Solubility chart

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A solubility chart is a chart describing whether the ionic compounds formed from different combinations of cations and anions dissolve in or precipitate from solution.

Contents

Chart

The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate. For compounds with multiple hydrates, the solubility of the most soluble hydrate is shown.

Some compounds, such as nickel oxalate, will not precipitate immediately even though they are insoluble, requiring a few minutes to precipitate out. [1]

Key
Shighly soluble or miscible≥20 g/L
sSslightly soluble0.1~20 g/L
Irelatively insoluble<0.1 g/L
Rreacts with or in water—
 ?unavailable—
Ions names and symbols Halogens Chalcogens Pnictogens Crystallogens
Fluoride
F−		 Chloride
Cl−		 Bromide
Br−		 Iodide
I−		 Perchlorate
ClO−
4		 Oxide
O2−		 Hydroxide
OH−		 Sulfide
S2−		 Sulfate
SO2−
4		 Nitrate
NO−
3 [lower-alpha 1] 		Phosphate
PO3−
4		 Carbonate
CO2−
3 [lower-alpha 1] 		Cyanide
CN−		 Thiocyanate
SCN−		 Acetate
C
2H
3O−
2		 Oxalate
C
2O2−
4
Hydrogen H+ S S S S S S S sS S S S S S S S S
Ammonium NH+
4 [lower-alpha 1] 		S S S S S S [lower-alpha 2] S R S S S S S S S S
Lithium Li+ sS S S S S R S R S S sS sS S S S S
Sodium Na+ S S S S S R S R S S S S S S S S
Potassium K+ S S S S sS R S R S S S S S S S S
Rubidium Rb+ S S S S sS R S R S S S S S S [3] S S
Caesium Cs+ S S S S sS R S R S S S S S S S S
Beryllium Be2+ S S S R S [4] I I R S S I sS R S [5] S S
Magnesium Mg2+ sS S S S S R I R S S I sS R S [6] S sS
Calcium Ca2+ I S S S S R sS R sS S I I R S [7] S sS
Strontium Sr2+ sS S S S S R sS R sS S sS I S S [8] S I
Barium Ba2+ sS S S S S R S R I S I [9] sS S S S I
Aluminium Al3+ sS S S S [lower-alpha 3] S [10] I I R S S I R R S [11] S I
Gallium Ga3+ I S S R S [10] I I R sS S I R R S [12] S  ?
Manganese(II) Mn2+ sS S S S S [13] I I I S S I I S S [14] S I
Iron(II) Fe2+ sS S S S S I I I S S I I S S S sS
Cobalt(II) Co2+ sS S S S S [15] I I I S S I I I S S I
Nickel(II) Ni2+ S S S S S I I I S S I I I S S I [1]
Copper(II) Cu2+ sS S S  ? S I I I S S I I [lower-alpha 4] I I S I
Zinc Zn2+ sS S S S S [16] I I I S S I I I S [17] S I
Cadmium Cd2+ S S S S S [18] I I I S S I I sS sS [17] S I
Mercury(II) Hg2+ R S sS I S [19] I I I R S I I S sS S sS [20]
Vanadium(III) V3+ I S S S S [21] I I I sS S I  ? ? S  ? ?
Chromium(III) Cr3+ sS S S S S I I I S S I I S S S  ?
Iron(III) Fe3+ S [lower-alpha 5] S S R S [22] I I I S S sS R [23] S S [24] S [25] [lower-alpha 6] sS
Gold(III) Au3+ R S sS ?  ? I I I  ? ? I I S  ? sS  ?
Tin(II) Sn2+ S S S S S [26] I I I S  ? I I  ? I [27] R sS
Lead(II) Pb2+ sS sS sS sS S I sS I I S I I sS sS S I
Silver Ag+ S I I I S I I I sS S I I I I sS I
Mercury(I) Hg2+
2		 R I I I S [28] I  ? ? sS S [lower-alpha 7]  ? I I  ? S [29] [lower-alpha 7]  ?
  Fluoride
F−		 Chloride
Cl−		 Bromide
Br−		 Iodide
I−		 Perchlorate
ClO−
4		 Oxide
O2−		 Hydroxide
OH−		 Sulfide
S2−		 Sulfate
SO2−
4		 Nitrate
NO−
3 [lower-alpha 1] 		Phosphate
PO3−
4		 Carbonate
CO2−
3 [lower-alpha 1] 		Cyanide
CN−		 Thiocyanate
SCN−		 Acetate
C
2H
3O−
2		 Oxalate
C
2O2−
4

See also

Notes

  1. 1 2 3 4 5 Compounds that include ammonium (NH+
    4    ), chlorate (ClO−
    3    ), or nitrate (NO−
    3    ) are soluble without exceptions. Compounds that include carbonate (CO2−
    3    ) are insoluble, unless the compound includes group 1 elements or ammonium. [2]
  2. ↑ "Ammonium oxide" does not exist. However, its theoretical molecular formula (NH+
    4    )2O2− represents that of aqueous ammonia.
  3. ↑ Partial electrolysis.
  4. ↑ The commonly encountered basic copper carbonate (CuCO3(OH)2) is insoluble in water. True copper(II) carbonate (CuCO3) is rare and reacts with water to form basic copper carbonate.
  5. ↑ Anhydrous FeF3 is slightly soluble in water; FeF3·3H2O is much more soluble in water.
  6. ↑ The commonly encountered basic iron(III) acetate ([Fe3O(OAc)6(H2O)3]OAc) is insoluble in water. True iron(III) acetate (Fe(OAc)3) is rare and is soluble in water.
  7. 1 2 Slowly decomposes in water.

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References

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  2. ↑ "Solubility Table". intro.chem.okstate.edu.
  3. ↑ M. J. Joyce; F. Ninio (1989). "Raman Spectrum of Rubidium Thiocyanate at 37 K and Room Temperature". Australian Journal of Physics. 42 (4): 389–400. doi: 10.1071/PH890389 .
  4. ↑ Birgitta Carell; Åke Olin (1961). "Studies on the Hydrolysis of Metal Ions. 37. Application of the Self-Medium Method to the Hydrolysis of Beryllium Perchlorate". Acta Chemica Scandinavica. 15: 1875–1884. doi: 10.3891/acta.chem.scand.15-1875 .
  5. ↑ W. J. Biermann; R. H. McCorkell (1967). "Liquid–liquid extraction of beryllium thiocyanate". Canadian Journal of Chemistry. 45 (22): 2846–2849. doi: 10.1139/v67-459 .
  6. ↑ K. Mereiter; A. Preisinger (1982). "Structure of magnesium isothiocyanate tetrahydrate". Acta Crystallographica B. 38: 1263–1265. doi:10.1107/S0567740882005433.
  7. ↑ Claudia Wickleder; Patrick Larsen (2002). "Ca(SCN)2 and Ca(SCN)2 · 2 H2O: Crystal Structure, Thermal Behavior and Vibrational Spectroscopy". Zeitschrift für Naturforschung B. 57 (12): 1419–1426. doi:10.1515/znb-2002-1213.
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  10. 1 2 Laurence S. Foster (1939). "(I) The Reaction of Gallium with Perchloric Acid and (II) the Preparation and Properties of Gallium Perchlorate Hydrates". Journal of the American Chemical Society. 61 (11): 3122–3124. doi:10.1021/ja01266a041.
  11. ↑ S.J. Patel (1971). "Aluminium(III) isothiocyanate and its addition compounds". Journal of Inorganic and Nuclear Chemistry. 33 (1): 17–22. doi:10.1016/0022-1902(71)80004-0.
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  13. ↑ "44318 Manganese(II) perchlorate hexahydrate, 99.995% (metals basis)". Alfa Aesar. Alfa Aesar. Retrieved 16 September 2022.
  14. ↑ B. Beagley; C.A. McAuliffe; A.G. Mackie; R.G. Pritchard (1984). "Preparation and crystal structure of manganese(II) isothiocyanate tetrahydrate". Inorganica Chimica Acta. 89 (3): 163–166. doi:10.1016/S0020-1693(00)82345-2.
  15. ↑ E. Kamieńska-Piotrowicz (1999). "Conductometric Studies of Cobalt(II) Perchlorate in Acetonitrile-Water Solutions". Zeitschrift für Physikalische Chemie. 210 (1): 1–13. doi:10.1524/zpch.1999.210.Part_1.001. S2CID   102316324.
  16. ↑ Lili Lin; Xiaohua Liu; Xiaoming Feng (2014). "Zinc(II) Perchlorate Hexahydrate". Encyclopedia of Reagents for Organic Synthesis. John Wiley & Sons, Ltd: 1–5. doi:10.1002/047084289X.rn01657. ISBN   9780470842898.
  17. 1 2 Masaki Kosaku (1931). "THE SOLUBILITIES OF THIOCYANATE OF METALS". Bulletin of the Chemical Society of Japan. 6 (7): 163–165. doi: 10.1246/bcsj.6.163 .
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  20. ↑ "Properties of substance: mercury(II) oxalate Group of substances". Chemister. Chemister. Retrieved 13 September 2022.
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  24. ↑ Sano Hirotoshi; Akane Michiko (1973). "MÖSSBAUER SPECTROSCOPIC STUDIES ON IRON THIOCYANATE". Chemistry Letters. 2 (1): 43–46. doi:10.1246/cl.1973.43.
  25. ↑ Ram C. Paul; Ramesh C. Narula; Sham K. Vasisht (1978). "Iron(III) acetates". Transition Metal Chemistry. 3: 35–38. doi:10.1007/BF01393501. S2CID   94447648.
  26. ↑ C.G.Davies; J.D.Donaldson (1968). "Tin(II) perchlorate trihydrate". Journal of Inorganic and Nuclear Chemistry. 30 (10). Chelsea College of Science and Technology: 2635–2639. doi:10.1016/0022-1902(68)80389-6.
  27. ↑ Tewfik B. Absi; Ramesh C. Makhija; Mario Onyszchuk (1978). "Synthesis and vibrational spectra of tin(II) isothiocyanate adducts with some O- and N-donor ligands". Canadian Journal of Chemistry. 56 (15): 2039–2041. doi:10.1139/v78-333.
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