tobermorite. It is often found in mineral assemblage with zeolites and other hydrated calcium silicates.

References

  1. 1 2 "A new perspective on ancient materials inspires future innovation". MIT News | Massachusetts Institute of Technology. 20 November 2017. Retrieved 2022-02-08.
  2. 1 2 Bertrand, Loïc; Gervais, Claire; Masic, Admir; Robbiola, Luc (2018). "Paleo-inspired Systems: Durability, Sustainability, and Remarkable Properties". Angewandte Chemie International Edition. 57 (25): 7288–7295. doi:10.1002/anie.201709303. ISSN   1521-3773. PMID   29154403. S2CID   205405638.
  3. Faber, Katherine T.; Casadio, Francesca; Masic, Admir; Robbiola, Luc; Walton, Marc (2021-07-26). "Looking Back, Looking Forward: Materials Science in Art, Archaeology, and Art Conservation". Annual Review of Materials Research. 51 (1): 435–460. Bibcode:2021AnRMS..51..435F. doi:10.1146/annurev-matsci-080819-013103. ISSN   1531-7331. S2CID   235522737.
  4. Powell, Devin; Service, Inside Science News. "Ancient Mayans Inspire Modern Fade Proof Dye". phys.org. Retrieved 2022-02-14.
  5. Sciau, Philippe; Goudeau, Philippe (25 May 2015). "Ceramics in art and archaeology: a review of the materials science aspects". The European Physical Journal B. 88 (5): 132. Bibcode:2015EPJB...88..132S. doi:10.1140/epjb/e2015-60253-8. ISSN   1434-6028. S2CID   18014681.
  6. Bertrand, Loïc; Thoury, Mathieu; Gueriau, Pierre; Anheim, Étienne; Cohen, Serge (2021-07-06). "Deciphering the Chemistry of Cultural Heritage: Targeting Material Properties by Coupling Spectral Imaging with Image Analysis". Accounts of Chemical Research. 54 (13): 2823–2832. doi:10.1021/acs.accounts.1c00063. ISSN   0001-4842. PMID   34143613. S2CID   235481574.
  7. Preuss, Paul (2013-06-04). "Roman Seawater Concrete Holds the Secret to Cutting Carbon Emissions". News Center. Retrieved 2022-02-14.
  8. Zhang, Yujie; Zhang, Junping; Wang, Aiqin (2015). "Facile preparation of stable palygorskite/methyl violet@SiO2 "Maya Violet" pigment". Journal of Colloid and Interface Science. 457: 254–263. Bibcode:2015JCIS..457..254Z. doi:10.1016/j.jcis.2015.07.030. PMID   26196708.