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IUPAC name (R)-[(2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methanol;sulfuric acid;tetratriiodide | |
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3D model (JSmol) | |
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ECHA InfoCard | 100.028.677 |
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Properties | |
C60H84I12N6O30S6 | |
Molar mass | 3084.56 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Herapathite, or iodoquinine sulfate , is a chemical compound whose crystals are dichroic and thus can be used for polarizing light.
It was discovered in 1852 [1] by William Bird Herapath, a Bristol surgeon and chemist. One of his pupils found that adding iodine to the urine of a dog that had been fed quinine produced unusual green crystals. Herapath noticed while studying the crystals under a microscope that they appeared to polarize light. [2]
In the 1930s, Ferdinand Bernauer invented a process to grow single herapathite crystals large enough to be sandwiched between two sheets of glass to create a polarizing filter; these were sold under brand name "Bernotar" by Carl Zeiss. Herapathite can be formed by precipitation by dissolving quinine sulfate in acetic acid and adding iodine tincture. [3]
Herapathite's dichroic properties came to the attention of Sir David Brewster, and were later used by Edwin H. Land in 1929 to construct the first type of Polaroid sheet polarizer. He did this by embedding herapathite crystals in a polymer instead of growing a single large crystal.
Structurally, herapathite consists of quinine (in a cationic doubly-protonated ammonium form), sulfate counterions, and triiodide units, all as a hydrate. They combine as 4C20H26N2O2•3SO4•2I3•6H2O, or sometimes other ratios and higher polyiodides. [4]
In optics, polarized light can be described using the Jones calculus, invented by R. C. Jones in 1941. Polarized light is represented by a Jones vector, and linear optical elements are represented by Jones matrices. When light crosses an optical element the resulting polarization of the emerging light is found by taking the product of the Jones matrix of the optical element and the Jones vector of the incident light. Note that Jones calculus is only applicable to light that is already fully polarized. Light which is randomly polarized, partially polarized, or incoherent must be treated using Mueller calculus.
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal can flow like a liquid, but its molecules may be oriented in a common direction as in a solid. There are many types of LC phases, which can be distinguished by their optical properties. The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. An LC material may not always be in an LC state of matter.
Microscopy is the technical field of using microscopes to view objects and areas of objects that cannot be seen with the naked eye. There are three well-known branches of microscopy: optical, electron, and scanning probe microscopy, along with the emerging field of X-ray microscopy.
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes or metamaterials.
In optics, a dichroic material is either one which causes visible light to be split up into distinct beams of different wavelengths (colours), or one in which light rays having different polarizations are absorbed by different amounts.
Polaroid is a type of synthetic plastic sheet which is used as a polarizer or polarizing filter. A trademark of the Polaroid Corporation, the term has since entered common use.
Birefringence means double refraction. It is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefringent or birefractive. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress.
Thin-film optics is the branch of optics that deals with very thin structured layers of different materials. In order to exhibit thin-film optics, the thickness of the layers of material must be similar to the coherence length; for visible light it is most often observed between 200 and 1000 nm of thickness. Layers at this scale can have remarkable reflective properties due to light wave interference and the difference in refractive index between the layers, the air, and the substrate. These effects alter the way the optic reflects and transmits light. This effect, known as thin-film interference, is observable in soap bubbles and oil slicks.
A Faraday rotator is a polarization rotator based on the Faraday effect, a magneto-optic effect involving transmission of light through a material when a longitudinal static magnetic field is present. The state of polarization is rotated as the wave traverses the device, which is explained by a slight difference in the phase velocity between the left and right circular polarizations. Thus it is an example of circular birefringence, as is optical activity, but involves a material only having this property in the presence of a magnetic field.
In optics, the Pockels effect, or Pockels electro-optic effect, is a directionally-dependent linear variation in the refractive index of an optical medium that occurs in response to the application of an electric field. It is named after the German physicist Friedrich Carl Alwin Pockels, who studied the effect in 1893. The non-linear counterpart, the Kerr effect, causes changes in the refractive index at a rate proportional to the square of the applied electric field. In optical media, the Pockels effect causes changes in birefringence that vary in proportion to the strength of the applied electric field.
A fiber laser is a laser in which the active gain medium is an optical fiber doped with rare-earth elements such as erbium, ytterbium, neodymium, dysprosium, praseodymium, thulium and holmium. They are related to doped fiber amplifiers, which provide light amplification without lasing.
Discrete dipole approximation (DDA), also known as coupled dipole approximation, is a method for computing scattering of radiation by particles of arbitrary shape and by periodic structures. Given a target of arbitrary geometry, one seeks to calculate its scattering and absorption properties by an approximation of the continuum target by a finite array of small polarizable dipoles. This technique is used in a variety of applications including nanophotonics, radar scattering, aerosol physics and astrophysics.
There are various classifications of the electro-optical modes of liquid crystal displays (LCDs).
A beam of light has radial polarization if at every position in the beam the polarization vector points towards the center of the beam. In practice, an array of waveplates may be used to provide an approximation to a radially polarized beam. In this case the beam is divided into segments, and the average polarization vector of each segment is directed towards the beam centre.
In optics, a nematicon is a spatial soliton in nematic liquid crystals (NLC). The name was invented in 2003 by G. Assanto. and used thereafter Nematicons are generated by a special type of optical nonlinearity present in NLC: the light induced reorientation of the molecular director. This nonlinearity arises from the fact that the molecular director tends to align along the electric field of light. Nematicons are easy to generate because the NLC dielectric medium exhibits the following properties:
An Airy beam, is a propagation invariant wave whose main intensity lobe propagates along a curved parabolic trajectory while being resilient to perturbations (self-healing).
The term chiral describes an object, especially a molecule, which has or produces a non-superposable mirror image of itself. In chemistry, such a molecule is called an enantiomer or is said to exhibit chirality or enantiomerism. The term "chiral" comes from the Greek word for the human hand, which itself exhibits such non-superimposeability of the left hand precisely over the right. Due to the opposition of the fingers and thumbs, no matter how the two hands are oriented, it is impossible for both hands to exactly coincide. Helices, chiral characteristics (properties), chiral media, order, and symmetry all relate to the concept of left- and right-handedness.
R. Clark Jones was an American physicist working in the field of optics. He studied at Harvard University and received his PhD in 1941. Until 1944 he worked at Bell Labs, later until 1982 with the Polaroid Corporation. In a sequence of publications between 1941 and 1956 he demonstrated a mathematical model to describe the polarization of coherent light, the Jones calculus.
Dr William Bird Herapath FRS FRSE FRCS was an English surgeon and chemist known for his discovery of Herapathite.
Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is LaF
3.