Biomass to liquid (BtL or BMtL) is a multi-step process of producing synthetic hydrocarbon fuels made from biomass via a thermochemical route. [1]
Biomass to liquid (BtL or BMtL) is a multi-step process of producing synthetic hydrocarbon fuels made from biomass via a thermochemical route. [1]
According to a study done by the U.S. Department of Agriculture and the Department of Energy, the United States can produce at least 1.3 billion tons of cellulosic biomass each year without decreasing the amount of biomass needed for food, animal feed, or exports. [2]
The Fischer–Tropsch process is used to produce synfuels from gasified biomass. Carbonaceous material is gasified and the gas is processed to make purified syngas (a mixture of carbon monoxide and hydrogen). The Fischer–Tropsch polymerizes syngas into diesel-range hydrocarbons. While biodiesel and bio-ethanol production so far only use parts of a plant, i.e. oil, sugar, starch or cellulose, BtL production can gasify and utilize the entire plant.
Flash pyrolysis—producing bio-oil (pyrolysis oil), char and gas at temperatures between 350 and 550 °C and residence times < 1 second (also called anhydrous pyrolysis).
Catalytic fast pyrolysis is a fast process in which the cellulose is broken down to a liquid biofuel. In this approach the cellulose is heated to 500 degrees Celsius in less than one second in a chamber to break apart the molecules. The catalyst forms chemical reactions that remove oxygen bonds and form carbon rings. After the reaction takes place gasoline is formed along with water, carbon dioxide, and carbon monoxide. [2]
Initially biomass undergoes pyrolysis process to produce pyrolysis gases and biochar. The volatile organic compounds in pyrolysis gases further undergo gasification process to produce syngas rich in hydrogen and carbon monoxide gases which is further converted in to methanol (CH3OH). [3] The carbon neutral biochar is further converted in to ethylene or ethanol with hydrogen generated from renewable electricity or used for carbon sequestration to reduce global warming CO2 gas in the atmosphere.[ citation needed ]
Fuel from energy grasses may be referred to as grassoline.
Switchgrass is a bunch grass native to North America that grows naturally in warm weather with wide adaptation capability and easy germination, allowing the switchgrass to grow faster; however, it has a low relative yield compared to other energy crops [4]
Sorghum is cultivated in warmer climates, mostly in the tropical regions. Sorghum has the potential to be an energy grass because it requires little water and can give a large yield. Sorghum, however, is an annual plant, is difficult to establish in an area, and requires a large input of fertilizers and pesticides. [4]
Miscanthus species are native to the tropical regions of Africa and southern Asia. Miscanthus can grow up to 3.5 meters high and has been trialed as a biofuel since the 1980s. The benefits of using Miscanthus are that it can live more than two years and requires low inputs, eliminating the need for extra irrigation, fertilizer and pesticides. The problems with Miscanthus arise from the time it takes to establish to an area. [4]
Sugarcane grows in irrigated lands of tropics and subtropics which can produce 15 kg biomass per square meter area. It is also suitable for BtL as its extracted juice is used to produce ethanol by traditional methods and also its remaining biomass (bagasse, leaves, shoots, etc.) can be converted in to carbon neutral ethanol or methanol by subjecting to pyrolysis and gasification. Biochar can also be produced for carbon sequestration to compensate the carbon emissions by fossil fuels or reduce CO2 gas concentration in the atmosphere.[ citation needed ]
Bamboo is one of the fastest growing plant/biomass which can be used as feed stock for BtL. [5] Most bamboo species are native to warm and moist tropical and to warm temperate climates. [6] However, many species are found in diverse climates, ranging from hot tropical regions to cool mountainous regions and highland cloud forests.
Fuel costs depend on how fast the grasses grow and other factors. [2] An estimated investment of over $325 billion (2008 basis) would be needed to build biofactories capable of producing the 65 billion gallons of biofuel needed to meet 2030 national goals. [7]
Biofuel is a fuel that is produced over a short period from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. Biofuel can be produced from plants or agricultural, domestic, or industrial biowaste. Biofuels are mostly used for transportation but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source. However, the use of biofuel has been controversial because of the several disadvantages associated with the use of it. These include for example : the "food vs fuel" debate, biofuel production methods being sustainable or not, leading to deforestation and loss of biodiversity or not.
Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principally used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII.
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.
Ethanol fuel is fuel containing ethyl alcohol, the same type of alcohol as found in alcoholic beverages. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline.
Cellulosic ethanol is ethanol produced from cellulose rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a biofuel. The carbon dioxide that plants absorb as they grow offsets some of the carbon dioxide emitted when ethanol made from them is burned, so cellulosic ethanol fuel has the potential to have a lower carbon footprint than fossil fuels.
Bioenergy is energy made or generated from biomass, which consists of recently living organisms, mainly plants. Types of biomass commonly used for bioenergy include wood, food crops such as corn, energy crops and waste from forests, yards, or farms. The IPCC defines bioenergy as a renewable form of energy. Bioenergy can either mitigate or increase greenhouse gas emissions. There is also agreement that local environmental impacts can be problematic.
Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbon-based products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas.
Waste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste, or the processing of waste into a fuel source. WtE is a form of energy recovery. Most WtE processes generate electricity and/or heat directly through combustion, or produce a combustible fuel commodity, such as methane, methanol, ethanol or synthetic fuels, often derived from the product syngas.
Pyrolysis oil, sometimes also known as bio-crude or bio-oil, is a synthetic fuel with limited industrial application and under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about 500 °C (900 °F) with subsequent cooling, separation from the aqueous phase and other processes. Pyrolysis oil is a kind of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. This high oxygen content results in non-volatility, corrosiveness, partial miscibility with fossil fuels, thermal instability, and a tendency to polymerize when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading.
The bioconversion of biomass to mixed alcohol fuels can be accomplished using the MixAlco process. Through bioconversion of biomass to a mixed alcohol fuel, more energy from the biomass will end up as liquid fuels than in converting biomass to ethanol by yeast fermentation.
Energy crops are low-cost and low-maintenance crops grown solely for renewable bioenergy production. The crops are processed into solid, liquid or gaseous fuels, such as pellets, bioethanol or biogas. The fuels are burned to generate electrical power or heat.
The United States produces mainly biodiesel and ethanol fuel, which uses corn as the main feedstock. The US is the world's largest producer of ethanol, having produced nearly 16 billion gallons in 2017 alone. The United States, together with Brazil accounted for 85 percent of all ethanol production, with total world production of 27.05 billion gallons. Biodiesel is commercially available in most oilseed-producing states. As of 2005, it was somewhat more expensive than fossil diesel, though it is still commonly produced in relatively small quantities.
Renewable Fuels are fuels produced from renewable resources. Examples include: biofuels, Hydrogen fuel, and fully synthetic fuel produced from ambient carbon dioxide and water. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.
Biofuel is fuel that is produced from organic matter (biomass), including plant materials and animal waste. It is considered a renewable source of energy that can assist in reducing carbon emissions. The two main types of biofuel currently being produced in Australia are biodiesel and bioethanol, used as replacements for diesel and petrol (gasoline) respectively. As of 2017 Australia is a relatively small producer of biofuels, accounting for 0.2% of world bioethanol production and 0.1% of world biodiesel production.
Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.
Dynamotive Energy Systems Corporation is a Canadian based Renewable Energy Company which specializes in fast pyrolysis, a process which creates a product named bio-oil. Its only other residue is char.
Ze-gen, Inc. was a renewable energy company developing advanced gasification technology to convert waste into synthesis gas. Founded in 2004, Ze-gen was a venture-backed company based in Boston, Massachusetts.
Chemrec AB (Chemrec) is a Stockholm, Sweden-based company with comprehensive experience of pioneering the development of black liquor gasification (BLG) technology for energy and chemicals recovery at pulp mills.
Syngas to gasoline plus (STG+) is a thermochemical process to convert natural gas, other gaseous hydrocarbons or gasified biomass into drop-in fuels, such as gasoline, diesel fuel or jet fuel, and organic solvents.
