Agrochemical

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The Passaic Agricultural Chemical Works in Newark, New Jersey, 1876 Passaic Agricultural Chemical Works. 1876.jpg
The Passaic Agricultural Chemical Works in Newark, New Jersey, 1876

An agrochemical or agrichemical, a contraction of agricultural chemical, is a chemical product used in industrial agriculture. Agrichemical typically refers to biocides (pesticides including insecticides, herbicides, fungicides and nematicides) alongside synthetic fertilizers. It may also include hormones and other chemical growth agents. [1] [2] Though the application of mineral fertilizers and pesticidal chemicals has a long history, the majority of agricultural chemicals were developed from the 19th century, and their use were expanded significantly during the Green Revolution and the late 20th century. [3] Agriculture that uses these chemicals is frequently called conventional agriculture. [4]

Contents

Agrochemicals are counted among speciality chemicals. Most agrochemicals are products of the petrochemical industry, where chemicals are derivitatives of fossil fuels. [5] The production and use of agrochemicals contribute substantially to climate change, both through direct emissions during production, and through indirect emissions created from soil ecology problems created by the chemicals. [5]

Agrochemicals, especially when improperly used or released in local environments, have led to a number of public health and environmental issues. [3] Agrochemicals and their production can be significant environmental pollution. [3] Agrochemicals are responsible for significant damage to waterways through runoff, and inproperly stored agrochemicals and agrochemical wastes are responsible for spills, especially during extreme weather events. [6] [3] Following the publication of Rachel Carson's Silent Spring , increased global attention has been paid to these ecological impacts of certain classes of chemicals, both in terms of effects on ecosystems and biodiversity loss. Some farmers choose not to use agrochemicals, with sustainable agriculture approaches such as organic farming or agroecology, avoiding use of pesticides and industrial chemicals, in favor of naturally occurring chemicals. [7]

Categories

Biological action

In most of the cases, agrochemicals refer to pesticides. [8]

Application method

Application process

Agrochemicals are typically applied to seeds or the field using a variety of different methods.

Seed treatment

A seed treatment is a treatment of the seed with either chemical agents or biological or by physical methods. Usually done to provide protection to the seed and improve the establishment of healthy crops. Not to be confused with a seed coating.

In agriculture and horticulture, coating of the seed is the process of applying exogenous materials to the seed. Also referred to as seed dressing.

A seed coating is the layer of material added to the seed, which may or may not contain a "protectant" (biological or chemical pesticide) or biostimulant applied to the seed and possibly some color... By the amount of material added, it can be divided into: [9]

  • A Film coating, a layer of thin film applied to the seed typically less than 10% of the mass of the original seed.
  • Encrustment, where the applied material is typically 100%500% of the original seed mass, but the shape is still discernible.
  • Pellet, where the applied material is so thick that the seed's original shape is not discernible.

Seed coating provides the following functions:

  • For formulations with pesticides, direct application to seeds can be environmentally more friendly, as the amounts used can be very small. [10]
  • Color makes treated seed less attractive to birds, and easier to see and clean up in the case of an accidental spillage. [11]
  • A thick coating can improve handling, by hand or by machine. Thinner coatings may also help with characteristics like flowability. [9]
  • Thick coatings may accommodate additional features such as fertilizers, plant hormones, plant-beneficial microbes, and water-retaining polymers. [9] [12]
Specialist machinery is required to safely and efficiently apply the chemical to the seed. [13] A cement mixer is enough for non-hazardous coating materials. [12] The term "seed dressing" is also used to refer to the process of removing chaff, weed seeds and straw from a seed stock.

Sprayers

Folded spray boom.jpg
Partially unfolded spray boom.jpg
Fully unfolded spray boom.jpg
A field sprayer system in folded, partially unfolded and open configuration
Aerial video of a sprayer (unfolding and driving)
A sprayer is a device used to spray a liquid, where sprayers are commonly used for projection of water, weed killers, crop performance materials, pest maintenance chemicals, as well as manufacturing and production line ingredients. In agriculture, a sprayer is a piece of equipment that is used to apply herbicides, pesticides, and fertilizers on agricultural crops. Sprayers range in size from man-portable units (typically backpacks with spray guns) to trailed sprayers that are connected to a tractor, to self-propelled units similar to tractors with boom mounts of 4–30 feet (1.2–9.1 m) up to 60–151 feet (18–46 m) in length depending on engineering design for tractor and land size. [14]

Aerial application

A PZL-106 Kruk crop duster applying a fine mist Gehling PLZ106AR Kruk OTT 2013 D7N9017 009.jpg
A PZL-106 Kruk crop duster applying a fine mist
A Mil Mi-8 spreading fertilizer Bundesarchiv Bild 183-1987-0721-301, Agrarflieger, Dungen, Forstwirtschaft.jpg
A Mil Mi-8 spreading fertilizer

Aerial application, or what is informally referred to as crop dusting, [15] involves spraying crops with crop protection products from an agricultural aircraft. Planting certain types of seed are also included in aerial application. The specific spreading of fertilizer is also known as aerial topdressing in some countries. Many countries have severely limited aerial application of pesticides and other products because of environmental and public health hazards like spray drift; most notably, the European Union banned it outright with a few highly restricted exceptions in 2009, [16] effectively ending the practice in all member states.

Agricultural aircraft are highly specialized, purpose-built aircraft. Today's agricultural aircraft are often powered by turbine engines of up to 1,500 shp (1,100 kW) and can carry as much as 800 US gallons (3,000 L) of crop protection product. Helicopters are sometimes used, and some aircraft serve double duty as water bombers in areas prone to wildfires. These aircraft are referred to as SEAT, or "single engine air tankers."

Ecology

Many agrochemicals are toxic, and agrichemicals in bulk storage may pose significant environmental and/or health risks, particularly in the event of accidental spills. In many countries, use of agrichemicals is highly regulated. Government-issued permits for purchase and use of approved agrichemicals may be required. Significant penalties can result from misuse, including improper storage resulting in spillage. On farms, proper storage facilities and labeling, emergency clean-up equipment and procedures, and safety equipment and procedures for handling, application and disposal are often subject to mandatory standards and regulations. Usually, the regulations are carried out through the registration process.

For instance, bovine somatotropin, though widely used in the United States, is not approved in Canada and some other jurisdictions as there are concerns for the health of cows using it.

Impacts of pesticides

Hazardous-pesticide.jpg
A farmworker wearing protective equipment pouring a concentrated pesticide into a sprayer tank with water.
Drainage nitrates vers HondeghemFr 2003 04 09.jpg
Drainage of fertilizers and pesticides into a stream
Pesticides being sprayed onto a recently plowed field by tractor. Aerial spraying is a main source of pesticide drift and application on loose topsoil increases the chance of runoff into waterways. Pesticides application 02.jpg
Pesticides being sprayed onto a recently plowed field by tractor. Aerial spraying is a main source of pesticide drift and application on loose topsoil increases the chance of runoff into waterways.

The environmental effects of pesticides describe the broad series of consequences of using pesticides. The unintended consequences of pesticides is one of the main drivers of the negative impact of modern industrial agriculture on the environment. Pesticides, because they are toxic chemicals meant to kill pest species, can affect non-target species, such as plants, animals and humans. Over 98% of sprayed insecticides and 95% of herbicides reach a destination other than their target species, because they are sprayed or spread across entire agricultural fields. [17] Other agrochemicals, such as fertilizers, can also have negative effects on the environment.

