Ferronickel platinum | |
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General | |
Category | Mineral |
Formula (repeating unit) | Pt2FeNi [1] Pt(Ni,Fe) [2] |
IMA symbol | Fnpt [3] |
Strunz classification | 1.AG.40 (8th edition: I/A.15) [4] |
Dana classification | 1.2.4.3 [4] |
Crystal system | Tetragonal |
Crystal class | ditetragonal-dipyramidal; 4/m 2/m 2/m [5] |
Space group | P4/mmm (No. 123) |
Identification | |
Colour | Silver white |
Mohs scale hardness | 4.5 to 5 (VHN50=381–592, average 481) |
Diaphaneity | Opaque |
Ferronickel platinum is a very rarely occurring minerals from the mineral class of elements (including natural alloys, intermetallic compounds, carbides, nitrides, phosphides and silicides) with the chemical composition Pt2FeNi [1] and thus is chemically seen as a natural alloy, more precisely an intermetallic compound of platinum, nickel and iron in a ratio of 2:1:1.
Ferronickel platinum crystallizes in the tetragonal crystal system, but has so far only been found in microcrystalline form. Ferronickel platinum occurs together with other platinum group minerals as irregular, slightly rounded or grape-like grains of up to 4.5 millimetres (180 mils) in size, with the mono-mineral areas only up to about 0.15 millimetres (5.9 mils) in size. [4]
Ferronickel platinum is opaque in every form and shows a metallic sheen on the silver-white grain surfaces.
Ferronickel platinum was discovered for the first time in a soap deposit on the Pekulney River in the Pekulney Mountains of the same name in the Chukotka Autonomous Okrug belonging to Russia. The mineral was described by N. S. Rudashevsky, A. G. Mochalov, Yu. P. Men'shikov and N. I. Shumskaya, who named it based on its chemical composition.
The mineral description and chosen name were submitted to the International Mineralogical Association(IMA) for examination in 1982 (internal register no. 1982-071). This recognized the mineral as independent in the same year. The publication of the new discovery followed the following year in the Russian scientific magazine "Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva" (Proceedings of the Russian Mineralogical Society) [6] and was published in 1984 by Pete J. Dunn et al. when the new mineral names recognized by the IMA were announced. [7]
The type material of the mineral is stored in the State Mining Institute in Saint Petersburg under catalog no. 1306/1. [7] [8]
As per 8th edition of the mineral classification by Strunz of ferronickel platinum belonged to the mineral class of "elements" and then to the Department of "metals and intermetallic alloys (semimetals)" where he collaborated with Chengdeit, Isoferroplatin, Nielsenit, Tetraferroplatinum and tulameenite formed the unnamed group I / A.15.
The 9th edition of Strunz's mineral systematics, which has been in effect since 2001 and is used by the IMA, also assigns isoferroplatinum to the “Metals and intermetallic compounds” section. However, this is further subdivided according to the predominant metals in the compound, which have been divided into metal families according to their related properties. According to its composition, ferronickel platinum can be found in the sub-section “PGE metal alloys”, where the “tetraferroplatinum group” with system no. 1.AG.40 forms.
The systematics of minerals according to Dana, which is mainly used in the English-speaking world, also assigns ferronickel platinum to the class and there in the department of the same name of "elements". Here it is also together with tetraferroplatinum, tulameenite and potarite in the " tetraferroplatinum group (space group P4/mmm) " with the system no. 02/01/04 within the sub-section "Elements: Platinum Group Metals and Alloys". [5]
On the basis of six grains in a polished area, the analysis with the aid of the electron microprobe showed the chemical composition of 75.7–77.6% platinum, 10.4–11.0% iron, 10.2–11.7% nickel, 0, 27-0.69% iridium and 0.33-0.36 copper (98.41-100.76% in total), which corresponds to an empirical composition of (Pt2.016Ir0.012)Fe0.983(Ni0.962Cu0.027) or the idealized one Composition corresponds to Pt2FeNi. Analyzes of a further four grains showed variable but low contents of Ruthenium, Rhodium, Palladium and Cobalt. Due to the variable Cu-Ni content, however, it is assumed that ferronickel platinum forms a gapless series of mixed crystals with tulameenite (Pt2FeCu). [7]
Ferronickel platinum crystallizes tetragonally in the space group P4/mmm (space group no. 123) with the lattice parameters a = 2.73 Å and c = 3.64 Å and one formula unit per unit cell. [2]
At its type locality on the Pekulnei River, the mineral was found in the heavy mineral concentrates of quaternary, alluvial deposits together with ultramafites in an ophiolite band. Cherepanovite, chromite, cooperite, hollingworthite, irarsite, isoferroplatinum, laurite, olivine, rutheniridosmin, sperrylite and tetraferroplatinum appeared as accompanying minerals.
In Russia they found ferronickel platinum out of the river Pekulnei still in Koriak-Kamchatka - folding zone in the Far East and in Kytlym complex and at the nearby platinum mine Gosshakhta in the Sverdlovsk Oblast in the Urals. [9]
Other sites known to date (as of 2018) are the Loma Peguera open pit nickel mine about 11 km northeast of Bonao in the Dominican Republic, the Bir Bir river in the Ethiopian region of Oromia, the Ophiolithe on Île Ouen in the municipality of Le Mont-Dore in New Caledonia, the Bushveld Complex in South Africa and an unspecified site near Nottingham Township in Chester County in the US state of Pennsylvania. [9]
Torbernite, also known as chalcolite, is a relatively common mineral with the chemical formula Cu[(UO2)(PO4)]2(H2O)12. It is a radioactive, hydrated green copper uranyl phosphate, found in granites and other uranium-bearing deposits as a secondary mineral. The chemical formula of torbernite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+ cation. Torbernite tends to dehydrate to metatorbernite with the sum formula Cu[(UO2)(PO4)]2(H2O)8.
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts. Sulfide minerals are inorganic compounds.
Chromium(II) carbide is a ceramic compound that exists in several chemical compositions: Cr3C2, Cr7C3, and Cr23C6. At standard conditions it exists as a gray solid. It is extremely hard and corrosion resistant. It is also a refractory compound, which means that it retains its strength at high temperatures as well. These properties make it useful as an additive to metal alloys. When chromium carbide crystals are integrated into the surface of a metal it improves the wear resistance and corrosion resistance of the metal, and maintains these properties at elevated temperatures. The hardest and most commonly used composition for this purpose is Cr3C2.
Talnakhite is a mineral of chalcopyrite group with formula: Cu9(Fe, Ni)8S16. It was named after the Talnakh ore deposit, near Norilsk in Western Siberia, Russia where it was discovered as reported in 1963 by I. Budko and E. Kulagov. It was officially named "talnakhite" in 1968. Despite the initial announcement it turned out to be not a face centered high-temperature polymorph of chalcopyrite, but to have composition Cu18(Fe, Ni)18S32. At 80 °C (176 °F) to 100 °C (212 °F) it decomposes to tetragonal cubanite plus bornite.
Nickel–Strunz classification is a scheme for categorizing minerals based upon their chemical composition, introduced by German mineralogist Karl Hugo Strunz in his Mineralogische Tabellen (1941). The 4th and the 5th edition was also edited by Christel Tennyson (1966). It was followed by A.S. Povarennykh with a modified classification.
Aleksite (IMA symbol: Alk) is a rare lead bismuth tellurium sulfosalt mineral with formula PbBi2Te2S2.
Alluaivite is a rare mineral of the eudialyte group, with complex formula written as Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl·2H2O. It is unique among the eudialyte group as the only titanosilicate (other representatives of the group are usually zirconosilicates). The two dual-nature minerals of the group, being both titano- and zirconosilicates, are labyrinthite and dualite. They both contain alluaivite module in their structures. Alluaivite is named after Mt. Alluaiv in Lovozero Tundry massif, Kola Peninsula, Russia, where it is found in ultra-agpaitic, hyperalkaline pegmatites.
Alsakharovite-Zn (IMA symbol: Ask-Zn) is an extremely rare alkaline strontium zinc titanium silicate mineral from the cyclosilicates class, with the chemical formula NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4·7H2O, from alkaline pegmatites. It belongs to the labuntsovite group.
Coyoteite is a hydrated sodium iron sulfide mineral. The mineral was named coyoteite after Coyote Peak near Orick, California, where it was discovered.
Braggite is a sulfide mineral of platinum, palladium and nickel with chemical formula: S. It is a dense, steel grey, opaque mineral which crystallizes in the tetragonal crystal system. It is the central member in the platinum group end-members cooperite and vysotskite.
Skaergaardite is an intermetallic platinum group mineral with the general chemical formula PdCu. The mineral is named after its discovery location: the Skaergaard intrusion, Kangerdlugssuaq area, East Greenland. The mineral name was approved by the International Mineralogical Association in 2003. The mineral has also been reported in the Duluth intrusion in Minnesota and the Rum layered intrusion in Scotland.
Native element minerals are those elements that occur in nature in uncombined form with a distinct mineral structure. The elemental class includes metals, intermetallic compounds, alloys, metalloids, and nonmetals. The Nickel–Strunz classification system also includes the naturally occurring phosphides, silicides, nitrides, carbides, and arsenides.
Abramovite is a very rare mineral from the sulfides and sulfosalt categories. It has the chemical formula Pb2SnInBiS7. It occurs as tiny elongated lamellar-shaped crystals, up 1 mm × 0.2 mm in size, and is characterized by its non-commensurate structure.
Daubréelite is a rare sulfide mineral. It crystallizes with cubic symmetry and has chemical composition of Fe2+Cr3+2S4. It usually occurs as black platy aggregates.
Carbokentbrooksite is a very rare mineral of the eudialyte group, with formula (Na,□)12(Na,Ce)3Ca6Mn3Zr3NbSiO(Si9O27)2(Si3O9)2(OH)3(CO3).H2O. The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group. Carbokenbrooksite characterizes in being carbonate-rich (the other eudialyte-group species with essential carbonate are zirsilite-(Ce), golyshevite, and mogovidite). It is also sodium rich, being sodium equivalent of zirsilite-(Ce), with which it is intimately associated.
Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula (Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)·H2O. The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group. Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated. The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the name) in dominance is johnsenite-(Ce).
Labyrinthite is a very rare mineral of the eudialyte group. When compared to other species in the group, its structure is extremely complex – with over 100 sites and about 800 cations and anions – hence its name, with its complexity expressed in its chemical formula (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3. The formula is simplified as it does not show the presence of cyclic silicate groups. Complexity of the structure results in symmetry lowering from the typical centrosymmetrical group to R3 space group. Other eudialyte-group representatives with such symmetry lowering include aqualite, oneillite, raslakite, voronkovite. Labyrinthite is the second dual-nature representative of the group after dualite and third with essential titanium after dualite and alluaivite.
Georgbarsanovite is a very rare mineral of the eudialyte group, formerly known under unaccepted name as barsanovite, with formula Na12(Mn,Sr,REE)3Ca6Fe32+Zr3NbSi(Si3O9)2(Si9O27)2O4Cl2·H2O. The original formula was extended to show the presence of cyclic silicate groups and the domination of silicon at the M4 site. "REE", standing for rare earth elements, is dominated by cerium. Georgbarsanovite is characterized in dominance of manganese at the N4 site. It also differs from most other accepted group representatives in its colour. The mineral was found in nepheline pegmatite near Petrelius River, Khibiny massif, Kola Peninsula, Russia. It is named after Russian mineralogist Georg Barsanov.
Freudenbergite is a mineral that is named in honor of Wilhelm Freudenberg, palaeontologist at the University of Tübingen and the University of Göttingen, and curator for mineralogy and geology at the National Collections of Natural History in Karlsruhe. He studied Katzenbuckel rocks.