In science and technology, an arbitrary unit (abbreviated arb. unit, [1] see below ) or procedure defined unit [2] (p.d.u.) is a relative unit of measurement to show the ratio of amount of substance, intensity, or other quantities, to a predetermined reference measurement. The reference measurement is typically defined by the local laboratories or dependent on individual measurement apparatus. It is therefore impossible to compare "1 arb. unit" by one measurer and "1000 arb. unit" by another measurer without detailed prior knowledge on how the respective "arbitrary units" were defined; thus, the unit is sometimes called an unknown unit. [2] The unit only serves to compare multiple measurements performed in similar environment, since the ratio between the measurement and the reference is a consistent and dimensionless quantity independent of what actual units are used. Units of such kind are commonly used in fields such as physiology to indicate substance concentration, and spectroscopy to express spectral intensity.
When the reference measurement is precisely defined and internationally agreed upon, arbitrary units can also be a unit capable of public comparison. One example of a publicly defined arbitrary unit is the WHO International Unit. [2]
Abbreviations for "arbitrary unit" include: arb. unit, [1] arb. u., AU, [3] and a.u. [4] Among these, "AU" and "a.u." are common abbreviations for astronomical units and atomic units. [5] For this reason, Physical Review journals, the Japanese Journal of Applied Physics, and an increasing number of other academic journals, recommend against using "a.u." (Jpn. J. Appl. Phys recommends "arb. unit" instead). [6]
In UCUM, arbitrary unit is represented as "[arb'U]". [7]
While arbitrary unit is not a formally recognized unit, [1] IUPAC and IFCC recognize the need to deal with "unknown units", and decided in 2008 to use the term "procedure defined unit" in their database. [2] The decision forbids using factors or denominators in conjunction with p.d.u. (such as "p.d.u./L").
The ampere, often shortened to amp, is the unit of electric current in the International System of Units (SI). One ampere is equal to 1 coulomb (C) moving past a point per second. It is named after French mathematician and physicist André-Marie Ampère (1775–1836), considered the father of electromagnetism along with Danish physicist Hans Christian Ørsted.
The katal is that catalytic activity that will raise the rate of conversion by one mole per second in a specified assay system. It is a unit of the International System of Units (SI) used for quantifying the catalytic activity of enzymes and other catalysts.
A physical constant, sometimes fundamental physical constant or universal constant, is a physical quantity that cannot be explained by a theory and therefore must be measured experimentally. It is distinct from a mathematical constant, which has a fixed numerical value, but does not directly involve any physical measurement.
Standard temperature and pressure (STP) or Standard conditions for temperature and pressure are various standard sets of conditions for experimental measurements used to allow comparisons to be made between different sets of data. The most used standards are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these are not universally accepted. Other organizations have established a variety of other definitions.
The mole (symbol mol) is a unit of measurement, the base unit in the International System of Units (SI) for amount of substance, a quantity proportional to the number of elementary entities of a substance. One mole contains exactly 6.02214076×1023 elementary entities (approximately 602 sextillion or 602 billion times a trillion), which can be atoms, molecules, ions, or other particles. The number of particles in a mole is the Avogadro number (symbol N0) and the numerical value of the Avogadro constant (symbol NA) expressed in mol-1. The value was chosen based on the historical definition of the mole as the amount of substance that corresponds to the number of atoms in 12 grams of 12C, which made the mass of a mole of a compound expressed in grams, numerically equal to the average molecular mass of the compound expressed in daltons. With the 2019 redefinition of the SI base units, the numerical equivalence is now only approximate but may be assumed for all practical purposes.
The Avogadro constant, commonly denoted NA or L, is an SI defining constant with an exact value of 6.02214076×1023 mol−1 (reciprocal moles). It is defined as the number of constituent particles (usually molecules, atoms, or ions) per mole (SI unit) and used as a normalization factor in the amount of substance in a sample. The constant is named after the physicist and chemist Amedeo Avogadro (1776–1856).
The dalton or unified atomic mass unit is a non-SI unit of mass defined as 1/12 of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at rest. The atomic mass constant, denoted mu, is defined identically, giving mu = 1/12m(12C) = 1 Da.
The metric system is a decimal-based system of measurement. The current international standard for the metric system is the International System of Units, in which all units can be expressed in terms of seven base units: the metre, kilogram, second, ampere, kelvin, mole, and candela.