The negative effects of pesticides are not just in the area of application. Runoff and pesticide drift can carry pesticides into distant aquatic environments or other fields, grazing areas, human settlements and undeveloped areas. Other problems emerge from poor production, transport, storage and disposal practices. [18] Over time, repeat application of pesticides increases pest resistance, while its effects on other species can facilitate the pest's resurgence. [19] Alternatives to heavy use of pesticides, such as integrated pest management, and sustainable agriculture techniques such as polyculture mitigate these consequences, without the harmful toxic chemical application.

Environmental modelling indicates that globally over 60% of global agricultural land (~24.5 million km²) is "at risk of pesticide pollution by more than one active ingredient", and that over 30% is at "high risk" of which a third are in high-biodiversity regions. [20] [21] Each pesticide or pesticide class comes with a specific set of environmental concerns. Such undesirable effects have led many pesticides to be banned, while regulations have limited and/or reduced the use of others. The global spread of pesticide use, including the use of older/obsolete pesticides that have been banned in some jurisdictions, has increased overall. [22] [23]

History

Sumerians from 4500 years ago have said to use insecticides in the form of sulfur compounds. Additionally, the Chinese from about 3200 years ago used mercury and arsenic compounds to control the body lice. [24]

Agrochemicals were introduced to protect crops from pests and enhance crop yields. The most common agrochemicals include pesticides and fertilizers. [25] Chemical fertilizers in the 1960s were responsible for the beginning of the "Green Revolution", where using the same surface of land using intensive irrigation and mineral fertilizers such as nitrogen, phosphorus, and potassium has greatly increased food production. [26] Throughout the 1970s through 1980s, pesticide research continued into producing more selective agrochemicals. [24] Due to the adaptation of pests to these chemicals, more and new agrochemicals were being used, causing side effects in the environment.

Companies

Syngenta was the Chinese owned worldwide leader in agrochemical sales in 2013 at approximately US$10.9 billion, followed by Bayer CropScience, BASF, Dow AgroSciences, Monsanto, and then DuPont with about $3.6 billion. [27] It is still in the worldwide leading position based on sales of year 2019. Based on a statistics by statistica, In 2019, the agrochemical market worldwide was worth approximately $234.2 billion. This is expected to increase to more than $300 billion in 2025. [28]

See also

Related Research Articles

<span class="mw-page-title-main">Pesticide</span> Substance used to destroy pests

Pesticides are substances that are used to control pests. They include herbicides, insecticides, nematicides, fungicides, and many others. The most common of these are herbicides, which account for approximately 50% of all pesticide use globally. Most pesticides are used as plant protection products, which in general protect plants from weeds, fungi, or insects. In general, a pesticide is a chemical or biological agent that deters, incapacitates, kills, or otherwise discourages pests. Target pests can include insects, plant pathogens, weeds, molluscs, birds, mammals, fish, nematodes (roundworms), and microbes that destroy property, cause nuisance, or spread disease, or are disease vectors. Along with these benefits, pesticides also have drawbacks, such as potential toxicity to humans and other species.

<span class="mw-page-title-main">Herbicide</span> Type of chemical used to kill unwanted plants

Herbicides, also commonly known as weed killers, are substances used to control undesired plants, also known as weeds. Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides kill plants indiscriminately. The combined effects of herbicides, nitrogen fertilizer, and improved cultivars has increased yields of major crops by three to six times from 1900 to 2000.

<span class="mw-page-title-main">Insecticide</span> Pesticide used against insects

Insecticides are pesticides used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. The major use of insecticides is in agriculture, but they are also used in home and garden settings, industrial buildings, for vector control, and control of insect parasites of animals and humans.

<span class="mw-page-title-main">Integrated pest management</span> Approach for economic control of pests

Integrated pest management (IPM), also known as integrated pest control (IPC) that integrates both chemical and non-chemical practices for economic control of pests. The UN's Food and Agriculture Organization defines IPM as "the careful consideration of all available pest control techniques and subsequent integration of appropriate measures that discourage the development of pest populations and keep pesticides and other interventions to levels that are economically justified and reduce or minimize risks to human health and the environment. IPM emphasizes the growth of a healthy crop with the least possible disruption to agro-ecosystems and encourages natural pest control mechanisms." Entomologists and ecologists have urged the adoption of IPM pest control since the 1970s. IPM is a safer pest control framework than reliance on the use of chemical pesticides, mitigating risks such as: insecticide-induced resurgence, pesticide resistance and (especially food) crop residues.

