Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes.
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in the fields of physics, biology, chemistry, neuroscience, computer science, information theory and sociology. Its main purpose is to clarify the properties of matter in aggregate, in terms of physical laws governing atomic motion.
Thermodynamics deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics plays a role in a wide variety of topics in science and engineering.
The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter. Another statement is: "Not all heat can be converted into work in a cyclic process."
In mathematics and science, a nonlinear system is a system in which the change of the output is not proportional to the change of the input. Nonlinear problems are of interest to engineers, biologists, physicists, mathematicians, and many other scientists since most systems are inherently nonlinear in nature. Nonlinear dynamical systems, describing changes in variables over time, may appear chaotic, unpredictable, or counterintuitive, contrasting with much simpler linear systems.
In mathematics, a measure-preserving dynamical system is an object of study in the abstract formulation of dynamical systems, and ergodic theory in particular. Measure-preserving systems obey the Poincaré recurrence theorem, and are a special case of conservative systems. They provide the formal, mathematical basis for a broad range of physical systems, and, in particular, many systems from classical mechanics as well as systems in thermodynamic equilibrium.
A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics.
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.
In science, a process that is not reversible is called irreversible. This concept arises frequently in thermodynamics. All complex natural processes are irreversible, although a phase transition at the coexistence temperature is well approximated as reversible.
Sir Joseph Larmor was an Irish physicist and mathematician who made breakthroughs in the understanding of electricity, dynamics, thermodynamics, and the electron theory of matter. His most influential work was Aether and Matter, a theoretical physics book published in 1900.
George Udny Yule, CBE, FRS, usually known as Udny Yule, was a British statistician, particularly known for the Yule distribution and proposing the preferential attachment model for random graphs.
A Boolean Delay Equation (BDE) is an evolution rule for the state of dynamical variables whose values may be represented by a finite discrete numbers os states, such as 0 and 1. As a novel type of semi-discrete dynamical systems, Boolean delay equations (BDEs) are models with Boolean-valued variables that evolve in continuous time. Since at the present time, most phenomena are too complex to be modeled by partial differential equations (as continuous infinite-dimensional systems), BDEs are intended as a (heuristic) first step on the challenging road to further understanding and modeling them. For instance, one can mention complex problems in fluid dynamics, climate dynamics, solid-earth geophysics, and many problems elsewhere in natural sciences where much of the discourse is still conceptual.
Research concerning the relationship between the thermodynamic quantity entropy and both the origin and evolution of life began around the turn of the 20th century. In 1910 American historian Henry Adams printed and distributed to university libraries and history professors the small volume A Letter to American Teachers of History proposing a theory of history based on the second law of thermodynamics and on the principle of entropy.
Reaction–diffusion systems are mathematical models that correspond to several physical phenomena. The most common is the change in space and time of the concentration of one or more chemical substances: local chemical reactions in which the substances are transformed into each other, and diffusion which causes the substances to spread out over a surface in space.
In mathematics, in the study of dynamical systems, the Hartman–Grobman theorem or linearisation theorem is a theorem about the local behaviour of dynamical systems in the neighbourhood of a hyperbolic equilibrium point. It asserts that linearisation—a natural simplification of the system—is effective in predicting qualitative patterns of behaviour. The theorem owes its name to Philip Hartman and David M. Grobman.
Dissipative solitons (DSs) are stable solitary localized structures that arise in nonlinear spatially extended dissipative systems due to mechanisms of self-organization. They can be considered as an extension of the classical soliton concept in conservative systems. An alternative terminology includes autosolitons, spots and pulses.
Energy dissipation and entropy production extremal principles are ideas developed within non-equilibrium thermodynamics that attempt to predict the likely steady states and dynamical structures that a physical system might show. The search for extremum principles for non-equilibrium thermodynamics follows their successful use in other branches of physics. According to Kondepudi (2008), and to Grandy (2008), there is no general rule that provides an extremum principle that governs the evolution of a far-from-equilibrium system to a steady state. According to Glansdorff and Prigogine, irreversible processes usually are not governed by global extremal principles because description of their evolution requires differential equations which are not self-adjoint, but local extremal principles can be used for local solutions. Lebon Jou and Casas-Vásquez (2008) state that "In non-equilibrium ... it is generally not possible to construct thermodynamic potentials depending on the whole set of variables". Šilhavý (1997) offers the opinion that "... the extremum principles of thermodynamics ... do not have any counterpart for [non-equilibrium] steady states ." It follows that any general extremal principle for a non-equilibrium problem will need to refer in some detail to the constraints that are specific for the structure of the system considered in the problem.
The free energy principle is a theoretical framework suggesting that the brain reduces surprise or uncertainty by making predictions based on internal models and updating them using sensory input. It highlights the brain's objective of aligning its internal model and the external world to enhance prediction accuracy. This principle integrates Bayesian inference with active inference, where actions are guided by predictions and sensory feedback refines them. It has wide-ranging implications for comprehending brain function, perception, and action.
Quantum thermodynamics is the study of the relations between two independent physical theories: thermodynamics and quantum mechanics. The two independent theories address the physical phenomena of light and matter. In 1905, Albert Einstein argued that the requirement of consistency between thermodynamics and electromagnetism leads to the conclusion that light is quantized, obtaining the relation . This paper is the dawn of quantum theory. In a few decades quantum theory became established with an independent set of rules. Currently quantum thermodynamics addresses the emergence of thermodynamic laws from quantum mechanics. It differs from quantum statistical mechanics in the emphasis on dynamical processes out of equilibrium. In addition, there is a quest for the theory to be relevant for a single individual quantum system.
Viachelav V. Belyi, also referred to as Slava Belyi was a Russian scientist who specialised in physics-thermodynamics, Laureate of a scientist Prize of the Russian Federation, junior, then senior and finally chief scientist at IZMIRAN (1971–2020), collaborator of Nobel prize Laureate Ilya Prigogine in 1980s and 1990s with an external affiliation to the Laboratoire de physique des plasmas at the ULB.
