1,2-Butadiene

1,2-Butadiene

Names
Preferred IUPAC name Buta-1,2-diene
Other names Methyl allene
Identifiers
CAS Number	590-19-2
3D model (JSmol)	Interactive image
Beilstein Reference	1730808
ChEBI	CHEBI:39480
ChemSpider	11051
ECHA InfoCard	100.008.796
EC Number	209-674-2
Gmelin Reference	1144
PubChem CID	11535
UNII	2AZI943A8R
CompTox Dashboard (EPA)	DTXSID5027225
InChI InChI=1S/C4H6/c1-3-4-2/h4H,1H2,2H3 Key: QNRMTGGDHLBXQZ-UHFFFAOYSA-N
SMILES CC=C=C
Properties
Chemical formula	C4H6
Molar mass	54.092 g·mol−1
Density	0.676 at 4 °C
Melting point	−136.2 °C (−213.2 °F; 137.0 K)
Boiling point	10.9 °C (51.6 °F; 284.0 K)
Refractive index (nD)	1.4205 at 1 °C
Thermochemistry
Enthalpy of vaporization (ΔfHvap)	23.426 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards	Frostbite, flammable
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H220, H224, H411
Precautionary statements	P210, P233, P240, P241, P242, P243, P273, P280, P303+P361+P353, P370+P378, P377, P381, P391, P403, P403+P235, P410+P403, P501
Flash point	−75 °C (−103 °F; 198 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

1,2-Butadiene is the organic compound with the formula CH₂=C=CHCH₃. It is an isomer of 1,3-butadiene, a common monomer used to make synthetic rubber. It is a colorless flammable gas, one of the simplest substituted allenes. ^[1]

Production

The C4-fraction obtained by cracking and separated by distillation consists of many compounds, predominantly (75%) 1,3-butadiene, isobutene, 1-butene. 1,2-Butadiene comprises less than 1% or this mixture. ^[2] It is partially purified by extraction with N-methylpyrrolidone. US product was 4,500 - 23,000 tons in 2005. ^[1]

References

1. "Product Safety Summary 1,2-BUTADIENE". ExxonMobil. March 2016. Archived from the original on 2023-11-24.
2. J. Grub; E. Löser (2012). "Butadiene". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a04_431.pub2. ISBN   978-3-527-30673-2.