Phyllic alteration

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Phyllic alteration is a hydrothermal alteration zone in a permeable rock that has been affected by circulation of hydrothermal fluids. It is commonly seen in copper porphyry ore deposits in calc-alkaline rocks. Phyllic alteration is characterised by the assemblage of quartz + sericite + pyrite, and occurs at high temperatures and moderately acidic (low pH) conditions. [1]

Hydrogen-ion metasomatism is the process that causes phyllic alteration. While the mineralogy of the rock is altered throughout, texture is preserved and primary porphyry structure (including position of original veins) may still be visible. [2] If a rock undergoes phyllic alteration, then orthoclase feldspar, biotite and various silicates are altered in addition to plagioclase. Plagioclase will be altered to sericite (a fine-grained white mica) by sericitic alteration, and mafic minerals are replaced by quartz. [2] Tourmaline may appear as radiating aggregate or prismatic crystals between the quartz-sericite assemblage. [2] Phyllic alteration is often closely associated with argillic alteration, which occurs at lower temperatures and dominantly affects plagioclase. [3]

Variation with depth

Phyllic alteration typically forms in the base-metal zone of a porphyry system. [2] Alteration assemblages vary with depth and with degree of fluid interaction. In deep environments, the most highly altered areas are veins and thin selvages, or halos, that surround them. The selvages are generally <10 cm in diameter and composed of major sericite and minor quartz. Vein orientation is preserved from original rock, but minerals within are mostly replaced by pyrite. [3] With decreasing depth, selvages widen (10 cm - 1m) and contain more quartz and pyrite.

Outside of selvages, most alteration occurs in replacement of mafic minerals by chlorite and of plagioclase by sericite. [3]

Related Research Articles

Amphibolite A metamorphic rock containing mainly amphibole and plagioclase

Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.

Skarn Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional, or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from either magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.

Metasomatism Chemical alteration of a rock by hydrothermal and other fluids

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Chlorite group Type of mineral

The chlorites are a group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

Lamprophyre Ultrapotassic igneous rocks

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References

Sericite at Mindat

  1. Yant, Marcella (2009). "Hydrothermal Alteration". www.indiana.edu. Indiana University.
  2. 1 2 3 4 Damian, Floarea (2003). "The Mineralogical Characteristics and the Zoning of the Hydrothermal Types of Alteration from the Nistru Ore Deposit, Baia Mare Metallogenic District". scholarcommons.usf.edu. Studia Universitatis Babes-Bolyai. Retrieved 18 April 2014.
  3. 1 2 3 Parry, W. T.; Jasumback, M.; Wilson, P. N. (2002). "Clay Mineralogy of Phyllic and Intermediate Argillic Alteration at Bingham, Utah". Economic Geology. 97: 221–239. doi:10.2113/gsecongeo.97.2.221.