Sulfur oxoacid

Last updated

Sulfur oxoacids are chemical compounds that contain sulfur, oxygen, and hydrogen. The best known and most important industrially used is sulfuric acid. Sulfur has several oxoacids; however, some of these are known only from their salts (these are shown in italics in the table below). The acids that have been characterised contain a variety of structural features, for example:

Contents

AcidFormulaFormal oxidation number StructureRelated anionsNotes
Sulfuric acid H2SO4+6 Sulfuric acid.svg Sulfate, SO2−
4
and hydrogen sulfate commonly known as bisulfate, HSO
4
Best known and industrially significant.
Polysulfuric acids including disulfuric acid (pyrosulfuric acid)H2SO4·nSO3+6 Dischwefelsaure - Disulfuric acid.svg Disulfate (commonly known as pyrosulfate), S
2
O2−
7
and trisulfate, S
3
O2−
10
Pure disulfuric acid melts at 36 °C. Present in fuming sulfuric acid, oleum. Examples known for n = 1 and n = 2.
Peroxymonosulfuric acid H2SO5+6 Caro Acid struct.svg Peroxomonosulfate, OOSO2−
3
"Caro's acid", a solid melting at 45 °C
Peroxydisulfuric acid H2S2O8+6 Peroxodischwefelsaure.svg Peroxydisulfate, O
3
SOOSO2−
3
"Marshall's acid", a solid melting at 65 °C.
Dithionic acid H2S2O6+5 Dithionsaure.svg Dithionate, O
3
SSO2−
3
Not isolated in pure form, only concentrated solutions have been prepared
Thiosulfuric acid H2S2O30 (for the terminal sulfur), +4 (for the central atom) Thioschwefelsaure.svg Thiosulfate, S
2
O2−
3

Hydrogenthiosulfate HS
2
O
3
(ammonium salt prepared in anhydrous methanol at −80 °C [1] )
Aqueous solutions decompose.
Disulfurous acid or pyrosulfurous acidH2S2O5+5 (of the sulfur atom bonded to 3 oxygen atoms), +3 (of other sulfur atom) Dischweflige Saure.svg Disulfite commonly known as metabisulfite, S
2
O2−
5
Not known.
Sulfurous acid H2SO3+4 Sulfurous-acid-2D-pyramidal.png Bisulfite, HSO
3
and sulfite, SO2−
3
Not known.
Dithionous acid H2S2O4+3 Dithionous acid.svg Dithionite, O
2
SSO2−
2
Not known.
Sulfoxylic acid H2SO2+2 Sulfoxylsaure.svg Sulfoxylate, SO2−
2
Free acid not known
Polythionic acid H2SxO60 (for the bridging S atoms), +5 (for the terminal central S atoms) Polythionic acid 2-D structure.png Polythionates, O
3
S(S
x−2
)SO2−
3
. Example trithionate, tetrathionate, pentathionate, hexathionate, heptathionate, octathionate, nonathionate, decathionate, undecathionate, dodecathionate, tridecathionate, and tetradecathionate.
Examples known with x = 3, 4, 5, 6, 7, 8, 10, 12, 14.
Thiosulfurous acid H2S2O2−1 (for the exterior sulfur atom ), +3 (for the central atom) Thioschweflige Saure.svg Thiosulfites Not known
Dihydroxydisulfane H2S2O2+1 Dihydroxydisulfane.svg Acid known

See also

Related Research Articles

<span class="mw-page-title-main">Acid</span> Chemical compound giving a proton or accepting an electron pair

An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen ion, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid.

<span class="mw-page-title-main">Chalcogen</span> Group of chemical elements

The chalcogens are the chemical elements in group 16 of the periodic table. This group is also known as the oxygen family. Group 16 consists of the elements oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and the radioactive elements polonium (Po) and livermorium (Lv). Often, oxygen is treated separately from the other chalcogens, sometimes even excluded from the scope of the term "chalcogen" altogether, due to its very different chemical behavior from sulfur, selenium, tellurium, and polonium. The word "chalcogen" is derived from a combination of the Greek word khalkόs (χαλκός) principally meaning copper, and the Latinized Greek word genēs, meaning born or produced.

<span class="mw-page-title-main">Sulfuric acid</span> Chemical compound (H₂SO₄)

Sulfuric acid or sulphuric acid, known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula H2SO4. It is a colorless, odorless, and viscous liquid that is miscible with water.

<span class="mw-page-title-main">Lipoic acid</span> Chemical compound

Lipoic acid (LA), also known as α-lipoic acid, alpha-lipoic acid (ALA) and thioctic acid, is an organosulfur compound derived from caprylic acid (octanoic acid). ALA is made in animals normally, and is essential for aerobic metabolism. It is also manufactured and is available as a dietary supplement in some countries where it is marketed as an antioxidant, and is available as a pharmaceutical drug in other countries. Lipoate is the conjugate base of lipoic acid, and the most prevalent form of LA under physiological conditions. Only the (R)-(+)-enantiomer (RLA) exists in nature and is essential for aerobic metabolism because RLA is an essential cofactor of many enzyme complexes.

<span class="mw-page-title-main">Lead(II) sulfate</span> Chemical compound

Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as fast white, milk white, sulfuric acid lead salt or anglesite.

<span class="mw-page-title-main">Sulfate-reducing microorganism</span> Microorganisms that "breathe" sulfates

Sulfate-reducing microorganisms (SRM) or sulfate-reducing prokaryotes (SRP) are a group composed of sulfate-reducing bacteria (SRB) and sulfate-reducing archaea (SRA), both of which can perform anaerobic respiration utilizing sulfate (SO2−
4
) as terminal electron acceptor, reducing it to hydrogen sulfide (H2S). Therefore, these sulfidogenic microorganisms "breathe" sulfate rather than molecular oxygen (O2), which is the terminal electron acceptor reduced to water (H2O) in aerobic respiration.

