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Molecular diffusion, often simply called diffusion, is the thermal motion of all particles at temperatures above absolute zero. The rate of this movement is a function of temperature, viscosity of the fluid and the size (mass) of the particles. Diffusion explains the net flux of molecules from a region of higher concentration to one of lower concentration. Once the concentrations are equal the molecules continue to move, but since there is no concentration gradient the process of molecular diffusion has ceased and is instead governed by the process of self-diffusion, originating from the random motion of the molecules. The result of diffusion is a gradual mixing of material such that the distribution of molecules is uniform. Since the molecules are still in motion, but an equilibrium has been established, the result of molecular diffusion is called a "dynamic equilibrium". In a phase with uniform temperature, absent external net forces acting on the particles, the diffusion process will eventually result in complete mixing.
Fick's laws of diffusion describe diffusion and were derived by Adolf Fick in 1855. They can be used to solve for the diffusion coefficient, D. Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation.
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology.
The F region of the ionosphere is home to the F layer of ionization, also called the Appleton–Barnett layer, after the English physicist Edward Appleton and New Zealand physicist and meteorologist Miles Barnett. As with other ionospheric sectors, 'layer' implies a concentration of plasma, while 'region' is the volume that contains the said layer. The F region contains ionized gases at a height of around 150–800 km above sea level, placing it in the Earth's thermosphere, a hot region in the upper atmosphere, and also in the heterosphere, where chemical composition varies with height. Generally speaking, the F region has the highest concentration of free electrons and ions anywhere in the atmosphere. It may be thought of as comprising two layers, the F1 and F2 layers.
The stratosphere is the second layer of the atmosphere of the Earth, located above the troposphere and below the mesosphere. The stratosphere is an atmospheric layer composed of stratified temperature layers, with the warm layers of air high in the sky and the cool layers of air in the low sky, close to the planetary surface of the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer. The temperature inversion is in contrast to the troposphere, near the Earth's surface, where temperature decreases with altitude.
The mesosphere is the third layer of the atmosphere, directly above the stratosphere and directly below the thermosphere. In the mesosphere, temperature decreases as altitude increases. This characteristic is used to define its limits: it begins at the top of the stratosphere, and ends at the mesopause, which is the coldest part of Earth's atmosphere, with temperatures below −143 °C. The exact upper and lower boundaries of the mesosphere vary with latitude and with season, but the lower boundary is usually located at altitudes from 50 to 65 km above sea level, and the upper boundary is usually from 85 to 100 km.
The thermosphere is the layer in the Earth's atmosphere directly above the mesosphere and below the exosphere. Within this layer of the atmosphere, ultraviolet radiation causes photoionization/photodissociation of molecules, creating ions; the thermosphere thus constitutes the larger part of the ionosphere. Taking its name from the Greek θερμός meaning heat, the thermosphere begins at about 80 km (50 mi) above sea level. At these high altitudes, the residual atmospheric gases sort into strata according to molecular mass. Thermospheric temperatures increase with altitude due to absorption of highly energetic solar radiation. Temperatures are highly dependent on solar activity, and can rise to 2,000 °C (3,630 °F) or more. Radiation causes the atmospheric particles in this layer to become electrically charged, enabling radio waves to be refracted and thus be received beyond the horizon. In the exosphere, beginning at about 600 km (375 mi) above sea level, the atmosphere turns into space, although, by the judging criteria set for the definition of the Kármán line (100 km), most of the thermosphere is part of space. The border between the thermosphere and exosphere is known as the thermopause.
The atmosphere of Earth or air is the layer of gases retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for liquid water to exist on the Earth's surface, absorbing ultraviolet solar radiation, warming the surface through heat retention, and reducing temperature extremes between day and night.
Atmospheric chemistry is a branch of atmospheric science in which the chemistry of the Earth's atmosphere and that of other planets is studied. It is a multidisciplinary approach of research and draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology and other disciplines. Research is increasingly connected with other areas of study such as climatology.
The Kármán line is an attempt to define a boundary between Earth's atmosphere and outer space, and offers a specific definition set by the Fédération aéronautique internationale (FAI), an international record-keeping body for aeronautics. Defining the edge of space is important for legal and regulatory purposes since aircraft and spacecraft fall under different jurisdictions and are subject to different treaties. International law does not define the edge of space, or the limit of national airspace.
The heterosphere is the layer of an atmosphere where the gases are separated out by molecular diffusion with increasing altitude such that lighter species become more abundant relative to heavier species. The heavier molecules and atoms tend to be present in the lower layers of the heterosphere while the lighter ones are present higher up. The exact boundaries between the different molecules vary according to temperature and solar activity. The heterosphere extends from the turbopause to the edge of a planet's atmosphere and lies directly above the homosphere.
