Stuart W. Krasner | |
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Born | |
Occupation | Environmental Research Chemist |
Known for | Determining occurrence, formation, and control of disinfection by-products of health and regulatory concern |
Awards | A.P. Black Research Award (2007) American Water Works Association and Dr. Pankaj Parekh Research Innovation Award (2017) Water Research Foundation. |
Stuart William Krasner (born 1949), was the Principal Environmental Specialist (retired) with the Metropolitan Water District of Southern California, at the Water Quality Laboratory located in La Verne, California. In his 41 years with Metropolitan, he made revolutionary changes in the field's understanding of how disinfection by-products occur, are formed and how they can be controlled in drinking water. His research contributions include the study of emerging DBPs including those associated with chlorine, chloramines, ozone, chlorine dioxide and bromide/iodide-containing waters. [1] He made groundbreaking advances in understanding the watershed sources of pharmaceuticals and personal care products (PPCPs) [2] and wastewater impacts on drinking-water supplies. [3] For DBPs and PPCPs, he developed analytical methods and occurrence data and he provided technical expertise for the development of regulations for these drinking water contaminants. [4] In the early 1990s, Krasner developed the 3x3 matrix illustrating removal of total organic carbon from drinking water as a function of water alkalinity and initial total organic carbon concentration. [5] The matrix was revised by him and included in the USEPA Stage 1 D/DBP regulation as the enhanced coagulation requirement. [6] Every water utility in the U.S. that is subject to this regulation is required to meet total organic carbon removal requirements along with their exceptions.
He has been a key member of the toxicology and epidemiology community by providing key data for the development of improved carcinogen and non-carcinogen exposure assessments. [7] In his early career at Metropolitan he developed key advances in the control of tastes and odors in drinking water including analytical methods, [8] sensory analysis [9] and determining sources [10] and treatment of off-flavors. [11]
Stuart W. Krasner was born in 1949 in Los Angeles, California, and at the age of two, he moved with his family to Van Nuys, California where he grew up. He attended Kester Avenue Elementary School and Van Nuys High School. His father worked as an aerospace engineer at several companies in the Los Angeles area. His mother worked in the bookkeeping department for Warner Bros. Movie Studios before becoming a homemaker. His brother, Stanley, is three years younger. Stuart married Jan Patrice Barth on September 10, 1989.
He earned his Bachelor of Science in chemistry (1971) and his Master of Science in analytical chemistry (1974) from the University of California, Los Angeles.
Krasner was a teaching and research assistant during his graduate work at UCLA. He worked for the Los Angeles County Sanitation Districts for four years (1974–77) before taking a position as a chemist with the Metropolitan Water District of Southern California in 1977. From the beginning of his career at Metropolitan, Krasner worked at the water quality laboratory which is located at the F.E. Weymouth Treatment Plant in La Verne, California. He held increasingly responsible positions as Research Chemist, Senior Chemist and Senior Research Chemist until being promoted to Principal Environmental Specialist in 1997. He retired from Metropolitan in September 2018.
As Principal Environmental Specialist, Krasner was responsible for the technical direction of DBP research at Metropolitan, as well as studies on the control of other micropollutants of health, regulatory, and aesthetic significance. He was involved in the design of experimental plans for natural organic matter (NOM), DBP, and PPCP research studies, project management, and interpretation of findings. In 1989, his article on the first national survey of multiple-DBP occurrence has received over 1,000 citations by other authors. [12] Another survey of a new generation of DBPs in 2006 has been cited over 1,100 times. [13]
A few of the many externally funded projects for which he was responsible include:
He was a consultant to the drinking water community since 1983. Some of his projects included:
He made professional contributions to many institutions, including: American Water Works Association (1977 – present), AWWA Research Foundation (now Water Research Foundation, WRF) and American Chemical Society (1975 – present).
For AWWA, he has been involved in over one hundred committees, workgroups and advisory committees, which have included:
For AWWA Research Foundation (now Water Research Foundation):
For the American Chemical Society:
Krasner has been a peer-reviewer for many professional and scientific journals including Journal American Water Works Association, Environmental Science & Technology, Ozone: Science & Engineering, Water Research, Journal of Water Supply: Research and Technology – Aqua, Journal of Exposure Analysis and Environmental Epidemiology, Analytical Chemistry, Water Environment Research, The Science of the Total Environment, Chemosphere and Talanta
Sodium hypochlorite, commonly known in a dilute solution as (chlorine) bleach, is an inorganic chemical compound with the formula NaOCl, consisting of a sodium cation and a hypochlorite anion. It may also be viewed as the sodium salt of hypochlorous acid. The anhydrous compound is unstable and may decompose explosively. It can be crystallized as a pentahydrate NaOCl·5H
2O, a pale greenish-yellow solid which is not explosive and is stable if kept refrigerated.
Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for human consumption, but water purification may also be carried out for a variety of other purposes, including medical, pharmacological, chemical, and industrial applications. The history of water purification includes a wide variety of methods. The methods used include physical processes such as filtration, sedimentation, and distillation; biological processes such as slow sand filters or biologically active carbon; chemical processes such as flocculation and chlorination; and the use of electromagnetic radiation such as ultraviolet light.
Chlorine dioxide is a chemical compound with the formula ClO2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is usually handled as an aqueous solution. It is commonly used as a bleach. More recent developments have extended its applications in food processing and as a disinfectant.
Total organic carbon (TOC) is an analytical parameter representing the concentration of organic carbon in a sample. TOC determinations are made in a variety of application areas. For example, TOC may be used as a non-specific indicator of water quality, or TOC of source rock may be used as one factor in evaluating a petroleum play. For marine surface sediments average TOC content is 0.5% in the deep ocean, and 2% along the eastern margins.
