Spinning (polymers)

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Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments. [1]

Contents

Melt spinning

If the polymer is a thermoplastic then it can undergo melt spinning. The molten polymer is extruded through a spinneret composed of capillaries where the resulting filament is solidified by cooling. Nylon, olefin, polyester, saran, and sulfar are produced via this process. [1]

Extrusion spinning

Pellets or granules of the solid polymer are fed into an extruder. The pellets are compressed, heated and melted by an extrusion screw, then fed to a spinning pump and into the spinneret.

Direct spinning

The direct spinning process avoids the stage of solid polymer pellets. The polymer melt is produced from the raw materials, and then from the polymer finisher directly pumped to the spinning mill. Direct spinning is mainly applied during production of polyester fibers and filaments and is dedicated to high production capacity (>100 ton/day).

Solution spinning

If the melting point of the polymer is higher than its degradation temperature, the polymer must undergo solution spinning techniques for fiber formation. The polymer is first dissolved in a solvent, forming a spinning solution (sometimes called a "dope"). The spinning solution then undergoes dry, wet, dry-jet wet, gel, or electrospinning techniques.

Dry spinning

A spinning solution consisting of polymer and a volatile solvent is extruded through a spinneret into an evaporating chamber. A stream of hot air impinges on the jets of spinning solution emerging from the spinneret, evaporating the solvent, and solidifying the filaments. Solution blow spinning is a similar technique where polymer solution is sprayed directly onto a target to produce a nonwoven fiber mat. [2]

Wet spinning

Wet spinning is the oldest of the five processes. The polymer is dissolved in a spinning solvent where it is extruded out through a spinneret submerged in a coagulation bath composed of nonsolvents. The coagulation bath causes the polymer to precipitate in fiber form. Acrylic, rayon, aramid, modacrylic, and spandex are produced via this process. [1]

A variant of wet spinning is dry-jet wet spinning, where the spinning solution passes through an air-gap prior to being submerged into the coagulation bath. This method is used in Lyocell spinning of dissolved cellulose, and can lead to higher polymer orientation due to the higher stretchability of the spinning solution versus the precipitated fiber.

Gel spinning

Gel spinning, also known as semi-melt spinning, is used to obtain high strength or other special properties in the fibers. Instead of wet spinning, which relies on precipitation as the main mechanism for solidification, gel spinning relies on temperature-induced physical gelation as the primary method for solidification. The resulting gelled fiber is then swollen with the spinning solvent (similar to gelatin desserts) which keeps the polymer chains somewhat bound together, resisting relaxation which is prevalent in wet spinning. The high solvent retention allows for ultra-high drawing as with ultra high molecular weight polyethylene (UHMWPE) (e.g., Spectra®) to produce fibers with a high degree of orientation, which increases fiber strength. The fibers are first cooled either with air or in a liquid bath to induce gelation, then the solvent is removed through ageing in a nonsolvent, or during the drawing stage. Some high strength polyethylene and polyacrylonitrile fibers are produced via this process. [1]

Electrospinning

Electrospinning uses an electrical charge to draw very fine (typically on the micro or nano scale) fibres from a liquid - either a polymer solution or a polymer melt. Electrospinning shares characteristics of both electrospraying and conventional solution dry spinning [3] of fibers. The process does not require the use of coagulation chemistry or high temperatures to produce solid threads from solution. This makes the process particularly suited to the production of fibers using large and complex molecules. Melt electrospinning is also practiced; this method ensures that no solvent can be carried over into the final product. [4] [5]

Post-spin processes

Drawing

Finally, the fibers are drawn to increase strength and orientation. This may be done while the polymer is still solidifying or after it has completely cooled. [1]

See also

Related Research Articles

<span class="mw-page-title-main">Rayon</span> Cellulose-based semi-synthetic fiber

Rayon, also called viscose and commercialised in some countries as sabra silk or cactus silk, is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. It can be woven or knit to make textiles for clothing and other purposes.

<span class="mw-page-title-main">Cellulose acetate</span> Organic compounds which are acetate esters of cellulose

In biochemistry, cellulose acetate refers to any acetate ester of cellulose, usually cellulose diacetate. It was first prepared in 1865. A bioplastic, cellulose acetate is used as a film base in photography, as a component in some coatings, and as a frame material for eyeglasses; it is also used as a synthetic fiber in the manufacture of cigarette filters and playing cards. In photographic film, cellulose acetate film replaced nitrate film in the 1950s, being far less flammable and cheaper to produce.

<span class="mw-page-title-main">PET bottle recycling</span> Recycling of bottles made of polyethylene terephthalate

Although PET is used in several applications, as of 2022 only bottles are collected at a substantial scale. The main motivations have been either cost reduction or recycle content of retail goods. An increasing amount is recycled back into bottles, the rest goes into fibres, film, thermoformed packaging and strapping. After sorting, cleaning and grinding, 'bottle flake' is obtained, which is then processed by either:

<span class="mw-page-title-main">Electrospinning</span> Fiber production method

Electrospinning is a fiber production method that uses electrical force to draw charged threads of polymer solutions for producing nanofibers with diameters ranging from nanometers to micrometers. Electrospinning shares characteristics of both electrospraying and conventional solution dry spinning of fibers. The process does not require the use of coagulation chemistry or high temperatures to produce solid threads from solution. This makes the process particularly suited to the production of fibers using large and complex molecules. Electrospinning from molten precursors is also practiced; this method ensures that no solvent can be carried over into the final product.

<span class="mw-page-title-main">Acrylic fiber</span> Synthetic fiber made from polymer

Acrylic fibers are synthetic fibers made from a polymer (polyacrylonitrile) with an average molecular weight of ~100,000, about 1900 monomer units. For a fiber to be called "acrylic" in the US, the polymer must contain at least 85% acrylonitrile monomer. Typical comonomers are vinyl acetate or methyl acrylate. DuPont created the first acrylic fibers in 1941 and trademarked them under the name Orlon. It was first developed in the mid-1940s but was not produced in large quantities until the 1950s. Strong and warm, acrylic fiber is often used for sweaters and tracksuits and as linings for boots and gloves, as well as in furnishing fabrics and carpets. It is manufactured as a filament, then cut into short staple lengths similar to wool hairs, and spun into yarn.

Ultra-high-molecular-weight polyethylene is a subset of the thermoplastic polyethylene. Also known as high-modulus polyethylene (HMPE), it has extremely long chains, with a molecular mass usually between 3.5 and 7.5 million amu. The longer chain serves to transfer load more effectively to the polymer backbone by strengthening intermolecular interactions. This results in a very tough material, with the highest impact strength of any thermoplastic presently made.

<span class="mw-page-title-main">Alginic acid</span> Polysaccharide found in brown algae

Alginic acid, also called algin, is a naturally occurring, edible polysaccharide found in brown algae. It is hydrophilic and forms a viscous gum when hydrated. When the alginic acid binds with sodium and calcium ions, the resulting salts are known as alginates. Its colour ranges from white to yellowish-brown. It is sold in filamentous, granular, or powdered forms.

<span class="mw-page-title-main">Polyester</span> Category of polymers, in which the monomers are joined together by ester links

Polyester is a category of polymers that contain one or two ester linkages in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include naturally occurring chemicals, such as in plants and insects, as well as synthetics such as polybutyrate. Natural polyesters and a few synthetic ones are biodegradable, but most synthetic polyesters are not. Synthetic polyesters are used extensively in clothing.

<span class="mw-page-title-main">Nonwoven fabric</span> Sheet of fibers

Nonwoven fabric or non-woven fabric is a fabric-like material made from staple fibre (short) and long fibres, bonded together by chemical, mechanical, heat or solvent treatment. The term is used in the textile manufacturing industry to denote fabrics, such as felt, which are neither woven nor knitted. Some non-woven materials lack sufficient strength unless densified or reinforced by a backing. In recent years, non-wovens have become an alternative to polyurethane foam.

<span class="mw-page-title-main">Plastic extrusion</span> Melted plastic manufacturing process

Plastics extrusion is a high-volume manufacturing process in which raw plastic is melted and formed into a continuous profile. Extrusion produces items such as pipe/tubing, weatherstripping, fencing, deck railings, window frames, plastic films and sheeting, thermoplastic coatings, and wire insulation.

Olefin fiber is a synthetic fiber made from a polyolefin, such as polypropylene or polyethylene. It is used in wallpaper, carpeting, ropes, and vehicle interiors.

Biotextiles are specialized materials engineered from natural or synthetic fibers. These textiles are designed to interact with biological systems, offering properties such as biocompatibility, porosity, and mechanical strength or are designed to be environmentally friendly for typical household applications. There are several uses for biotextiles since they are a broad category. The most common uses are for medical or household use. However, this term may also refer to textiles constructed from biological waste product. These biotextiles are not typically used for industrial purposes.

<span class="mw-page-title-main">Spinneret (polymers)</span> Any structure natural or artificial used to extrude polymers into fibers

A spinneret is a device used to extrude a polymer solution or polymer melt to form fibers. Streams of viscous polymer exit via the spinneret into air or liquid leading to a phase inversion which allows the polymer to solidify. The individual polymer chains tend to align in the fiber because of viscous flow. This airstream liquid-to-fiber formation process is similar to the production process for cotton candy. The fiber production process is generally referred to as "spinning". Depending on the type of spinneret used, either solid or hollow fibers can be formed. Spinnerets are also used for electrospinning and electrospraying applications. They are sometimes called coaxial needles, or coaxial emitters.

<span class="mw-page-title-main">Twinwall plastic</span>

Twin-wall plastic, specifically twin-wall polycarbonate, is an extruded multi-wall polymer product created for applications where its strength, thermally insulative properties, and moderate cost are ideal. Polycarbonate, which is most commonly formed through the reaction of Bisphenol A and Carbonyl Chloride, is an extremely versatile material. It is significantly lighter than glass, while managing to be stronger, more flexible, and more impact resistant. Twin-wall polycarbonate is used most commonly for green houses, where it can support itself in a structurally sound configuration, limit the amount of UV light due to its nominal translucence, and can withstand the rigors of daily abuse in an outdoor environment. The stagnant air in the cellular space between sheets provides insulation, and additional cell layers can be extruded to enhance insulative properties at the cost of light transmission.

<span class="mw-page-title-main">Separator (electricity)</span>

A separator is a permeable membrane placed between a battery's anode and cathode. The main function of a separator is to keep the two electrodes apart to prevent electrical short circuits while also allowing the transport of ionic charge carriers that are needed to close the circuit during the passage of current in an electrochemical cell.

<span class="mw-page-title-main">Melt electrospinning</span>

Melt electrospinning is a processing technique to produce fibrous structures from polymer melts for applications that include tissue engineering, textiles and filtration. In general, electrospinning can be performed using either polymer melts or polymer solutions. However, melt electrospinning is distinct in that the collection of the fiber can very focused; combined with moving collectors, melt electrospinning writing is a way to perform 3D printing. Since volatile solvents are not used, there are benefits for some applications where solvent toxicity and accumulation during manufacturing are a concern.

A die in polymer processing is a metal restrictor or channel capable of providing a constant cross sectional profile to a stream of liquid polymer. This allows for continuous processing of shapes such as sheets, films, pipes, rods, and other more complex profiles. This is a continuous process, allowing for constant production, as opposed to a sequential (non-constant) process such as injection molding.

<span class="mw-page-title-main">Hollow fiber membrane</span> Class of artificial membranes containing a semi-permeable hollow fiber barrier

Hollow fiber membranes (HFMs) are a class of artificial membranes containing a semi-permeable barrier in the form of a hollow fiber. Originally developed in the 1960s for reverse osmosis applications, hollow fiber membranes have since become prevalent in water treatment, desalination, cell culture, medicine, and tissue engineering. Most commercial hollow fiber membranes are packed into cartridges which can be used for a variety of liquid and gaseous separations.

<span class="mw-page-title-main">Melt blowing</span> Micro- and nanofiber fabrication method

Melt blowing is a conventional fabrication method of micro- and nanofibers where a polymer melt is extruded through small nozzles surrounded by high speed blowing gas. The randomly deposited fibers form a nonwoven sheet product applicable for filtration, sorbents, apparels and drug delivery systems. The substantial benefits of melt blowing are simplicity, high specific productivity and solvent-free operation. Choosing an appropriate combination of polymers with optimized rheological and surface properties, scientists have been able to produce melt-blown fibers with an average diameter as small as 36 nm.

<span class="mw-page-title-main">Hydrogel fiber</span>

Hydrogel fiber is a hydrogel made into a fibrous state, where its width is significantly smaller than its length. The hydrogel's specific surface area at fibrous form is larger than that of the bulk hydrogel, and its mechanical properties also changed accordingly. As a result of these changes, hydrogel fiber has a faster matter exchange rate and can be woven into different structures.

References

  1. 1 2 3 4 5 Manufacturing: Synthetic and Cellulosic Fiber Formation Technology, archived from the original on 1998-05-26, retrieved 2008-11-19.
  2. Daristotle, John L.; Behrens, Adam M.; Sandler, Anthony D.; Kofinas, Peter (2016-12-28). "A Review of the Fundamental Principles and Applications of Solution Blow Spinning". ACS Applied Materials & Interfaces. 8 (51): 34951–34963. doi:10.1021/acsami.6b12994. ISSN   1944-8252. PMC   5673076 . PMID   27966857.
  3. Ziabicki, A. Fundamentals of fiber formation, John Wiley and Sons, London, 1976, ISBN   0-471-98220-2.
  4. Nagy,Z.K.; Balogh,A.; et al. (2012). "Solvent-free melt electrospinning for preparation of fast dissolving drug delivery system and comparison with solvent-based electrospun and melt extruded systems". Journal of Pharmaceutical Sciences. 102 (2): 508–517. doi:10.1002/jps.23374. PMID   23161110.
  5. Hutmacher DW & Dalton PD (2011) Melt Electrospinning. Chem Asian J, 6, 44-5.