A base unit of measurement is a unit of measurement adopted for a base quantity. A base quantity is one of a conventionally chosen subset of physical quantities, where no quantity in the subset can be expressed in terms of the others. The SI base units, or Systeme International d'unites, consists of the metre, kilogram, second, ampere, kelvin, mole and candela.
Metrology is the scientific study of measurement. It establishes a common understanding of units, crucial in linking human activities. Modern metrology has its roots in the French Revolution's political motivation to standardise units in France when a length standard taken from a natural source was proposed. This led to the creation of the decimal-based metric system in 1795, establishing a set of standards for other types of measurements. Several other countries adopted the metric system between 1795 and 1875; to ensure conformity between the countries, the Bureau International des Poids et Mesures (BIPM) was established by the Metre Convention. This has evolved into the International System of Units (SI) as a result of a resolution at the 11th General Conference on Weights and Measures (CGPM) in 1960.
In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they are pure numbers with no associated units of measurement. Commonly used are parts-per-million, parts-per-billion, parts-per-trillion and parts-per-quadrillion. This notation is not part of the International System of Units (SI) system and its meaning is ambiguous.
Relative atomic mass, also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a given sample to the atomic mass constant. The atomic mass constant is defined as being 1/12 of the mass of a carbon-12 atom. Since both quantities in the ratio are masses, the resulting value is dimensionless. These definitions remain valid even after the 2019 redefinition of the SI base units.
In chemistry, the standard state of a material is a reference point used to calculate its properties under different conditions. A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°). The degree symbol has become widespread, although the Plimsoll is recommended in standards, see discussion about typesetting below.
In chemistry, the amount of substance (symbol n) in a given sample of matter is defined as a ratio (n = N/NA) between the number of elementary entities (N) and the Avogadro constant (NA). The entities are usually molecules, atoms, or ions of a specified kind. The particular substance sampled may be specified using a subscript, e.g., the amount of sodium chloride (NaCl) would be denoted as nNaCl. The unit of amount of substance in the International System of Units is the mole (symbol: mol), a base unit. Since 2019, the value of the Avogadro constant NA is defined to be exactly 6.02214076×1023 mol−1. Sometimes, the amount of substance is referred to as the chemical amount or, informally, as the "number of moles" in a given sample of matter.
The standard atomic weight of a chemical element (symbol Ar°(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element weighted by each isotope's abundance on Earth. For example, isotope 63Cu (Ar = 62.929) constitutes 69% of the copper on Earth, the rest being 65Cu (Ar = 64.927), so
The Unified Code for Units of Measure (UCUM) is a system of codes for unambiguously representing measurement units. Its primary purpose is machine-to-machine communication rather than communication between humans.
A unit of measurement, or unit of measure, is a definite magnitude of a quantity, defined and adopted by convention or by law, that is used as a standard for measurement of the same kind of quantity. Any other quantity of that kind can be expressed as a multiple of the unit of measurement.
In 2019, four of the seven SI base units specified in the International System of Quantities were redefined in terms of natural physical constants, rather than human artifacts such as the standard kilogram. Effective 20 May 2019, the 144th anniversary of the Metre Convention, the kilogram, ampere, kelvin, and mole are now defined by setting exact numerical values, when expressed in SI units, for the Planck constant, the elementary electric charge, the Boltzmann constant, and the Avogadro constant, respectively. The second, metre, and candela had previously been redefined using physical constants. The four new definitions aimed to improve the SI without changing the value of any units, ensuring continuity with existing measurements. In November 2018, the 26th General Conference on Weights and Measures (CGPM) unanimously approved these changes, which the International Committee for Weights and Measures (CIPM) had proposed earlier that year after determining that previously agreed conditions for the change had been met. These conditions were satisfied by a series of experiments that measured the constants to high accuracy relative to the old SI definitions, and were the culmination of decades of research.
The Joint Committee for Guides in Metrology (JCGM) is an organization in Sèvres that prepared the Guide to the Expression of Uncertainty in Measurement (GUM) and the International Vocabulary of Metrology (VIM). The JCGM assumed responsibility for these two documents from the ISO Technical Advisory Group 4 (TAG4).
NPU terminology is a patient centered clinical laboratory terminology for use in the clinical laboratory sciences. Its function is to enable results of clinical laboratory examinations to be used safely across technology, time and geography. To achieve this, the NPU terminology supplies: