The Beer-Lambert law is commonly applied to chemical analysis measurements to determine the concentration of chemical species that absorb light. It is often referred to as Beer's law. In physics, the Bouguer–Lambert law is an empirical law which relates the extinction or attenuation of light to the properties of the material through which the light is travelling. It had its first use in astronomical extinction. The fundamental law of extinction is sometimes called the Beer-Bouguer-Lambert law or the Bouguer-Beer-Lambert law or merely the extinction law. The extinction law is also used in understanding attenuation in physical optics, for photons, neutrons, or rarefied gases. In mathematical physics, this law arises as a solution of the BGK equation.
In physics, the cross section is a measure of the probability that a specific process will take place when some kind of radiant excitation intersects a localized phenomenon. For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during an interaction with an atomic nucleus. Cross section is typically denoted σ (sigma) and is expressed in units of area, more specifically in barns. In a way, it can be thought of as the size of the object that the excitation must hit in order for the process to occur, but more exactly, it is a parameter of a stochastic process.
Stimulated emission is the process by which an incoming photon of a specific frequency can interact with an excited atomic electron, causing it to drop to a lower energy level. The liberated energy transfers to the electromagnetic field, creating a new photon with a frequency, polarization, and direction of travel that are all identical to the photons of the incident wave. This is in contrast to spontaneous emission, which occurs at a characteristic rate for each of the atoms/oscillators in the upper energy state regardless of the external electromagnetic field.
The active laser medium is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from a higher energy state previously populated by a pump source.
In probability theory, a log-normal (or lognormal) distribution is a continuous probability distribution of a random variable whose logarithm is normally distributed. Thus, if the random variable X is log-normally distributed, then Y = ln(X) has a normal distribution. Equivalently, if Y has a normal distribution, then the exponential function of Y, X = exp(Y), has a log-normal distribution. A random variable which is log-normally distributed takes only positive real values. It is a convenient and useful model for measurements in exact and engineering sciences, as well as medicine, economics and other topics (e.g., energies, concentrations, lengths, prices of financial instruments, and other metrics).
In physics, mean free path is the average distance over which a moving particle travels before substantially changing its direction or energy, typically as a result of one or more successive collisions with other particles.
In probability theory and statistics, a covariance matrix is a square matrix giving the covariance between each pair of elements of a given random vector.
In mathematics, a Gaussian function, often simply referred to as a Gaussian, is a function of the base form
Tunable diode laser absorption spectroscopy is a technique for measuring the concentration of certain species such as methane, water vapor and many more, in a gaseous mixture using tunable diode lasers and laser absorption spectrometry. The advantage of TDLAS over other techniques for concentration measurement is its ability to achieve very low detection limits. Apart from concentration, it is also possible to determine the temperature, pressure, velocity and mass flux of the gas under observation. TDLAS is by far the most common laser based absorption technique for quantitative assessments of species in gas phase.
Radiative transfer is the physical phenomenon of energy transfer in the form of electromagnetic radiation. The propagation of radiation through a medium is affected by absorption, emission, and scattering processes. The equation of radiative transfer describes these interactions mathematically. Equations of radiative transfer have application in a wide variety of subjects including optics, astrophysics, atmospheric science, and remote sensing. Analytic solutions to the radiative transfer equation (RTE) exist for simple cases but for more realistic media, with complex multiple scattering effects, numerical methods are required. The present article is largely focused on the condition of radiative equilibrium.
Opacity is the measure of impenetrability to electromagnetic or other kinds of radiation, especially visible light. In radiative transfer, it describes the absorption and scattering of radiation in a medium, such as a plasma, dielectric, shielding material, glass, etc. An opaque object is neither transparent nor translucent. When light strikes an interface between two substances, in general some may be reflected, some absorbed, some scattered, and the rest transmitted. Reflection can be diffuse, for example light reflecting off a white wall, or specular, for example light reflecting off a mirror. An opaque substance transmits no light, and therefore reflects, scatters, or absorbs all of it. Other categories of visual appearance, related to the perception of regular or diffuse reflection and transmission of light, have been organized under the concept of cesia in an order system with three variables, including opacity, transparency and translucency among the involved aspects. Both mirrors and carbon black are opaque. Opacity depends on the frequency of the light being considered. For instance, some kinds of glass, while transparent in the visual range, are largely opaque to ultraviolet light. More extreme frequency-dependence is visible in the absorption lines of cold gases. Opacity can be quantified in many ways; for example, see the article mathematical descriptions of opacity.
The statistics of random permutations, such as the cycle structure of a random permutation are of fundamental importance in the analysis of algorithms, especially of sorting algorithms, which operate on random permutations. Suppose, for example, that we are using quickselect to select a random element of a random permutation. Quickselect will perform a partial sort on the array, as it partitions the array according to the pivot. Hence a permutation will be less disordered after quickselect has been performed. The amount of disorder that remains may be analysed with generating functions. These generating functions depend in a fundamental way on the generating functions of random permutation statistics. Hence it is of vital importance to compute these generating functions.
In physics, a quantum amplifier is an amplifier that uses quantum mechanical methods to amplify a signal; examples include the active elements of lasers and optical amplifiers.
Self-pulsation is a transient phenomenon in continuous-wave lasers. Self-pulsation takes place at the beginning of laser action. As the pump is switched on, the gain in the active medium rises and exceeds the steady-state value. The number of photons in the cavity increases, depleting the gain below the steady-state value, and so on. The laser pulsates; the output power at the peaks can be orders of magnitude larger than that between pulses. After several strong peaks, the amplitude of pulsation reduces, and the system behaves as a linear oscillator with damping. Then the pulsation decays; this is the beginning of the continuous-wave operation.
Self-focusing is a non-linear optical process induced by the change in refractive index of materials exposed to intense electromagnetic radiation. A medium whose refractive index increases with the electric field intensity acts as a focusing lens for an electromagnetic wave characterized by an initial transverse intensity gradient, as in a laser beam. The peak intensity of the self-focused region keeps increasing as the wave travels through the medium, until defocusing effects or medium damage interrupt this process. Self-focusing of light was discovered by Gurgen Askaryan.
The McCumber relation is a relationship between the effective cross-sections of absorption and emission of light in the physics of solid-state lasers. It is named after Dean McCumber, who proposed the relationship in 1964.
Photon transport in biological tissue can be equivalently modeled numerically with Monte Carlo simulations or analytically by the radiative transfer equation (RTE). However, the RTE is difficult to solve without introducing approximations. A common approximation summarized here is the diffusion approximation. Overall, solutions to the diffusion equation for photon transport are more computationally efficient, but less accurate than Monte Carlo simulations.
When an electromagnetic wave travels through a medium in which it gets attenuated, it undergoes exponential decay as described by the Beer–Lambert law. However, there are many possible ways to characterize the wave and how quickly it is attenuated. This article describes the mathematical relationships among:
Laser linewidth is the spectral linewidth of a laser beam.
Laser theory of Fabry-Perot (FP) semiconductor lasers proves to be nonlinear, since the gain, the refractive index and the loss coefficient are the functions of energy flux. The nonlinear theory made it possible to explain a number of experiments some of which could not even be explained, much less modeled, on the basis of other theoretical models; this suggests that the nonlinear theory developed is a new paradigm of the laser theory.