The following outline is provided as an overview of and topical guide to Earth science:
The atmosphere of Mars is the layer of gases surrounding Mars. It is primarily composed of carbon dioxide (95%), molecular nitrogen (2.8%), and argon (2%). It also contains trace levels of water vapor, oxygen, carbon monoxide, hydrogen, and noble gases. The atmosphere of Mars is much thinner than Earth's. The average surface pressure is only about 610 pascals (0.088 psi) which is less than 1% of the Earth's value. The currently thin Martian atmosphere prohibits the existence of liquid water on the surface of Mars, but many studies suggest that the Martian atmosphere was much thicker in the past. The higher density during spring and fall is reduced by 25% during the winter when carbon dioxide partly freezes at the pole caps. The highest atmospheric density on Mars is equal to the density found 35 km (22 mi) above the Earth's surface and is ≈0.020 kg/m3. The atmosphere of Mars has been losing mass to space since the planet's core slowed down, and the leakage of gases still continues today.
The homosphere is the layer of an atmosphere where the bulk gases are homogeneously mixed due to turbulent mixing or eddy diffusion. The bulk composition of the air is mostly uniform so the concentrations of molecules are the same throughout the homosphere. The top of the homosphere is called the homopause, also known as the turbopause. Above the homopause is the heterosphere, where diffusion is faster than mixing, and heavy gases decrease in density with altitude more rapidly than lighter gases.
The atmosphere of Uranus is composed primarily of hydrogen and helium. At depth it is significantly enriched in volatiles such as water, ammonia and methane. The opposite is true for the upper atmosphere, which contains very few gases heavier than hydrogen and helium due to its low temperature. Uranus's atmosphere is the coldest of all the planets, with its temperature reaching as low as 49 K.
Diffusion is the net movement of anything generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical potential. It is possible to diffuse "uphill" from a region of lower concentration to a region of higher concentration, like in spinodal decomposition.
The atmosphere of Jupiter is the largest planetary atmosphere in the Solar System. It is mostly made of molecular hydrogen and helium in roughly solar proportions; other chemical compounds are present only in small amounts and include methane, ammonia, hydrogen sulfide, and water. Although water is thought to reside deep in the atmosphere, its directly measured concentration is very low. The nitrogen, sulfur, and noble gas abundances in Jupiter's atmosphere exceed solar values by a factor of about three.
Equimolar counterdiffusion is an instance of molecular diffusion in a binary mixture, and occurs when equal numbers of molecules of the two substances are moving in opposite directions.
Microwave Radiometer (MWR) is an instrument on the Juno orbiter sent to planet Jupiter. MWR is a multi-wavelength microwave radiometer for making observations of Jupiter's deep atmosphere. MWR can observe radiation from 1.37 to 50 cm in wavelength, from 600 MHz to 22 GHz in frequencies. This supports its goal of observing the previously unseen atmospheric features and chemical abundances hundreds of miles/km into Jupiter's atmosphere. MWR is designed to detect six different frequencies in that range using separate antennas.
Diffusion-limited escape occurs when the rate of atmospheric escape to space is limited by the upward diffusion of escaping gases through the upper atmosphere, and not by escape mechanisms at the top of the atmosphere. The escape of any atmospheric gas can be diffusion-limited, but only diffusion-limited escape of hydrogen has been observed in our solar system, on Earth, Mars, Venus and Titan. Diffusion-limited hydrogen escape was likely important for the rise of oxygen in Earth's atmosphere and can be used to estimate the oxygen and hydrogen content of Earth's prebiotic atmosphere.
References
- "The Atmosphere". web.haystack.mit.edu. Archived from the original on 8 November 2005.
- Specific
- ↑ Atreya, Sushil K. (1986), "Vertical Mixing", in Atreya, Sushil K. (ed.), Atmospheres and Ionospheres of the Outer Planets and Their Satellites, Physics and Chemistry in Space, vol. 15, Springer Berlin Heidelberg, pp. 66–79, doi:10.1007/978-3-642-71394-1_4, ISBN 9783642713941
- ↑ "Turbopause - AMS Glossary". glossary.ametsoc.org. Retrieved 2019-06-01.
- ↑ Catling, David; Kasting, James (2017). Atmospheric Evolution on Inhabited and Lifeless Worlds. Cambridge University Press. p. 6. ISBN 9780521844123.
- ↑ Varnoteaux, Philippe. "Il y a 60 ans, Véronique AGI emmenait la France dans l'espace – PARTIE 1 : La campagne de tirs" (in French). Retrieved 2019-08-31.