<span class="mw-page-title-main">Agricultural wastewater treatment</span> Farm management for controlling pollution from confined animal operations and surface runoff

Agricultural wastewater treatment is a farm management agenda for controlling pollution from confined animal operations and from surface runoff that may be contaminated by chemicals in fertilizer, pesticides, animal slurry, crop residues or irrigation water. Agricultural wastewater treatment is required for continuous confined animal operations like milk and egg production. It may be performed in plants using mechanized treatment units similar to those used for industrial wastewater. Where land is available for ponds, settling basins and facultative lagoons may have lower operational costs for seasonal use conditions from breeding or harvest cycles. Animal slurries are usually treated by containment in anaerobic lagoons before disposal by spray or trickle application to grassland. Constructed wetlands are sometimes used to facilitate treatment of animal wastes.

<span class="mw-page-title-main">Aerial application</span> Dispersal of chemicals from aircraft or helicopters

Aerial application, or what is informally referred to as crop dusting, involves spraying crops with crop protection products from an agricultural aircraft. Planting certain types of seed are also included in aerial application. The specific spreading of fertilizer is also known as aerial topdressing in some countries. Many countries have severely limited aerial application of pesticides and other products because of environmental and public health hazards like spray drift; most notably, the European Union banned it outright with a few highly restricted exceptions in 2009, effectively ending the practice in all member states.

A Biopesticide is a biological substance or organism that damages, kills, or repels organisms seens as pests. Biological pest management intervention involves predatory, parasitic, or chemical relationships.

<span class="mw-page-title-main">Soil contamination</span> Pollution of land by human-made chemicals or other alteration

Soil contamination, soil pollution, or land pollution as a part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons, solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapour from the contaminants, or from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting clean ups are time-consuming and expensive tasks, and require expertise in geology, hydrology, chemistry, computer modelling, and GIS in Environmental Contamination, as well as an appreciation of the history of industrial chemistry.

<span class="mw-page-title-main">Phytotoxicity</span> Toxic effect by a compound on plant growth

Phytotoxicity describes any adverse effects on plant growth, physiology, or metabolism caused by a chemical substance, such as high levels of fertilizers, herbicides, heavy metals, or nanoparticles. General phytotoxic effects include altered plant metabolism, growth inhibition, or plant death. Changes to plant metabolism and growth are the result of disrupted physiological functioning, including inhibition of photosynthesis, water and nutrient uptake, cell division, or seed germination.

<span class="mw-page-title-main">Sprayer</span> Agricultural machine used in farms

A sprayer is a device used to spray a liquid, where sprayers are commonly used for projection of water, weed killers, crop performance materials, pest maintenance chemicals, as well as manufacturing and production line ingredients. In agriculture, a sprayer is a piece of equipment that is used to apply herbicides, pesticides, and fertilizers on agricultural crops. Sprayers range in size from man-portable units to trailed sprayers that are connected to a tractor, to self-propelled units similar to tractors with boom mounts of 4–30 feet (1.2–9.1 m) up to 60–151 feet (18–46 m) in length depending on engineering design for tractor and land size.

Neonicotinoids are a class of neuro-active insecticides chemically similar to nicotine, developed by scientists at Shell and Bayer in the 1980s.

A seed treatment is a treatment of the seed with either chemical agents or biological or by physical methods. Usually done to provide protection to the seed and improve the establishment of healthy crops. Not to be confused with a seed coating.

