Zunyite | |
---|---|
General | |
Category | Sorosilicates |
Formula (repeating unit) | Al13Si5O20(OH,F)18Cl |
IMA symbol | Znu [1] |
Strunz classification | 9.BJ.55 |
Crystal system | Isometric |
Crystal class | Hextetrahedral (43m) H-M symbol: (43m) |
Space group | F43m |
Unit cell | a = 13.8654 - 13.8882 Å; Z = 4 |
Identification | |
Color | Grayish white, flesh-red; colorless in thin section |
Crystal habit | Crystalline - occurs as well-formed fine sized crystals |
Twinning | On {111}, contact and penetration |
Cleavage | Good on {111} |
Fracture | Uneven |
Tenacity | Brittle |
Mohs scale hardness | 7 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent to translucent with inclusions |
Specific gravity | 2.874(5) (meas.) 2.87 - 2.90 (calc.) |
Optical properties | Isotropic |
Refractive index | n = 1.592 - 1.600 |
Other characteristics | May fluoresce red under UV |
References | [2] [3] [4] |
Zunyite is a sorosilicate mineral, Al 13 Si 5 O 20(OH,F)18 Cl, composed of aluminium, silicon, hydrogen, chlorine, oxygen, and fluorine.
Zunyite occurs in highly aluminous shales and hydrothermally altered volcanic rocks. It occurs in association with pyrophyllite, kaolinite, alunite, diaspore, rutile, pyrite, hematite and quartz. [2]
It was discovered in 1884, and named for its discovery site, the Zuni mine in the Silverton District, San Juan County, Colorado. [3]
Petalite, also known as castorite, is a lithium aluminum tektosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones.
Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula (Ca,Na)(Mg,Fe,Al,Ti)(Si,Al)2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−
3) are arranged in a triangular planar configuration, and the manganese ions (Mn2+) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is one of the national symbols of Argentina.
Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5FeS4 that crystallizes in the orthorhombic system (pseudo-cubic).
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today.
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate (ZnCO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion. The distinct mineral smithsonite was named in 1832 by François Sulpice Beudant in honor of English chemist and mineralogist James Smithson (c. 1765–1829), who first identified the mineral in 1802.
Kieserite, or magnesium sulfate monohydrate, is a hydrous magnesium sulfate mineral with formula (MgSO4·H2O).
Erythrite, also known as red cobalt, is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula Ni
3(AsO
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Bismuthinite is a mineral consisting of bismuth sulfide (Bi2S3). It is an important ore for bismuth. The crystals are steel-grey to off-white with a metallic luster. It is soft enough to be scratched with a fingernail and rather dense.
Aluminite is a hydrous aluminium sulfate mineral with formula: Al2SO4(OH)4·7H2O. It is an earthy white to gray-white monoclinic mineral which almost never exhibits crystal form. It forms botryoidal to mammillary clay-like masses. It has a very soft Mohs hardness of 1–2 and a specific gravity of 1.66–1.82.
Taenite is a mineral found naturally on Earth mostly in iron meteorites. It is an alloy of iron and nickel, with a chemical formula of Fe,Ni and nickel proportions of 20% up to 65%.
Neptunite is a silicate mineral with the formula KNa2Li(Fe2+, Mn2+)2Ti2Si8O24. With increasing manganese it forms a series with mangan-neptunite. Watatsumiite is the variety with vanadium replacing the titanium in the formula.
Vantasselite is a rare aluminium phosphate mineral with formula: Al4(PO4)3(OH)3 •9H2O. It crystallizes in the orthorhombic system and has a white color, a hardness of 2 to 2.5, a white streak and a pearly luster.
Stibiconite is an antimony oxide mineral with formula: Sb3O6(OH). Its name originates from Greek stíbi (στίβι), 'antimony' and kónis (κόνις), 'powder', alluding to its composition and habit. It is a member of the pyrochlore super group.
Antarcticite is an uncommon calcium chloride hexahydrate mineral with formula CaCl2·6H2O. It forms colorless acicular trigonal crystals. It is hygroscopic and has a low specific gravity of 1.715.
Nambulite is a lithium bearing manganese silicate mineral with the chemical formula (Li,Na)Mn4Si5O14(OH). It is named after the mineralogist, Matsuo Nambu (born 1917) of Tohoko University, Japan, who is known for his research in manganese minerals. The mineral was first discovered in the Funakozawa Mine of northeastern Japan, a metasedimentary manganese ore.
Imogolite is an aluminium silicate clay mineral with the chemical formula Al2SiO3(OH)4. It occurs in soils formed from volcanic ash and was first described in 1962 for an occurrence in Uemura, Kumamoto prefecture, Kyushu Region, Japan. Its name originates from the Japanese word imogo, which refers to the brownish yellow soil derived from volcanic ash. It occurs together with allophane, quartz, cristobalite, gibbsite, vermiculite and limonite.
Paralaurionite is a colorless mineral consisting of a basic lead chloride PbCl(OH) that is dimorphous with laurionite. It is a member of the matlockite group. The name is derived from para-, the Greek for "near", and laurionite, because of its polymorphic relationship to it. Bright, yellow tips of thorikosite can form on paralaurionite crystals and paralaurionite may also be intergrown with mendipite.