Piypite

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Piypite
Piypite-88672.jpg
Green acicular crystals of piypite
General
Category Sulfate mineral
Formula
(repeating unit)
K2Cu2O(SO4)2
IMA symbol Piy [1]
Strunz classification 7.BC.40
Crystal system Tetragonal
Crystal class Pyramidal (4)
H-M symbol: (4)
Space group I4
Unit cell a = 13.6 Å, c = 4.95 Å; Z = 2
Identification
ColorEmerald-green, dark green, black
Crystal habit Acicular crystals elongated along [001], square cross section, commonly hollow; also as mosslike aggregates
Cleavage Perfect, parallel to elongation
Tenacity Brittle
Mohs scale hardness2.5
Luster Vitreous to greasy
Streak Yellowish green
Diaphaneity Transparent to translucent
Specific gravity 3.0 - 3.1
Optical propertiesUniaxial (+)
Refractive index nω = 1.583 nε = 1.695
Birefringence δ = 0.112
Pleochroism Distinct; O = pale green, yellowish green; E = deep green, pale yellowish green
Solubility Soluble in water, leaves residue
References [2] [3] [4] [5]

Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster. [3] [4]

It was first described in 1982 for an occurrence in the Main Fracture of the Tolbachik volcano, Kamchatka Oblast, Russia. It has also been reported from Mount Vesuvius, Italy, and in a slag deposit in the Bad Ems District in the Rhineland-Palatinate, Germany. [3] [2] Piypite occurs as a sublimate phase in a fumarole environment. Associated minerals include halite, sylvite, langbeinite, tenorite, hematite, tolbachite, dolerophanite, urusovite, aphthitalite, ponomarevite, cotunnite, chalcocyanite, sofiite, euchlorine, averievite, fedotovite, alarsite, alumoklyuchevskite, nabokoite and lammerite at the type locality in Kamchatka. On Vesuvius, it occurs with paratacamite. [3]

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References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Piypite on Mindat.org
  3. 1 2 3 4 Piypite in the Handbook ov Mineralogy
  4. 1 2 Piypite data on Webmineral
  5. Mineralienatlas