Intensive crop farming is a modern industrialized form of crop farming. Intensive crop farming's methods include innovation in agricultural machinery, farming methods, genetic engineering technology, techniques for achieving economies of scale in production, the creation of new markets for consumption, patent protection of genetic information, and global trade. These methods are widespread in developed nations.

<span class="mw-page-title-main">Pesticide application</span> Delivery of pesticides

Pesticide application is the practical way in which pesticides are delivered to their biological targets. Public concern about the use of pesticides has highlighted the need to make this process as efficient as possible, in order to minimise their release into the environment and human exposure. The practice of pest management by the rational application of pesticides is supremely multi-disciplinary, combining many aspects of biology and chemistry with: agronomy, engineering, meteorology, socio-economics and public health, together with newer disciplines such as biotechnology and information science.

<span class="mw-page-title-main">Pesticide drift</span> Diffusion of pesticides into the environment

Pesticide drift, also known as spray drift refers to the unintentional diffusion of pesticides toward nontarget species. It is one of the most negative effects of pesticide application. Drift can damage human health, environment, and crops. Together with runoff and leaching, drift is a mechanism for agricultural pollution. Some drift results from contamination of sprayer tanks.

<span class="mw-page-title-main">Environmental impact of pesticides</span> Environmental effect

The environmental effects of pesticides describe the broad series of consequences of using pesticides. The unintended consequences of pesticides is one of the main drivers of the negative impact of modern industrial agriculture on the environment. Pesticides, because they are toxic chemicals meant to kill pest species, can affect non-target species, such as plants, animals and humans. Over 98% of sprayed insecticides and 95% of herbicides reach a destination other than their target species, because they are sprayed or spread across entire agricultural fields. Other agrochemicals, such as fertilizers, can also have negative effects on the environment.

<span class="mw-page-title-main">Clothianidin</span> Chemical compound

Clothianidin is an insecticide developed by Takeda Chemical Industries and Bayer AG. Similar to thiamethoxam and imidacloprid, it is a neonicotinoid. Neonicotinoids are a class of insecticides that are chemically similar to nicotine, which has been used as a pesticide since the late 1700s. Clothianidin and other neonicotinoids act on the central nervous system of insects as an agonist of nAChR, the same receptor as acetylcholine, the neurotransmitter that stimulates and activating post-synaptic acetylcholine receptors but not inhibiting AChE. Clothianidin and other neonicotinoids were developed to last longer than nicotine, which is more toxic and which breaks down too quickly in the environment.

The environmental impact of agriculture is the effect that different farming practices have on the ecosystems around them, and how those effects can be traced back to those practices. The environmental impact of agriculture varies widely based on practices employed by farmers and by the scale of practice. Farming communities that try to reduce environmental impacts through modifying their practices will adopt sustainable agriculture practices. The negative impact of agriculture is an old issue that remains a concern even as experts design innovative means to reduce destruction and enhance eco-efficiency. Animal agriculture practices tend to be more environmentally destructive than agricultural practices focused on fruits, vegetables and other biomass. The emissions of ammonia from cattle waste continue to raise concerns over environmental pollution.

<span class="mw-page-title-main">Agricultural pollution</span> Type of pollution caused by agriculture

Agricultural pollution refers to biotic and abiotic byproducts of farming practices that result in contamination or degradation of the environment and surrounding ecosystems, and/or cause injury to humans and their economic interests. The pollution may come from a variety of sources, ranging from point source water pollution to more diffuse, landscape-level causes, also known as non-point source pollution and air pollution. Once in the environment these pollutants can have both direct effects in surrounding ecosystems, i.e. killing local wildlife or contaminating drinking water, and downstream effects such as dead zones caused by agricultural runoff is concentrated in large water bodies.

Early twenty-first century pesticide research has focused on developing molecules that combine low use rates and that are more selective, safer, resistance-breaking and cost-effective. Obstacles include increasing pesticide resistance and an increasingly stringent regulatory environment.

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