Cryptosporidium, sometimes called crypto, is an apicomplexan genus of alveolates which are parasites that can cause a respiratory and gastrointestinal illness (cryptosporidiosis) that primarily involves watery diarrhea, sometimes with a persistent cough.
Calcium hypochlorite is an inorganic compound with formula Ca(ClO)2. It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. This compound is relatively stable as a solid and solution and has greater available chlorine than sodium hypochlorite. "Pure" samples have 99.2% active chlorine. Given common industrial purity, an active chlorine content of 65-70% is typical. It is the main active ingredient of commercial products called bleaching powder, used for water treatment and as a bleaching agent.
Monochloramine, often called chloramine, is the chemical compound with the formula NH2Cl. Together with dichloramine (NHCl2) and nitrogen trichloride (NCl3), it is one of the three chloramines of ammonia. It is a colorless liquid at its melting point of −66 °C (−87 °F), but it is usually handled as a dilute aqueous solution, in which form it is sometimes used as a disinfectant. Chloramine is too unstable to have its boiling point measured.
Portable water purification devices are self-contained, easily transported units used to purify water from untreated sources for drinking purposes. Their main function is to eliminate pathogens, and often also of suspended solids and some unpalatable or toxic compounds.
Haloacetic acids are carboxylic acids in which a halogen atom takes the place of a hydrogen atom in acetic acid. Thus, in a monohaloacetic acid, a single halogen would replace a hydrogen atom. For example, chloroacetic acid would have the structural formula CH2ClCO2H. In the same manner, in dichloroacetic acid two chlorine atoms would take the place of two hydrogen atoms (CHCl2CO2H). The inductive effect caused by the electronegative halogens often result in the higher acidity of these compounds by stabilising the negative charge of the conjugate base.
Swimming pool sanitation is the process of ensuring healthy conditions in swimming pools. Proper sanitation is needed to maintain the visual clarity of water and to prevent the transmission of infectious waterborne diseases.
Iodoacetic acid is a derivative of acetic acid. It is a toxic compound, because, like many alkyl halides, it is an alkylating agent.
Bleach is the generic name for any chemical product that is used industrially or domestically to remove colour (whitening) from fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".
Disinfection by-products (DBPs) are organic and inorganic compounds resulting from chemical reactions between organic and inorganic substances such as contaminates and chemical treatment disinfection agents, respectively, in water during water disinfection processes.
Arthur Thomas Palin was a British chemist and bacteriologist. As well as inventing the DPD method of detecting chlorine in water and working as an official advisor to the American Water Works Association (AWWA), Palin was responsible for what the Manual of British Water Engineering Practice records as one of the key historical developments, when breakpoint chlorination was first used in England in the city of Coventry in 1943.
John Laing Leal was an American physician and water treatment expert who, in 1908, was responsible for conceiving and implementing the first disinfection of a U.S. drinking water supply using chlorine. He was one of the principal expert witnesses at two trials which examined the quality of the water supply in Jersey City, New Jersey, and which evaluated the safety and utility of chlorine for production of "pure and wholesome" drinking water. The second trial verdict approved the use of chlorine to disinfect drinking water which led to an explosion of its use in water supplies across the U.S.
George Chandler Whipple was an American civil engineer and an expert in the field of sanitary microbiology. His career extended from 1889 to 1924 and he is best known as a co-founder of the Harvard School of Public Health. Whipple published some of the most important books in the early history of public health and applied microbiology.
Michael John McGuire is an American environmental engineer and writer whose career has focused on drinking water quality improvement. He has been recognized for his expertise in the control of trace organic and inorganic contaminants and microbial pathogens in water. He is also known for his work in the identification, control and treatment of taste and odor problems in drinking water. He has published numerous articles in professional journals and he has been the co-editor of five books and compilations of articles. He published a book that documented the first continuous disinfection of a drinking water supply in the U.S. With Marie S. Pearthree, he wrote a book on the corrosive water debacle in Tucson, Arizona in 1992–94. He has been active in the American Water Works Association, and he has served as a volunteer and officer in that organization. In 2009, he was elected to the National Academy of Engineering.
Water chlorination is the process of adding chlorine or chlorine compounds such as sodium hypochlorite to water. This method is used to kill bacteria, viruses and other microbes in water. In particular, chlorination is used to prevent the spread of waterborne diseases such as cholera, dysentery, and typhoid.
Respiratory risks of indoor swimming pools can include coughing, wheezing, aggravated asthma, and airway hyper-responsiveness. The chemicals used for pool water disinfection can react with organic compounds in the water to create disinfection by-products or DBPs. Exposure to these DBPs are the potential cause for respiratory symptoms in swimmers. Multiple studies have shown the potential correlation between chronic exposure to DBPs and respiratory symptoms among competitive swimmers but more research is needed on the effects of these DBPs on recreational swimmers. The studies on recreational swimmers that have been done show a decreased risk for respiratory symptoms due to a decreased exposure to DBPs. Some studies have been done on the vulnerability of younger children and DBP exposure. Studies done on the vulnerability of younger children demonstrate that immature lungs are more likely to absorb more of these DBPs.
Chlorine-releasing compounds, also known as chlorine base compounds, is jargon to describe certain chlorine-containing substances that are used as disinfectants and bleaches. They include the following chemicals: sodium hypochlorite, chloramine, halazone, and sodium dichloroisocyanurate. They are widely used to disinfect water and medical equipment, and surface areas as well as bleaching materials such as cloth. The presence of organic matter can make them less effective as disinfectants. They come as a liquid solution, or as a powder that is mixed with water before use.