In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.
Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.
The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8.
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or 'record-groove' effect.
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.
Labradorite ((Ca, Na)(Al, Si)4O8) is a calcium-enriched feldspar mineral first identified in Labrador, Canada, which can display an iridescent effect (schiller).
Bytownite is a calcium rich member of the plagioclase solid solution series of feldspar minerals with composition between anorthite and labradorite. It is usually defined as having between 70 and 90%An. Like others of the series, bytownite forms grey to white triclinic crystals commonly exhibiting the typical plagioclase twinning and associated fine striations.
Anorthite is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is CaAl2Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon.
Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3O
8. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.
Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite (NaAlSi3O8) and anorthite (CaAl2Si2O8). The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30.
Aegirine is a member of the clinopyroxene group of inosilicate minerals. Aegirine is the sodium endmember of the aegirine-augite series. Aegirine has the chemical formula NaFeSi2O6 in which the iron is present as Fe3+. In the aegirine-augite series the sodium is variably replaced by calcium with iron(II) and magnesium replacing the iron(III) to balance the charge. Aluminium also substitutes for the iron(III). Acmite is a fibrous, green-colored variety.
Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.
Monzogranites are biotite granite rocks that are considered to be the final fractionation product of magma. Monzogranites are characteristically felsic (SiO2 > 73%, and FeO + MgO + TiO2 < 2.4), weakly peraluminous (Al2O3/ (CaO + Na2O + K2O) = 0.98–1.11), and contain ilmenite, sphene, apatite and zircon as accessory minerals. Although the compositional range of the monzogranites is small, it defines a differentiation trend that is essentially controlled by biotite and plagioclase fractionation. (Fagiono, 2002). Monzogranites can be divided into two groups (magnesio-potassic monzogranite and ferro-potassic monzogranite) and are further categorized into rock types based on their macroscopic characteristics, melt characteristics, specific features, available isotopic data, and the locality in which they are found.
An endmember in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of some chemical elements, rather than as substances with an exact chemical formula. There may be two or more endmembers in a group or series of minerals.
In subsolvus or two feldspar granites crystallisation occurs at high water pressures resulting in the formation of two types of feldspar as opposed to hypersolvus granites in which crystallization at relatively low water pressures results in the formation of a single feldspar variety. Quoting Tuttle and Bowen in 1958 : ″A classification of salic rocks based on the nature of the alkali feldspar is proposed. The classification has two major divisions: (1) subsolidus, and (2) hypersolvus, depending on the whereabouts of the soda feldspar. In the hypersolvus rocks all the soda feldspar is or was in solid solution in the potash feldspar whereas in the subsolvus rocks the plagioclase is present as discrete grains. The two major divisions are further subdivided according to the nature of the alkali feldspar modification.″ Note that here the word "subsolidus" unfortunately looks like a misprint and probably has to be replaced by "subsolvus".
Pargasite is a complex inosilicate mineral of the amphibole group with formula NaCa2(Mg4Al)(Si6Al2)O22(OH)2.
Banalsite is a rare barium, sodium aluminium silicate mineral with formula: BaNa2Al4Si4O16. Banalsite is a tectosilicate of the feldspar group.
