Argillic alteration is hydrothermal alteration [ citation needed ] of wall rock which introduces clay minerals including kaolinite, smectite and illite. The process generally occurs at low temperatures and may occur in atmospheric conditions. Argillic alteration is representative of supergene environments where low temperature groundwater becomes acidic.
Argillic assemblages include kaolinite replacing plagioclase and montmorillonite replacing amphibole and plagioclase. Orthoclase is generally stable and unaffected. Argillic grades into phyllic alteration at higher temperatures in an ore deposit hydrothermal system. [1]
Advanced argillic alteration occurs under lower pH and higher temperature conditions. Kaolinite and dickite occur at lower temperatures whereas pyrophyllite and andalusite occur under high temperature conditions (T > 300°C). Quartz deposition is common. Alunite, topaz, zunyite, tourmaline, enargite and tennantite may also occur. Greisen alteration is similar. [1]
Kaolinite is a clay mineral, with the chemical composition Al2Si2O5(OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica (SiO
4) linked through oxygen atoms to one octahedral sheet of alumina (AlO
6) octahedra. Rocks that are rich in kaolinite are known as kaolin or china clay.
Metamorphism is the change of minerals or geologic texture in pre-existing rocks (protoliths), without the protolith melting into liquid magma. The change occurs primarily due to heat, pressure, and the introduction of chemically active fluids. The chemical components and crystal structures of the minerals making up the rock may change even though the rock remains a solid. Changes at or just beneath Earth's surface due to weathering or diagenesis are not classified as metamorphism. Metamorphism typically occurs between diagenesis, and melting (~850°C).
Hydrothermal circulation in its most general sense is the circulation of hot water. Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism.
Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase.
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional, or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from either magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on the original composition of both the hydrothermal fluid and the original composition of the protolith.
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.
The chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the following four elements in the silicate lattice; Mg, Fe, Ni, and Mn.
Volcanogenic massive sulfide ore deposits, also known as VMS ore deposits, are a type of metal sulfide ore deposit, mainly copper-zinc which are associated with and created by volcanic-associated hydrothermal events in submarine environments.
Sericite is the name given to very fine, ragged grains and aggregates of white (colourless) micas, typically made of muscovite, illite, or paragonite. Sericite is produced by the alteration of orthoclase or plagioclase feldspars in areas that have been subjected to hydrothermal alteration typically associated with copper, tin, or other hydrothermal ore deposits. Sericite also occurs as the fine mica that gives the sheen to phyllite and schistose metamorphic rocks.
Various theories of ore genesis explain how the various types of mineral deposits form within the Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
Zeolite facies describes the mineral assemblage resulting from the pressure and temperature conditions of low-grade metamorphism.
Sedimentary exhalative deposits are ore deposits which are interpreted to have been formed by release of ore-bearing hydrothermal fluids into a water reservoir, resulting in the precipitation of stratiform ore.
Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic with reference to sedimentary rocks as well as to particles in sediment transport whether in suspension or as bed load, and in sediment deposits.
Uranium ore deposits are economically recoverable concentrations of uranium within the Earth's crust. Uranium is one of the more common elements in the Earth's crust, being 40 times more common than silver and 500 times more common than gold. It can be found almost everywhere in rock, soil, rivers, and oceans. The challenge for commercial uranium extraction is to find those areas where the concentrations are adequate to form an economically viable deposit. The primary use for uranium obtained from mining is in fuel for nuclear reactors.
Svanbergite is a colorless, yellow or reddish mineral with the chemical formula SrAl3(PO4)(SO4)(OH)6. It has rhombohedral crystals.
Phyllic alteration is a hydrothermal alteration zone in a permeable rock that has been affected by circulation of hydrothermal fluids. It is commonly seen in copper porphyry ore deposits in calc-alkaline rocks. Phyllic alteration is characterised by the assemblage of quartz + sericite + pyrite, and occurs at high temperatures and moderately acidic conditions.
Mineral alteration refers to the various natural processes that alter a mineral's chemical composition or crystallography.
A subduction zone is a region of the earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets created by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types created by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process creates and destroys water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.
El Laco is a volcanic complex in the Antofagasta Region of Chile. It is directly south of the Cordón de Puntas Negras volcanic chain. Part of the Central Volcanic Zone of the Andes, it is a group of seven stratovolcanoes and a caldera. It is about two million years old. The main summit of the volcano is a lava dome called Pico Laco, which is variously reported to be 5,325 metres (17,470 ft) or 5,472 metres (17,953 ft) high. The edifice has been affected by glaciation, and some reports indicate that it is still fumarolically active.
Hydrothermal mineral deposits are accumulations of valuable minerals which formed from hot waters circulating in Earth's crust through fractures. They eventually create rich-metallic fluids concentrated in a selected volume of rock, which become supersaturated and then precipitate ore minerals. In some occurrences, minerals can be extracted at a profit by mining. Discovery of mineral deposits consumes considerable time and resources and only about one in every one thousand prospects explored by companies are eventually developed into a mine. A mineral deposit is any geologically significant concentration of an economically useful rock or mineral present in a specified area. The presence of a known but unexploited mineral deposit implies a lack of evidence for profitable extraction.