<span class="mw-page-title-main">Chlorine oxide</span> Index of chemical compounds with the same name

Chlorine and oxygen can bond in many ways:

Organosulfur chemistry is the study of the properties and synthesis of organosulfur compounds, which are organic compounds that contain sulfur. They are often associated with foul odors, but many of the sweetest compounds known are organosulfur derivatives, e.g., saccharin. Nature is abound with organosulfur compounds—sulfur is vital for life. Of the 20 common amino acids, two are organosulfur compounds, and the antibiotics penicillin and sulfa drugs both contain sulfur. While sulfur-containing antibiotics save many lives, sulfur mustard is a deadly chemical warfare agent. Fossil fuels, coal, petroleum, and natural gas, which are derived from ancient organisms, necessarily contain organosulfur compounds, the removal of which is a major focus of oil refineries.

<span class="mw-page-title-main">Disulfuric acid</span> Chemical compound

Disulfuric acid (alternative spelling disulphuric acid) or pyrosulfuric acid (alternative spelling pyrosulphuric acid), also named oleum, is a sulfur oxoacid. It is a major constituent of fuming sulfuric acid, oleum, and this is how most chemists encounter it. As confirmed by X-ray crystallography, the molecule consists of a pair of SO2(OH) groups joined by an oxide.

<span class="mw-page-title-main">Phosphorus pentoxide</span> Chemical compound

Phosphorus pentoxide is a chemical compound with molecular formula P4O10 (with its common name derived from its empirical formula, P2O5). This white crystalline solid is the anhydride of phosphoric acid. It is a powerful desiccant and dehydrating agent.

Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.

In chemistry, phosphorus oxoacid is a generic name for any acid whose molecule consists of atoms of phosphorus, oxygen, and hydrogen. There is a potentially infinite number of such compounds. Some of them are unstable and have not been isolated, but the derived anions and organic groups are present in stable salts and esters. The most important ones—in biology, geology, industry, and chemical research—are the phosphoric acids, whose esters and salts are the phosphates.

Permanganic acid (or manganic(VII) acid) is the inorganic compound with the formula HMnO4. This strong oxoacid has been isolated as its dihydrate. It is the conjugate acid of permanganate salts. It is the subject of few publications and its characterization as well as its uses are very limited.

<span class="mw-page-title-main">Bromic acid</span> Chemical compound

Bromic acid, also known as hydrogen bromate, is an oxoacid with the molecular formula HBrO3. It only exists in aqueous solution. It is a colorless solution that turns yellow at room temperature as it decomposes to bromine. Bromic acid and bromates are powerful oxidizing agents and are common ingredients in Belousov–Zhabotinsky reactions. Belousov-Zhabotinsky reactions are a classic example of non-equilibrium thermodynamics.

An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H+ cation and the anion of the acid.

Microbial metabolism is the means by which a microbe obtains the energy and nutrients it needs to live and reproduce. Microbes use many different types of metabolic strategies and species can often be differentiated from each other based on metabolic characteristics. The specific metabolic properties of a microbe are the major factors in determining that microbe's ecological niche, and often allow for that microbe to be useful in industrial processes or responsible for biogeochemical cycles.

<span class="mw-page-title-main">Disulfurous acid</span> Chemical compound

Disulfurous acid or pyrosulfurous acid is an oxoacid of sulfur with the formula H2S2O5. The salts of disulfurous acid are called disulfites or metabisulfites. Disulfurous acid is, like sulfurous acid (H2SO3), a phantom acid, which does not exist in the free state. In contrast to disulfate (S
2
O2−
7
), disulfite has two directly connected sulfur atoms. The oxidation state of the sulfur atom bonded to three oxygen atoms is +5 while that of the other is +3.

<span class="mw-page-title-main">Polythionic acid</span>

Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula Sn(SO3H)2 (n > 2). Trithionic acid (H2S3O6), tetrathionic acid (H2S4O6) are simple examples. They are the conjugate acids of polythionates. The compounds of n < 80 are expected to exist, and those of n < 20 have already been synthesized. Dithionic acid (H2S2O6) does not belong to the polythionic acids due to strongly different properties.

<span class="mw-page-title-main">Selenenic acid</span> Class of chemical compounds

A selenenic acid is an organoselenium compound and an oxoacid with the general formula RSeOH, where R ≠ H. It is the first member of the family of organoselenium oxoacids, which also include seleninic acids and selenonic acids, which are RSeO2H and RSeO3H, respectively. Selenenic acids derived from selenoenzymes are thought to be responsible for the antioxidant activity of these enzymes. This functional group is sometimes called SeO-selenoperoxol.

<span class="mw-page-title-main">Sulfoxylic acid</span> Chemical compound

Sulfoxylic acid (H2SO2) (also known as hyposulfurous acid or sulfur dihydroxide) is an unstable oxoacid of sulfur in an intermediate oxidation state between hydrogen sulfide and dithionous acid. It consists of two hydroxy groups attached to a sulfur atom. Sulfoxylic acid contains sulfur in an oxidation state of +2. Sulfur monoxide (SO) can be considered as a theoretical anhydride for sulfoxylic acid, but it is not actually known to react with water.

References

  1. Raman spectroscopic discovery of the hydrogenthiosulphate anion, HSSO
    3
    , in solid NH4HS2O3
    Steudel Rr.; Prenzel A Zeitschrift für Naturforschung 1989,44, 12, 1499-1502